Naming a point in time when sorbitan monostearate entered the industrial chemistry scene takes us back to wider interest in emulsifiers and food additives during the mid-20th century. This molecule didn’t just stumble into tables and factories by accident. Food chemists and safety regulators looked for ways to stabilize blends that wouldn’t otherwise mix, and their search led to sorbitan monostearate. The sugar alcohol sorbitol, made through hydrogenation of glucose, and stearic acid, found in animal and vegetable fats, combined through esterification—a controlled reaction where water comes out and the two molecules merge. The result solved more than just a technical challenge; it built a new category of additive products, opening up safer and more reliable food processes.
Sorbitan monostearate stands out as a versatile emulsifier. Its structure carries both hydrophilic and lipophilic parts, allowing it to blend substances like oil and water that want nothing to do with each other. In practice, you’ll see this additive on ingredient lists in food, pharmaceuticals, and cosmetics. It offers more than convenience. Emulsifiers like sorbitan monostearate support the shelf life and appearance of products. Margarine, creamy spreads, whipped toppings, and even vitamin supplements depend on these molecules to avoid splitting and separation. The daily experience of a consumer often traces back to choices made by manufacturers that hinge on this emulsifier's reliability.
On the bench, sorbitan monostearate appears as a pale yellow waxy solid or powder. At room temperature, it holds a mild odor and smooth texture to the touch, with a melting point in the range of 50-55°C. Solubility tells an important story: it's almost insoluble in water but dissolves in warm oils and certain organic solvents. Its amphiphilic nature—the presence of both polar and non-polar regions—allows it to anchor itself along the boundary between phases in an emulsion, keeping droplets from merging. This property underpins every technical and commercial application.
Every kilogram of sorbitan monostearate that moves through supply chains carries a set of quality measures. Suppliers and regulators rely on standards such as those set by the Food Chemicals Codex or the European Food Safety Authority, which specify purity, acid value, saponification value, and residual solvent levels. On labels, food producers usually mark it as E491 in Europe or disclose it plainly in the United States, responding to consumer awareness and legal requirements. Knowing what to look for in ingredient lists and technical sheets informs not only purchasing decisions but also consumer advocacy and dietary choices, which have become more prominent conversations around additives in recent years.
Crafting sorbitan monostearate starts with two familiar ingredients: sorbitol and stearic acid. Technicians heat these under vacuum, often with a catalyst to speed up the reaction while removing water formed during the process. Careful monitoring is crucial because an incomplete reaction leaves unreacted sorbitol or excess stearic acid, which can change the taste, function, or even safety of the final product. Companies bring efficiency and reproducibility by using reactors suited to food-grade standards, and batches often undergo rigorous testing.
Chemists sometimes push sorbitan monostearate further by tweaking its structure with ethylene oxide to produce polysorbates, such as the common polysorbate 60. These derivatives behave differently—often more water-soluble—and expand the range of uses. Such modifications show how the original molecule acts as a building block, not just a finished product. Each tweak means changes in emulsifying power, physical stability, or the way the additive interacts with the other components in food, pharmaceuticals, or skin care products.
Sorbitan monostearate often wears many names depending on industry and geography. “Span 60” appears on many industrial product lists. Other descriptors include “sorbitan stearate” or “E491.” In regulatory circles or technical documents, each alias reflects not only chemical composition but also application focus. Recognizing these synonyms helps avoid confusion—especially when switching suppliers or reviewing international compliance documentation. These names can also flag differences in manufacturing process or source material, which matters for those with dietary or ethical preferences.
Any discussion about additives must address safety. Regulatory agencies have scrutinized sorbitan monostearate for decades. In food, it’s considered safe at standard concentrations, as supported by evaluations from organizations like JECFA (Joint FAO/WHO Expert Committee on Food Additives). Operators in manufacturing plants need to follow guidelines regarding dust inhalation and skin contact, as with any fine powder or solid additive. The additive’s history isn’t spotless: some studies raised questions over time, usually related to extremely high doses not feasible in typical diets. Care at the plant level, accurate dosing in production, and transparent reporting all play roles in long-term safety.
