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Material Safety Data Sheet (MSDS) for Terpene Resin

Identification

Product Name: Terpene Resin
Synonyms: Polyterpene, Terpene Polymer, Pine Resin
CAS Number: 8050-26-8
Manufacturer: Multiple global suppliers; contact local distributor for details
Emergency Phone Number: Refer to local supplier
Recommended Use: Adhesives, coatings, inks, rubber compounding, chewing gum bases, fragrances
Restrictions on Use: Industrial processing, not for direct ingestion or inhalation
Date of Preparation: Refer to packaging or latest revision from supplier

Hazard Identification

Classification: Non-hazardous under OSHA 29 CFR 1910.1200
GHS Label Elements: None required
Hazard Statements: May cause mild skin or eye irritation
Precautionary Statements: Avoid direct contact, use adequate ventilation
Routes of Exposure: Skin, eyes, inhalation of dust or heated fumes
Symptoms: Redness, itching, dryness on skin; temporary eye discomfort
Physical Hazards: Can become slippery when spilled
Environmental Hazards: Not considered an aquatic hazard in typical quantities

Composition / Information on Ingredients

Substance: Homopolymerized Terpene Hydrocarbons
Purity: Typically above 95%
Impurities: Minor traces of unreacted monoterpenes, proprietary stabilizers
Ingredient Listings: Contains no ingredients listed as carcinogenic or mutagenic by IARC, NTP, or OSHA
Other Additives: None reported for standard grades

First Aid Measures

Inhalation: Move affected person to fresh air; provide oxygen if respiratory distress occurs; seek medical advice if symptoms persist
Eye Contact: Flush gently with water for at least 15 minutes; remove contact lenses if present; obtain medical attention for continuing irritation
Skin Contact: Wash thoroughly with soap and water; remove contaminated clothing; apply moisturizing lotion for dryness
Ingestion: Rinse mouth with water; do not induce vomiting; get medical help if feeling unwell
Notes for Physician: Treat symptomatically; no known specific antidote

Fire-Fighting Measures

Suitable Extinguishing Media: Foam, dry chemical, carbon dioxide, water spray
Unsuitable Media: Direct water jets can spread molten resin
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, complex hydrocarbons, irritant fumes
Special Protective Equipment: Full protective gear and self-contained breathing apparatus recommended for fire-fighting
Specific Hazards: Melts and flows when heated, increasing risk of spreading flames
Fire/Explosion Risk: Dust clouds from powder forms may pose explosion hazard in confined spaces

Accidental Release Measures

Personal Precautions: Avoid direct contact; ventilate area; keep unauthorized persons away
Protective Equipment: Gloves, goggles, dust mask or respirator if airborne resin particles form
Environmental Precautions: Prevent entry into drains, sewers, surface waters
Clean-up Methods: Sweep up solids, shovel into containers for disposal; for molten material, allow to cool and solidify before handling; wash residues with detergent and water
Spill Response: Use sand or inert material to absorb spill; avoid generating dust

Handling and Storage

Handling: Minimize dust formation; avoid breathing dust or fumes; use local exhaust for heated processes; wash hands thoroughly after handling
Storage Conditions: Store in cool, dry, well-ventilated place, away from heat, sparks, and open flames; keep container tightly closed
Incompatible Materials: Strong oxidizers, acids, bases
Packaging Materials: Use original or compatible containers
Special Requirements: Avoid stacking heavy pallets; protect from moisture

Exposure Controls and Personal Protection

Exposure Limits: No established OSHA PEL or ACGIH TLV for terpene resin; maintain airborne dust below 10 mg/m³ for nuisance particulates
Engineering Controls: Adequate ventilation, dust extraction systems where necessary
Personal Protection: Safety goggles, impervious gloves (nitrile or PVC), long sleeves
Respiratory Protection: Use dust mask or respirator if airborne concentrations exceed comfort levels
Hygiene Measures: Wash hands before eating, drinking, smoking; change contaminated clothing

Physical and Chemical Properties

Appearance: Light yellow to amber granules, flakes, or solid blocks
Odor: Mild pine or citrus aroma
pH: Not applicable (insoluble in water)
Boiling Point: Decomposes before boiling
Melting Point: 80°C – 135°C (176°F – 275°F) depending on grade
Flash Point: Above 225°C (437°F), Cleveland Open Cup
Flammability: Not easily ignited, slow to catch fire
Solubility: Insoluble in water; soluble in alcohols, hydrocarbons, esters
Vapor Pressure: Not measurable at room temperature
Vapor Density: Not applicable
Specific Gravity: 0.97–1.10
Partition Coefficient: Not available
Evaporation Rate: Not applicable
Viscosity: Very high (solid at ambient temperature)

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Thermal Decomposition: Forms fumes and irritant gases at elevated temperatures
Reactivity: Not reactive with most materials under normal conditions
Conditions to Avoid: Prolonged exposure to high temperature, direct sunlight
Incompatible Materials: Strong oxidizers, concentrated acids
Hazardous Polymerization: Will not occur
Corrosivity: Not corrosive to metals or tissue

Toxicological Information

Acute Toxicity: No known acute systemic toxicity in animal studies or human exposures
Skin Corrosion/Irritation: Possible mild irritation with prolonged contact
Eye Damage/Irritation: Possible temporary redness
Inhalation Effects: Excessive dust or heated fumes may cause mild respiratory irritation
Ingestion Effects: Very low toxicity; large quantities could cause gastrointestinal upset
Chronic Effects: No evidence of carcinogenicity, mutagenicity, or teratogenicity
Sensitization: Not known to cause sensitization
Medical Conditions Aggravated: Pre-existing skin or respiratory problems might worsen with exposure

Ecological Information

Ecotoxicity: Not acutely toxic to aquatic life in practical use scenarios
Biodegradability: Slowly biodegradable under natural conditions
Bioaccumulation: Little potential due to insolubility and molecular size
Mobility in Soil: Minimal, does not migrate in soil
Persistence: Degrades over months to years through physical and biological processes
Other Adverse Effects: No known effects on ozone layer, global warming potential, or photochemical smog

Disposal Considerations

Waste Generation: Minimize excess by precise process control; avoid unnecessary spills
Waste Disposal Method: Solid resin can be landfilled according to local regulations; incinerate if permitted by environmental authority
Contaminated Packaging: Rinse thoroughly before recycling or disposal; treat as industrial waste
Special Precautions: Prevent large amounts from entering waterways due to potential physical blockages
Hazardous Waste Classification: Not classified as hazardous waste under U.S. RCRA or most international norms

Transport Information

UN Number: Not regulated
Proper Shipping Name: Not applicable
Hazard Class: Not classified as dangerous for transport
Packing Group: Not applicable
Bulk Transport: Clean, labeled containers; avoid overheating
Special Precautions: Prevent excessive stacking; ensure containers are sealed
Marine Pollutant: No

Regulatory Information

OSHA Status: Not hazardous according to OSHA Hazard Communication Standard
TSCA Status: Listed
REACH Registration: Notified where required
Canadian DSL: Listed
Australian AICS: Listed
California Prop 65: No components listed
SARA 313: Does not contain listed chemicals
Right-to-Know (US – NJ, PA, MA): Not listed
Other Local Regulations: Check for regional chemical inventories and workplace safety codes