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Sodium Erythorbate: Material Safety Data Sheet (MSDS)

Identification

Product Name: Sodium Erythorbate
Chemical Formula: C6H7NaO6
Synonyms: Erythorbic acid, sodium salt
CAS Number: 6381-77-7
Recommended Use: Antioxidant in food processing, corrosion inhibitor, shelf-life enhancer
Manufacturer Information: Refer to supplier for address and contact details
Emergency Contact: Reference local regulations or supplier for emergency response number

Hazard Identification

Classification: Not classified as hazardous according to OSHA or EU standards for most uses
Potential Health Effects: Inhalation can irritate respiratory tract; skin contact might cause mild irritation; eye contact typically stings; ingestion causes mild gastrointestinal upset in excess
GHS Label Elements: May include minimal precautionary statements; not a significant chemical hazard under normal conditions
Environmental Impact: Not classified as environmentally hazardous
Specific Hazards: Combustible under strong heat; produces irritating and toxic gases if decomposed by fire
Signal Word: None required for non-industrial handling

Composition / Information on Ingredients

Chemical Name: Sodium erythorbate
Concentration: Typically 99% or greater
Impurities: Minor traces of inorganic salts or related compounds
Additives: Not generally formulated with additional chemicals
Ingredient Statement: Pure chemical substance; always check batch certificate for exact composition

First Aid Measures

Inhalation: Move person to fresh air; seek medical attention for persistent cough or irritation
Skin Contact: Wash affected skin with soap and plenty of water; remove contaminated clothing
Eye Contact: Rinse eyes thoroughly with water for at least 15 minutes; seek medical help if irritation remains
Ingestion: Rinse mouth, drink water; seek medical advice if large quantities consumed or discomfort occurs
Most Important Symptoms: Mild irritation of skin, eyes, or respiratory tract; no severe symptoms expected in routine use
Notes for Physicians: Symptomatic and supportive care, no specific antidote

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, carbon dioxide, dry powder
Unsuitable Media: Avoid high-pressure water jets for large fires
Specific Hazards from Fire: Combustion releases carbon oxides and sodium compounds; heat may cause decomposition
Protective Equipment: Firefighters should use standard protective gear and self-contained breathing apparatus
Fire-Fighting Procedures: Fight fire from a safe distance; prevent runoff from entering drains or watercourses

Accidental Release Measures

Personal Precautions: Use dust masks and goggles; avoid raising dust
Environmental Precautions: Sweep up material to prevent entry into water systems
Collection Methods: Collect with a dry shovel into sealed containers; dispose according to regulation
Cleanup Procedures: Ventilate area, wash spill site under local regulations
Decontamination: Clean up with water if residue remains

Handling and Storage

Handling: Avoid inhaling dust, direct contact with skin, or eyes; use with adequate ventilation; follow good hygiene practices
Storage Conditions: Store in a cool, dry, ventilated space away from strong acids, alkalis, and oxidizers
Packaging: Use sealed containers to limit moisture and contamination
Storage Stability: Stable under recommended conditions; keep container tightly closed
Other Precautions: Regularly check containers for leaks or degradation; label clearly for safe identification

Exposure Controls and Personal Protection

Occupational Exposure Limits: Not established for sodium erythorbate
Engineering Controls: Local exhaust or general room ventilation
Personal Protective Equipment (PPE): Safety glasses, gloves, dust mask, and appropriate clothing in cases of frequent or bulk handling
Hygiene Measures: Wash hands after use; remove contaminated clothing and equipment before eating
Respiratory Protection: For dusty operations, use NIOSH/MSHA-approved respirators as needed

Physical and Chemical Properties

Appearance: White to slightly yellow crystalline powder
Odor: Odorless or faint chemical scent
pH (1% Solution): 6.5–8.0
Melting Point: Decomposes above 220°C
Solubility: Easily dissolves in water; practically insoluble in alcohol
Relative Density: About 1.2 g/cm³
Boiling Point: Not applicable (decomposes before boiling)
Vapor Pressure: Negligible
Flash Point: Not flammable under standard conditions
Partition Coefficient (Log Kow): Not significant for practical purposes

Stability and Reactivity

Chemical Stability: Stable under standard temperatures and pressures in closed containers
Incompatibility: Strong oxidizers, strong acids, and alkalis may cause degradation
Conditions to Avoid: High temperature, humidity, exposure to open air
Hazardous Decomposition Products: Carbon oxides, sodium oxides, possible irritating fumes
Polymerization: Not expected under normal conditions

Toxicological Information

Acute Toxicity: Low acute toxicity by oral, dermal, or inhalation routes in animal studies
Skin Corrosion/Irritation: Mild or no irritation
Eye Damage/Irritation: Temporary irritation if contacted
Respiratory Effects: Dust inhalation may cause coughing or slight throat irritation
Long-Term Exposure: No known carcinogenic, mutagenic, or reproductive hazards in humans
Additional Data: Generally recognized as safe (GRAS) when used in food, based on FDA evaluation

Ecological Information

Ecotoxicity: No significant risk for aquatic or terrestrial organisms at normal concentrations
Persistence and Degradability: Readily biodegradable in environment
Bioaccumulation: Does not accumulate in living organisms
Mobility: Water soluble; disperses readily if spilled
Other Adverse Effects: No known adverse effects on the ecosystem at the quantities typically used

Disposal Considerations

Product Disposal: Dispose through licensed waste handler using landfilling or incineration if no other method available
Container Disposal: Rinse empty containers and recycle or dispose following local regulations
Special Precautions: Prevent large quantities from entering drains, surface water, or soil
Regulatory Notes: Not a hazardous waste under U.S. RCRA; always check local and national rules

Transport Information

UN Number: Not classified under international regulations
Proper Shipping Name: Sodium erythorbate
Transport Hazard Class: Not regulated
Packing Group: None assigned
Labels: No hazard labels needed
Special Precautions: Ship in dry, sealed packaging; avoid exposure to high heat or humidity
Marine Pollutant: Not designated as a marine pollutant

Regulatory Information

US Regulations: Generally Recognized As Safe (GRAS) for food under FDA 21CFR182.3041
EU Classification: Not classified as dangerous under Regulation (EC) No 1272/2008
Global Inventories: Listed on TSCA, EINECS, DSL, AICS, ENCS, and other major inventories
Workplace Labelling: Comply with OSHA communication standards; use clear chemical labels
Other Provisions: Food industry should verify compliance with national and international food safety/certification bodies; follow local occupational health standards