The reach of sorbitan monostearate goes far beyond food. In bakery applications, it makes dough softer and helps bread rise more evenly. Chocolatiers use it to temper chocolate, creating the glossy finish and satisfying snap found in high-quality confections. Non-food use matters too: manufacturers rely on it in creams, ointments, and emulsions for pharmaceuticals and personal care products. As an anti-static agent, it appears in plastics to reduce the cling of synthetic fibers or packaging. Each use case draws from the same basic ability to stand at the interface between incompatible materials and keep them together.
Ongoing research explores how sorbitan monostearate and its derivatives interact with other food ingredients, affect texture, or influence sensory experience for consumers. Scientists keep refining blends to lower costs or improve environmental profiles, such as moving away from animal-based stearic acid to plant-derived sources for vegan and kosher production. Novel encapsulation methods, nanoemulsions, and combination emulsifiers keep appearing in scientific journals and technical conferences, pushing the boundaries of what products can do and how they can perform under stress.
Toxicologists have reviewed the data on sorbitan monostearate exhaustively. At typical dosages used in foods and cosmetics, the molecule doesn’t build up in the body and breaks down into fatty acids and sorbitol, both of which are handled by standard metabolic pathways. Few allergic responses or acute reactions appear in the case literature. Problems emerge only under unrealistically high doses in animal studies, which don’t reflect consumer exposure. Ongoing vigilance remains important; additive safety never settles as final, with new findings sometimes arising from longer-term or more sensitive studies. Consumers, scientists, and manufacturers all benefit from access to up-to-date, peer-reviewed research in this space.
Looking to the future, industry leaders and researchers push to find cleaner production methods, sources that align with sustainability goals, or derivatives that support the trend in “clean label” products with fewer or more natural-sounding ingredients. As food systems move in step with climate and consumer priorities, the pressure mounts to trace every component’s origin and environmental footprint. Innovations may include biotechnological processes, upcycling techniques, or fusion with plant-based proteins. As regulatory scrutiny sharpens, maintaining clear and accurate communication with end users will help companies and regulators work together on safer and more transparent use of all food and industrial additives.
Sorbitan monostearate pops up on food labels and personal care products more often than most folks notice. It works as an emulsifier. That means it helps oil and water mix, keeping salad dressings creamy instead of separating, and chocolate smooth instead of blooming with white streaks. I’ve seen it as E491 on ice cream containers and in different types of cosmetics—it’s everywhere because it works.
Food makers use sorbitan monostearate to tackle problems that frustrate people at home: Think about melted butter sitting in a pool of water, or peanut butter that never mixes right. This ingredient cuts out that mess. In bread, it keeps crumbs soft longer. In cake mixes, it stops fat from rising and keeps the cake tender for several days. If you ever wondered why store-bought bakery goods last longer on shelves, chances are an emulsifier like this plays a big part.
Beyond food, you find it in lotions and creams. It makes products glide onto skin without leaving that heavy, greasy feeling. Shampoos and conditioners use a touch of it, too, to blend ingredients that would otherwise separate. I once noticed a cheap brand of moisturizer started feeling grainy compared to my usual. A quick look at the ingredients label showed the cheaper one didn’t use this kind of emulsifier.
Sorbitan monostearate comes from sorbitol and stearic acid. Sorbitol occurs naturally in fruits like apples and pears, and stearic acid is a type of fat found in vegetable oils and animal fat. These are processed and combined to make the compound used in food and cosmetics. People with allergies to certain sources or who practice strict vegan eating want to know where the raw materials come from. Most big food producers use plant-based inputs, but some might not. If the origin matters, checking with the manufacturer or looking for vegan labeling helps.
The Food and Drug Administration, along with safety agencies in the EU, Canada, and Australia, allow sorbitan monostearate in food and cosmetics within certain limits. The European Food Safety Authority reviewed studies and found no risk at normal consumption levels. As with any ingredient, moderation is key. No evidence links reasonable intake to health issues for most people, though someone with rare conditions should check with a medical provider.
One concern about food additives is the idea that “processed” equals bad. I get it. Folks feel wary when ingredient lists run long or use chemical-sounding names. The best move is to read labels and keep processed foods as a smaller part of meals. European organic standards ban several emulsifiers, pushing food makers to find natural alternatives like lecithin from eggs or soy, or certain fibers like guar gum. Those substitutes can change the texture or taste, so some products use a blend to get the right mouthfeel.
