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Material Safety Data Sheet: Sodium Aluminium Phosphate (SALP)

Identification

Product Name: Sodium Aluminium Phosphate
Other Names: SALP; Sodium Aluminum Phosphate; Food Additive E541
Recommended Use: Food processing (mainly as a leavening agent in baked goods), chemical manufacturing
Chemical Formula: NanAlmHx(PO4)y
CAS Number: 7785-88-8
Supplier Details: Refer to specific supplier for address and contact information
Emergency Phone: Refer to supplier information or local poison control

Hazard Identification

GHS Classification: Not classified as hazardous according to GHS
Main Hazards: Inhalation and ingestion can irritate mucous membranes, eyes, and skin. Contact with fine dust may worsen preexisting respiratory problems. Consuming large quantities can impact bone health.
Pictograms: None required for food-grade SALP
Signal Word: None
Hazard Statements: May cause mild irritation to skin, eyes, and respiratory tract
Precautionary Statements: Avoid breathing dust, wash hands thoroughly after handling, avoid eating or smoking when handling the product

Composition / Information on Ingredients

Chemical Identity: Sodium Aluminium Phosphate
Content: Typically 98-100% by weight
Impurities: Trace amounts of sodium phosphate, aluminum phosphate, naturally occurring minerals
Molecular Weight: Varies by specific formulation (most common: NaH14Al3(PO4)8, MW ~712 g/mol)

First Aid Measures

Eye Contact: Rinse with plenty of water for several minutes while holding eyelids apart. Remove contact lenses if easy to do so. If irritation persists, get medical advice.
Skin Contact: Wash with soap and water. Remove contaminated clothing. If redness or discomfort continues, seek medical care.
Inhalation: Move person to fresh air. Support breathing as needed. If symptoms (cough, shortness of breath) develop, seek medical attention.
Ingestion: Rinse mouth thoroughly. Drink water to dilute if victim is conscious. Do not induce vomiting. Get medical attention if a large amount is swallowed or if symptoms appear.

Fire-Fighting Measures

Suitable Extinguishing Media: Use water, carbon dioxide, foam, or dry chemical extinguishers. Product itself is not flammable, but packaging may burn.
Specific Hazards: Thermal decomposition releases irritating or toxic fumes such as sodium oxides, phosphorous oxides, and aluminum oxides.
Protective Equipment: Firefighters wear self-contained breathing apparatus and protective suits in heavily contaminated areas.
Special Precautions: Avoid dispersing dust into the air. Prevent runoff from entering drains or water courses.

Accidental Release Measures

Personal Precautions: Use dust mask, gloves, and protective goggles. Avoid breathing dust. Ensure good ventilation.
Clean-Up Methods: Sweep up using method to minimize dust production. Collect and place in suitable container for disposal. Wash spill area with water.
Environmental Procedures: Prevent product from entering drains, sewers, and water ways. Avoid releases to the environment.

Handling and Storage

Handling: Use only in well-ventilated areas. Avoid dust generation and inhalation. After handling, wash hands and remove contaminated clothing.
Storage: Store product in a dry, cool, well-ventilated area. Keep containers closed to avoid moisture uptake and contamination. Protect from direct sunlight, acidic environments, and incompatible substances (strong acids and alkalis).

Exposure Controls and Personal Protection

Engineering Controls: Use local exhaust ventilation or process enclosure to control airborne dust. Facilities for eye washing and washing hands should be available.
Exposure Limits: OSHA/NIOSH do not specify limits for SALP, but nuisance dust limits (15 mg/m3 total dust, 5 mg/m3 respirable) apply.
Personal Protective Equipment: Wear dust proof goggles or safety glasses, gloves, and dust mask (N95 or equivalent). Use full cover work clothing.
Hygiene Measures: Do not eat, drink, or smoke in work area. Wash hands after handling and before meals.

Physical and Chemical Properties

Appearance: White or off-white, fine powder
Odor: Odorless
pH (1% solution): 8.0 – 9.5
Solubility in Water: Slightly soluble (varies by grade and formulation)
Melting Point/Freezing Point: Decomposes at >150°C
Boiling Point: Not applicable
Flash Point: Not flammable
Vapor Pressure: Not applicable
Density: Approximately 2.5 – 2.7 g/cm3
Other Data: Stable under normal conditions

Stability and Reactivity

Chemical Stability: Stable in ambient temperature and recommended storage conditions
Conditions to Avoid: Exposure to moisture, humidity, and strong acidic or basic environments
Incompatible Materials: Strong acids, strong bases
Hazardous Decomposition Products: Sodium oxides, aluminum oxides, phosphorus oxides under heated conditions
Polymerization: Will not occur

Toxicological Information

Acute Toxicity: Low acute oral toxicity, estimated LD50 (rat) >2000 mg/kg
Skin/Eye Contact: Can cause temporary eye and skin irritation
Inhalation: Dust can irritate respiratory tract. Prolonged inhalation may aggravate respiratory diseases.
Chronic Effects: No known carcinogenic, mutagenic, or reproductive toxicity found in standard studies. Prolonged high intake of phosphates and aluminum compounds may affect bone and kidney function.
Sensitization: Not classified as a sensitizer

Ecological Information

Ecotoxicity: Not expected to be dangerous to aquatic or terrestrial organisms at typical concentrations.
Mobility: Insoluble in water, settles in soil and water bodies
Persistence and Degradability: Inorganic material—does not degrade but may become part of the natural phosphorus cycle
Bioaccumulation: Not likely to bioaccumulate due to low solubility
Other Adverse Effects: High concentrations may cause eutrophication in sensitive water bodies

Disposal Considerations

Product Disposal: Dispose of unused material as non-hazardous waste in accordance with local, state, and federal regulations. Avoid release into the environment.
Container Disposal: Containers and packaging should be emptied and sent for recycling or disposal according to government requirements.
Waste Treatment: Physically separate from domestic waste; do not wash into sewers or natural water courses.

Transport Information

UN Number: Not regulated for transport
UN Proper Shipping Name: Not regulated
Transport Hazard Class: Not hazardous
Packing Group: None
Special Precautions: Prevent physical damage to packaging. Avoid generating dust during transport and unloading.

Regulatory Information

TSCA Status: Listed on the US Toxic Substances Control Act inventory
Food Additive Approval: Approved by FDA for use as a food additive (21 CFR 182.1781, 21 CFR 182.1787)
WHMIS Classification (Canada): Not controlled
REACH Status (EU): Exempt as food additive
SARA Title III: Not subject to reporting requirements
Right to Know: Listed in state and national chemical inventories as sodium aluminium phosphate