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MSDS: Zinc Acetate

Identification

Product Name: Zinc Acetate
Chemical Formula: C4H6O4Zn
CAS Number: 557-34-6
EC Number: 209-170-2
Recommended Use: Laboratory chemicals, manufacturing, pharmaceutical ingredient
Supplier Details: Manufacturer’s contact details, emergency phone number, address
Synonyms: Acetic acid zinc salt, Zinc diacetate, Zinc ethanoate

Hazard Identification

GHS Classification: Acute toxicity (oral, category 4), Eye irritation (category 2A), Specific target organ toxicity (single exposure, category 3)
Signal Word: Warning
Hazard Statements: Harmful if swallowed. Causes serious eye irritation. May cause respiratory irritation.
Pictograms: Exclamation mark
Precautionary Statements: Avoid breathing dust. Wash thoroughly after handling. Use in well-ventilated area. Wear protective gloves and eye protection. If in eyes: rinse with water. If inhaled: remove to fresh air.

Composition / Information on Ingredients

Chemical Identity: Zinc Acetate
Percentage: 99–100%
Impurities: Trace moisture possible, no major impurities expected in reagent-grade material
Hazardous Components: Zinc acetate anhydrous or dihydrate depending on supplier specification
Additional Information: No other ingredients present classified as hazardous above threshold limits

First Aid Measures

Inhalation: Move person to fresh air. Seek medical attention if symptoms develop. Maintain clear airways.
Skin Contact: Remove contaminated clothing. Rinse skin with soap and water. Consult physician if irritation continues.
Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses if present.
Ingestion: Rinse mouth. Do not induce vomiting unless instructed by medical professional. Seek immediate help.
Symptoms: Cough, throat irritation, eye redness, abdominal pain, nausea may appear. Prolonged contact heightens health risk.

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide for small fires.
Unsuitable Extinguishing Media: Do not use high-pressure water streams, as these may disperse powder.
Hazardous Combustion Products: Oxides of zinc, carbon monoxide, carbon dioxide
Protective Equipment for Firefighters: Wear self-contained breathing apparatus and full protective gear. Use caution in smoke production.
Special Hazards: Powder can form explosive mixtures with air. Keep containers cool by spraying with water.

Accidental Release Measures

Personal Precautions: Wear gloves, goggles, and dust mask. Avoid breathing dust and prevent skin or eye exposure.
Environmental Precautions: Prevent material entry into drains, water courses, and soil.
Cleanup Methods: Sweep up and place in a suitable, closed chemical waste container. Avoid creating dust. Ventilate area.
Decontamination: Wash spill site after complete pickup. Dispose as hazardous waste as per regulations.
Reporting: Notify supervisory personnel and authorities if release enters environment.

Handling and Storage

Handling Guidance: Use appropriate personal protective equipment. Handle only in well-ventilated areas. Avoid dust generation and inhalation. Do not eat, drink, or smoke during use. Wash hands after handling.
Storage Conditions: Store in tightly sealed original container. Place in dry, cool, well-ventilated area away from incompatibles such as oxidizers and acids.
Incompatible Materials: Strong acids, strong oxidizing agents
Storage Class: Chemical storage, keep away from direct sunlight and moisture.
Special Packaging Requirements: Use containers resistant to corrosion and chemical attack.

Exposure Controls and Personal Protection

Occupational Exposure Limit: OSHA PEL for zinc compounds (10 mg/m³ Total dust)
Engineering Controls: Use local exhaust ventilation or chemical fume hood. Facilities should have eyewash and safety shower.
Personal Protection: Wear gloves resistant to chemicals (nitrile recommended), safety goggles, and lab coat. Use dust mask (NIOSH approved) or respirator if airborne concentrations are high.
Hygiene Measures: Wash hands before breaks and at end of work. Do not touch face or rub eyes. Remove contaminated clothing and wash before reuse.
Environmental Controls: Implement measures to keep out of water systems and soil to prevent ecosystem exposure.

Physical and Chemical Properties

Appearance: White, crystalline powder or granules (may be colorless in pure form)
Odor: Slight acetic acid scent
pH: 5.0–6.0 (50g/l water)
Melting Point: Decomposes at 237°C for dihydrate
Boiling Point: Not applicable (decomposes on heating)
Solubility: Soluble in water and ethanol
Vapor Pressure: Negligible at room temperature
Relative Density: 1.74 g/cm³ at 25°C (dihydrate)
Partition Coefficient: Log Kow not determined
Other Data: Slightly hygroscopic, dust can disperse easily in dry air

Stability and Reactivity

Chemical Stability: Stable under normal conditions; avoid excessive moisture and heat.
Reactivity: Reacts with strong acids and strong oxidizers; may release flammable or toxic fumes.
Hazardous Polymerization: Will not occur.
Decomposition Products: Releases zinc oxide and acetic acid fumes; carbon oxides if combusted.
Conditions to Avoid: Heat, incompatibles, humidity, open flames

Toxicological Information

Acute Toxicity (Oral): Harmful; LD50 (oral, rat) around 1,200 mg/kg
Acute Toxicity (Dermal/Inhalation): Not well established, irritant to skin, eyes, and mucous membranes
Chronic Exposure: Extended contact can lead to skin dryness, respiratory irritation, and possible zinc poisoning with systemic exposure
Symptoms: Abdominal pain, nausea, vomiting, headache, cough, and eye redness are possible
Sensitization: Not known to be a skin sensitizer
Carcinogenicity: Not listed by IARC, NTP, or OSHA as carcinogen
Mutagenicity/Reproductive Toxicity: No evidence of mutagenicity or reproductive risk in standard studies

Ecological Information

Aquatic Toxicity: Harmful to aquatic life; zinc ions are toxic to fish and invertebrates
Persistence and Degradability: Inorganic compound; does not biodegrade, persists in environment
Bioaccumulation Potential: Zinc can accumulate in aquatic organisms
Mobility in Soil: Moderately mobile; sorbs to soil particles at lower pH
Other Adverse Effects: Release into waterways can disrupt aquatic ecosystems and food chains

Disposal Considerations

Waste Disposal Methods: Dispose of contents and container in accordance with local, state, and federal regulations. Do not flush into water systems.
Contaminated Packaging: Rinse container, then offer for recycling if available or dispose as hazardous waste.
Physical/Chemical Removal: Transfer to hazardous waste incineration or approved landfill.
Precautions: Avoid uncontrolled release to environment. Consult waste disposal experts for large quantities.

Transport Information

UN Number: Not regulated for ground, air, or ocean transport under most jurisdictions
Proper Shipping Name: Zinc Acetate
Hazard Class: Not classified as dangerous goods
Packing Group: No special packing group
Transport Precautions: Store upright, prevent moisture ingress, secure containers during movement

Regulatory Information

OSHA: Covered under Hazard Communication Standard; zinc compounds included in chemical exposure limits
TSCA: Listed on US Toxic Substances Control Act Inventory
SARA Title III: Not subject to reporting requirements as hazardous substance
REACH: Registered under European Regulation (EC) No 1907/2006 for zinc compounds
Other Regulations: Subject to workplace safety laws requiring risk assessment and record keeping; not on California Prop 65 list; observe national and regional environmental protection directives