For people with allergies or on diets for religious or ethical reasons, direct manufacturer information offers the clearest path. Products labeled “vegan” or “allergy-friendly” usually lean on plant sources.
Sorbitan monostearate doesn’t get headlines, but it quietly works behind the scenes to improve foods and everyday products. Being informed helps sort the useful from the hype. Clear food labeling and honest marketing mean shoppers can decide what they want in their homes and on their tables.
Sorbitan monostearate shows up in a variety of processed foods you might find in any grocery store. This waxy substance acts as an emulsifier, keeping ingredients like oil and water from separating in products like margarine, baked goods, chocolate, and coffee creamers. If you check an ingredient label and spot E491, that’s it. Seeing strange names like this tends to make people uneasy, but something sounding like a chemistry set doesn’t automatically spell danger.
Both the U.S. Food and Drug Administration (FDA) and the European Food Safety Authority (EFSA) have reviewed the scientific studies on sorbitan monostearate. Both agencies classify it as generally recognized as safe for use in food. This status does not come lightly. The agencies rely on research exploring possible effects on the human body at normal consumption levels. Studies have not turned up evidence that sorbitan monostearate causes harm when eaten as part of a typical diet.
People ask questions about what constant exposure to food additives might do. Chronic exposure to small quantities of many food additives feels like rolling dice with your long-term health. Some studies in animals have looked for cancer risks or problems with reproduction, but the data don’t reveal real problems at the amounts people typically eat. For anyone with food allergies or digestive conditions, it’s always smart to scan food labels and keep an eye on any unusual symptoms, though sorbitan monostearate doesn’t rank as a common allergen.
Many food ingredients seem harmless on paper but interact with our bodies in ways we don’t fully understand yet. My own family tries to eat more foods that come with simple labels and fewer additives. There’s comfort in knowing exactly what goes into your meals. Still, it’s difficult to avoid additives completely unless you make everything at home from scratch, which isn’t realistic for most people living busy lives. People want their food to last longer, taste better, and look appealing; sorbitan monostearate plays a role here. Sometimes, it helps cut costs and reduce waste, making food more affordable and less likely to spoil on shelves. That said, convenience shouldn’t override health, and the push for cleaner ingredients won’t go away anytime soon.
Consumers eager to steer clear of additives can prioritize whole foods—fruits, vegetables, unprocessed grains, and fresh proteins. Cooking at home brings more control. On the regulatory side, food safety watchdogs continue to monitor new research and adjust recommendations as more evidence appears. The scientific method means never closing the door on new data, so agencies review old rulings as new studies get published.
Clearer food labels would make life easier for shoppers. When companies make ingredient lists readable and keep unnecessary additives out, everybody wins. Food makers can explore natural alternatives, experiment with traditional recipes, and work closely with nutrition experts to develop products that put both quality and safety front and center. Personal judgment plays a role too. Knowing which processed foods fit within individual health goals and comfort zones means you get to decide what belongs in your cart—and on your plate.
Sorbitan monostearate shows up on many ingredient lists in foods from margarine to chewing gum to some coffee creamers. People often trust these products without digging much further than the nutrition label. After talking to dietitians and manufacturers, something became clear: the real answer about its vegan or vegetarian status doesn't fit on that little label.
Manufacturers make sorbitan monostearate from two basic things: sorbitol and stearic acid. Sorbitol comes from plant starch — most often corn or wheat. The real question comes down to stearic acid. Here’s where things get muddy. Companies can source stearic acid from animal fats or from vegetable oils. Animal sources often use tallow, a product of animal fat processing. Vegetable sources usually come from palm or coconut oils.
I used to believe that if a product said "vegetable-derived," it settled things. Reality looks different. Food companies rarely disclose their fatty acid source unless pressed by consumers. Some call or email for details, but answers sometimes just repeat marketing lines. Industry standards don’t force companies to clearly label every source, so shoppers play a guessing game.
With global supply chains spreading across several countries, batch-to-batch variations can even change ingredients depending on cost and availability. What counted as vegan last year sometimes isn’t this year. This lack of transparency frustrates consumers trying to make food choices that fit their values.
