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Reduced Iron: A Practical Look at Its Past, Present, and Future

Historical Development

Long before skyscrapers cut across city skylines and factories hummed with machines, artisans and blacksmiths worked with iron that bore a much slower pace—produced by heating ore using charcoal, pulling metal from stone with patience and sweat. Reduced iron, or sponge iron, traces its roots to those early blast furnaces and bloomery hearths, where direct ironmaking shaped swords, plows, and the foundation of modern infrastructure. Unlike pig iron, which appeared with the blast furnace, reduced iron methods offered a more basic, low-carbon output, letting early civilizations take advantage of a metal that could be forged into nearly anything. Steelmaking giants around the world still rely on direct reduced iron (DRI) processes born from advances in the 20th century as pollution controls, energy efficiency, and feedstock availability shaped metal markets. Walk into industrial zones in India, the Middle East, or Latin America and you’ll find clusters of rotary kiln and shaft furnace plants that keep this legacy alive, adapting as resource pressure and climate targets raise the bar every decade.

Product Overview

Reduced iron carries less carbon than most forms of processed iron, earning a place as a clean, solid feedstock for electric arc furnaces where scrap faces impurities or fluctuating supply. Producers usually refer to it as direct reduced iron, DRI, or sometimes sponge iron, thanks to its porous texture. These iron pellets or lumps result from removing oxygen from iron ore at temperatures lower than those needed for melting. Supply chains often run across continents, connecting miners in Australia or Brazil, gas-rich countries utilizing natural gas for reduction, and steel plants seeking to wean themselves from coal.

Physical & Chemical Properties

Reduced iron’s biggest tell is its spongy, porous structure—light gray, brittle, and practically a sieve for moisture and oxygen if left unattended. Compress a handful and dust coats your palm. This texture results from incomplete sintering, leaving behind a decent specific surface area. Composition runs heavy on iron, generally around 90% or higher by weight, with traces of silica, alumina, and a smattering of other residual minerals. Unlike traditional pig iron, the product holds only a fraction of the carbon—often between 0.01% and 2%—sidestepping many issues linked with steel cleanliness downstream. Oxygen, not completely driven off, hovers below 2%, while sulfur and phosphorus can sneak through depending on ore quality and process controls.

Technical Specifications & Labeling

Labels for reduced iron rarely leave out two basics: iron content and metallization. The former tells buyers how much pure iron they’re getting, usually reported above 90%, while metallization measures how thoroughly the iron oxide ore has been stripped of oxygen. Well-made DRI clocks in at metallization rates over 92%. Agglomerate size, typically around 6 to 18 mm, matters too, especially for feedstock handling and melt efficiency. Global standards such as ISO 10835 and the American Iron and Steel Institute provide the backbone for what buyers expect to see, laying out everything from allowable impurity levels to moisture and density. Storage, transport, and emergency procedures find a place on product documents, pushed by the fire and reactivity risks that sometimes haunt oxidized iron materials. A mistake here turns shipping containers into fire hazards—a lesson modern suppliers take very seriously.

Preparation Method

Iron ore doesn’t just turn into reduced iron by luck. Operators run carefully chunked ore through rotary kilns, fluidized beds, or fixed shaft furnaces at roughly 800–1100°C, avoiding complete fusion. Instead of coke, reducing gases—often hydrogen and carbon monoxide stripped from natural gas—react with the ore, snatching away oxygen and leaving behind porous iron. Natural gas-based reduction dominates, but coal-based rotary kilns and emerging hydrogen-fired systems claim a growing share of the market. Over the past decade, careful control of pressure, residence time, and temperature profiles allows operators to tweak output for downstream steelplant needs. Off-gases are recycled or cleaned to minimize emissions, a far cry from the smokestacks of old.

Chemical Reactions & Modifications

Inside the reactors, the big show boils down to the reduction of Fe2O3 (hematite) or Fe3O4 (magnetite) with carbon monoxide and hydrogen. At core, reactions strip away oxygen like this: Fe2O3 + 3CO → 2Fe + 3CO2 or Fe2O3 + 3H2 → 2Fe + 3H2O. Switch fuels and the chemistry shifts, but the goal stays the same—free iron with as little carbon and sulfur as possible. Some plants tweak basic DRI after production, coating it with carbon to improve melting in electric arc furnaces or compacting it into hot briquetted iron (HBI), which ships more safely and resists re-oxidation. Research in green steel leans toward hydrogen as a reducer, which slashes CO2 emissions and sets the stage for truly low-carbon metals production.

Synonyms & Product Names

Step into trade markets and you’ll hear reduced iron described by a handful of names. Direct reduced iron, DRI, sponge iron, and—when compacted—hot briquetted iron, HBI, stand out as the most common tags in bills of lading and technical specs. In some circles, metallized iron ore or pre-reduced iron also show up, but rarely lead major contracts outside technical documents. Producers love their local branding, though, so names can reflect company, process, or even locale, causing the occasional confusion on international shipments. For the working metallurgist or purchasing officer, iron content and shipping condition matter more than what’s printed on the bag.