Assuming something is vegan or vegetarian because it’s used in processed foods, or because the name sounds technical, can land someone in a spot they never intended. Anyone avoiding animal products for ethical reasons deserves clearer answers than the current system gives.
Some groups keep running lists of "safe" emulsifiers, but these lists sometimes rely on outdated information. Products sold under different brands or in different countries use the same name but not always the same ingredients. People deserve better than detective work during grocery runs.
Over the last few years, buyers asking hard questions about sourcing have nudged some brands toward clearer labeling. Vegan certifications carry real meaning because a third party verifies every source. Ingredient transparency can’t happen unless companies see that shoppers want it, and will pick a different box or bottle without it.
People who care about vegan or vegetarian ingredients can keep pushing for meaningful change — not just for sorbitan monostearate, but for everything that lands on the plate. Make a call. Write an email. Choose certified products. Every label change traces back to customers demanding to know, not just trusting the system. That effort eventually helps other people who also want to avoid animal products for ethical, environmental, or health reasons.
If getting a straight answer matters to you, look for brands with clear vegan or vegetarian certifications. Ask questions of manufacturers, even if it takes a few rounds to get a direct reply. Some supermarkets share ingredient sourcing with interested customers — though it isn't always in the open on the shelf. Until food labeling standards get tighter, educated and vocal consumers can move the needle for everyone.
Plenty of people scan ingredient lists these days, watching for things they can’t pronounce or figure out. Sorbitan monostearate falls into this camp. Walking down supermarket aisles, it crops up in more foods than most realize. It isn’t some mysterious chemical whipped up in secret—it’s a food additive that creates smoother, more appealing textures in processed foods. People rarely talk about it, but this single ingredient shapes how bread stays soft, chocolate remains glossy, and desserts turn out creamy.
Let’s get specific. Sorbitan monostearate shows up in foods that need improved texture or longer shelf lives. Bakers use it in breads, cakes, and even tortillas. Ever wondered why some bread feels pillow-soft for days? That’s the handiwork of additives like sorbitan monostearate. You’ll spot it in flavored creams, cake frostings, and packaged donuts, keeping everything moist and palatable long past home-baked freshness.
Ice cream and frozen desserts need help to prevent icy chunks or excess frost. Commercial producers add sorbitan monostearate so ice crystals don’t get out of hand. Next time you enjoy a scoop from your favorite brand, there’s a good chance this emulsifier worked behind the scenes. The same goes for pudding cups and creamy yogurts piled high with fruit. In processed cheese slices, it battles oil and water so bites deliver a consistent taste.
I grew up packing lunch sandwiches and picking candies at the corner store. Looking back, packaged chocolates—bars, bonbons, anything that shouldn’t melt in your hand—rely on sorbitan monostearate to achieve that satisfying snap and glossy finish. Even chewing gum sometimes contains it, helping flavors distribute evenly with each chew.
Mass-produced foods sit on trucks, shelves, and in lunchboxes long before anyone eats them. To keep foods from crumbling, separating, or drying out, processors reach for reliable emulsifiers. Sorbitan monostearate stabilizes mixtures that usually fight to separate. In margarine and whipped toppings, it guarantees a smooth spread. Salad dressings—especially creamy or “lite” styles—use it to stop ingredients from splitting into a gloppy mess.
It pops up in powdered drink mixes too. I remember mixing up instant chocolate milk as a kid and never thinking about what made the powder dissolve evenly—additives like this one mean you don’t end up with mysterious clumps at the bottom of your cup.
A lot of consumers raise eyebrows at complex-sounding ingredients. Regulatory agencies like the US Food and Drug Administration and the European Food Safety Authority have agreed it’s generally safe to eat in moderate amounts. Still, its presence highlights a bigger trend in processed foods. The more additives go into supermarket staples, the farther we drift from relying on simple home-cooked meals with ingredients anyone can recognize.
Keeping an eye on how often you eat ultra-processed foods matters. Additives like sorbitan monostearate help get foods from factories to store shelves looking and tasting great, but they won’t bring the same nutritional value as fresh or minimally processed options. Cooking at home, reading ingredient lists, and varying your diet go a long way in managing your exposure—not just to this additive, but to the many others lurking in packaged goods.
Sorbitan monostearate crops up in a lot of places. Many people don’t recognize the name, but you’ll spot it in breads, chocolates, ice creams, chewing gum, cosmetics, and even vitamin supplements. The job of this additive is straightforward—it keeps oil and water from parting ways. It stops salad dressings from separating, helps chocolate bars stay smooth, and makes makeup less greasy.
Families notice weird ingredients on ingredient lists now more than ever. I’ve been there, squinting at the back of snack packages, wondering what long words actually do once inside the body. Sorbitan monostearate comes from sorbitol (a sugar alcohol) and stearic acid, usually derived from animal fat or vegetable oil. The U.S. Food and Drug Administration says this ingredient is “generally recognized as safe” in the small amounts used in food. Food safety authorities in the European Union only let companies use it when it doesn’t exceed certain limits.
Most people won’t notice a thing after eating something with sorbitan monostearate. That doesn’t make everyone feel comfortable, especially with so much talk about ultra-processed foods. Research points out that this additive doesn’t cause big problems for most people. Still, large doses can cause digestive issues—think bloating, gas, or mild cramping—since it’s based on sugar alcohol.
Lab tests in animals given huge amounts don’t reveal dangerous long-term effects. Most adults would have to eat far more than a typical diet just to feel any impact. Allergy reports linked to sorbitan monostearate are extremely rare, but a handful of people share that it makes their eczema flare up or causes hives.
Plenty of people ask why strange-sounding chemicals land up in family meals in the first place. Additives stretch shelf life, improve texture, and help with large-scale food production. Some of us try to avoid unfamiliar ingredients, choosing foods with labels we can pronounce in a pinch. Others aren’t fazed, leaning on guidance from health professionals.
Dieticians still encourage eating less processed food overall. Sadly, many people—especially in busy households—find it tough to avoid packaged food. If digestive issues come up after eating a certain food, jotting down what you’ve eaten helps narrow down triggers. Doctors and nutritionists can work with that info to spot patterns.
We live in a world packed with information and just as many rumors. Confusion about food chemicals comes up all the time. Peer-reviewed studies and science-backed sources, like the European Food Safety Authority and the U.S. FDA, both show routine amounts of sorbitan monostearate don’t pose clear dangers. Still, a lot changes as new research rolls out.
Instead of worrying about every last additive, keeping a balanced diet and reading labels does more for health than stressing over each ingredient. Watching portion sizes, eating more whole foods, and knowing where food comes from puts control back in families’ hands. For those with sensitivities or allergies, sharing symptoms with their healthcare provider leads to peace of mind and tailored advice.
Sorbitan monostearate usually goes unnoticed and untroubled in most people’s diets. The real power comes from choosing whole foods, asking good questions, and turning small changes into lasting habits.
| Names | |
| Preferred IUPAC name | Sorbitan stearate |
| Other names |
Span 60 Sorbitan stearate Glycol stearate monoester Sorbitan monooctadecanoate E491 |
| Pronunciation | /ˈsɔːr.bɪ.tæn ˌmɒn.əʊˈstɪə.reɪt/ |
| Preferred IUPAC name | (2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl octadecanoate |
| Other names |
Span 60 Sorbitan stearate Sorbitan monooctadecanoate |
| Pronunciation | /ˈsɔːrbɪtæn ˌmɒn.oʊˈstiːəreɪt/ |
| Identifiers | |
| CAS Number | 1338-41-6 |
| Beilstein Reference | 89054 |
| ChEBI | CHEBI:5355 |
| ChEMBL | CHEMBL1207272 |
| ChemSpider | 11745 |
| DrugBank | DB11160 |
| ECHA InfoCard | 100.034.255 |
| EC Number | EC 212-790-3 |
| Gmelin Reference | 81688 |
| KEGG | C14427 |
| MeSH | D013512 |
| PubChem CID | 5369487 |
| RTECS number | WL3450000 |
| UNII | EN2LO0199Q |
| UN number | UN number: "UN3257 |
| CompTox Dashboard (EPA) | urn:cmpd:DTXSID7020150 |
| CAS Number | [1338-41-6] |
| Beilstein Reference | 1630723 |
| ChEBI | CHEBI:53428 |
| ChEMBL | CHEMBL1507821 |
| ChemSpider | 12767 |
| DrugBank | DB11102 |
| ECHA InfoCard | 100.245.760 |
| EC Number | EC 201-783-9 |
| Gmelin Reference | 114774 |
| KEGG | C14635 |
| MeSH | D020245 |
| PubChem CID | 5363244 |
| RTECS number | WGK3 |
| UNII | KGM4W2QGS8 |
| UN number | UN 3082 |
| CompTox Dashboard (EPA) | UQ9I9Y6OEC |
| Properties | |
| Chemical formula | C24H46O6 |
| Molar mass | 430.62 g/mol |
| Appearance | White to yellowish waxy solid or beads |
| Odor | Characteristic |
| Density | 1.03 g/cm3 |
| Solubility in water | insoluble |
| log P | 2.8 |
| Vapor pressure | Negligible |
| Acidity (pKa) | > 7.8 |
| Basicity (pKb) | 15.7 |
| Magnetic susceptibility (χ) | Diamagnetic |
| Refractive index (nD) | 1.463 |
| Viscosity | Viscous liquid or semi-solid |
| Dipole moment | 2.92 D |
| Chemical formula | C24H46O6 |
| Molar mass | 430.62 g/mol |
| Appearance | White to off-white powder or flake |
| Odor | Odorless |
| Density | 1.03 g/cm³ |
| Solubility in water | Insoluble |
| log P | log P: 6.8 |
| Vapor pressure | Negligible |
| Basicity (pKb) | 7.7 |
| Magnetic susceptibility (χ) | -73.5e-6 cm³/mol |
| Refractive index (nD) | 1.453 |
| Viscosity | Viscous liquid |
| Dipole moment | 2.12 D |
| Thermochemistry | |
| Std molar entropy (S⦵298) | 1084.6 J·mol⁻¹·K⁻¹ |
| Std enthalpy of formation (ΔfH⦵298) | -1200.7 kJ/mol |
| Std enthalpy of combustion (ΔcH⦵298) | -16820.7 kJ/mol |
| Std molar entropy (S⦵298) | 1064.6 J·mol⁻¹·K⁻¹ |
| Std enthalpy of formation (ΔfH⦵298) | -1610.7 kJ/mol |
| Std enthalpy of combustion (ΔcH⦵298) | -17600 kJ/mol |
| Pharmacology | |
| ATC code | A06AD18 |
| ATC code | A06AD18 |
| Hazards | |
| Main hazards | May cause mild skin and eye irritation. |
| GHS labelling | GHS07 |
| Pictograms | GHS07 |
| Signal word | Not classified |
| Hazard statements | No hazard statements. |
| NFPA 704 (fire diamond) | 1-1-0 |
| Flash point | > 182.8 °C (361 °F) |
| Autoignition temperature | 310°C |
| Lethal dose or concentration | LD50 (Rat, oral): > 25,000 mg/kg |
| LD50 (median dose) | LD50 (median dose): Rat oral 34,600 mg/kg |
| NIOSH | FH1575000 |
| PEL (Permissible) | Not established |
| REL (Recommended) | Not more than 10,000 mg/kg |
| Main hazards | May cause mild skin and eye irritation. |
| GHS labelling | GHS labelling for Sorbitan Monostearate: Not classified as hazardous according to GHS; no pictogram, signal word, hazard statement, or precautionary statement required. |
| Pictograms | GHS07 |
| Signal word | No signal word |
| Hazard statements | No hazard statements. |
| Precautionary statements | P264, P270, P301+P312, P305+P351+P338, P337+P313 |
| NFPA 704 (fire diamond) | 1-1-0 |
| Flash point | 182 °C |
| Autoignition temperature | ~340 °C |
| Lethal dose or concentration | LD50 (Rat, oral): > 25,000 mg/kg |
| LD50 (median dose) | > LD50 (median dose): Rat oral > 25,000 mg/kg |
| NIOSH | TR4439100 |
| PEL (Permissible) | Not established |
| REL (Recommended) | Up to 25 mg/kg bw |
| Related compounds | |
| Related compounds |
Sorbitan tristearate Sorbitan monooleate Sorbitan monolaurate Stearic acid Sorbitol |
| Related compounds |
Stearic acid Sorbitan monooleate Polysorbate 60 Sorbitan tristearate Sorbitan monolaurate |