Safety & Operational Standards

Safety issues with reduced iron often haunt anyone touching powdery or porous metal. Fresh DRI, if wet or exposed to humid air, can heat up dangerously through oxidation—a recipe for self-ignition in ship holds or warehouses. Ships carrying DRI need strict safety protocols, as detailed in the International Maritime Solid Bulk Cargoes (IMSBC) Code, to guard against fires or asphyxiating gases. On the job site, workers watch for dust explosions and the quirks of handling reactive, sometimes pyrophoric, metal. Fire risk management rests on dry storage, fast shipping, and strict air exclusion, drawing on lessons from costly shipping incidents of the past few decades. Industry standards back up these practices, pushing companies to invest in monitoring, well-trained teams, and risk audits as part of routine operations.

Application Area

The workhorse for reduced iron sits inside electric arc furnaces and induction furnaces, providing steady iron units where scrap alone can’t hack it for quality or consistency. Foundries blend DRI with scrap to lift yield and tamp down impurities, especially in alloy and specialty steel. Some chemical industries use reduced iron for hydrogen production or as a reducing agent, though these markets pale beside steelmaking. Pellet plants and DRI modules close to ports or gas fields ship straight into global value chains, feeding customers from rebar mills in Turkey to pipe producers in Iran. As emissions standards tighten, plants using DRI instead of coke-based blast furnaces score points with regulators, nudging steel toward a lower-carbon future.

Research & Development

Research labs and steel majors invest time and cash in pushing reduced iron further—chasing better energy use, cleaner output, and smarter integration with scrap streams. Hydrogen-based reduction has moved from concept to pilot to limited commercial operation in countries like Sweden, offering a glimpse at fossil-free steel if renewable electricity can keep up. Studies probe changes in ore composition, new catalysts, and smarter reactor designs to lift yield and cut cost. Academics dig into nano-scale properties, seeking pathways to higher-end alloys or cross-application in chemical industries. At conferences, researchers share breakthroughs on process optimization, slag control, or impurity removal, trading technical secrets that ripple out to plant floors over years. For me, watching these projects grow from trial patches to new standards brings home how tradition and technology play off each other in heavy industry—a never-ending process of improvement rooted in curiosity.

Toxicity Research

Despite the industrial feel, toxicity concerns around reduced iron need a closer look. Workers and communities near DRI plants face more risk from dust, transport, and accidental fires than from the metal itself, though fine particulates pose known respiratory hazards. Research draws lines between health outcomes and chronic exposure to airborne iron dust, especially where plant controls miss the mark. Handling chemicals involved in reduction—like carbon monoxide or volatile hydrocarbons—requires tight environmental monitoring, not just for worker safety but for neighborhoods on the fence line. The international push for air quality standards has nudged plants to capture, clean, and reuse process off-gases, lowering particulate and greenhouse gas footprints. Regulators demand ongoing monitoring, setting limits based on evolving epidemiology that finds new risks in long-term exposure.

Future Prospects

Looking ahead, reduced iron holds a rare position as both a bridge and a destination in the world’s quest for lower-carbon metals. Hydrogen-based DRI holds top billing for climate-minded producers in Europe and Asia, promising near-zero emissions if made with green hydrogen and renewable energy. Recycling, scrap sorting tech, and digital twins in plant control will change how DRI fits into global steelmaking, blending old-school chemistry with new engineering. Economics weigh heavily—rising gas prices, hydrogen availability, and ore quality will sort winners from losers as producers juggle cost, quality, and climate. Materials science could open the door for DRI tailored for specialty steels or cross-industry use, deepening partnerships between miners, utilities, and steelmakers. Climate targets will keep DRI in the spotlight and raise expectations for safety, transparency, and community engagement along the way.




What is reduced iron and how is it produced?

Understanding Reduced Iron

Reduced iron, often called sponge iron or DRI (Direct Reduced Iron), shows up in the steel world as a fresh, solid alternative to scrap metal. You can spot it in factories where cleaner steel gets top priority—a response to growing worries about dirty air from old-school blast furnaces. Instead of feeding pig iron through a furnace, steelmakers lean on this material to cut emissions and keep process control tighter.

How It’s Made

Making reduced iron takes a special route. Workers start with natural iron ore—usually in the form of pellets or lumps. They heat the ore with gases packed with hydrogen and a bit of carbon monoxide, often stripped from natural gas. Here’s where things get interesting: temperatures run high enough to break oxygen away from the iron ore, but not so high that the ore melts. The result is a spongy matrix of nearly pure iron, holding small amounts of leftover carbon and trace minerals from the ore.

Plants use big, vertical shaft furnaces, horizontal rotary kilns, or fluidized bed reactors. The choice depends on local energy costs, ore quality, and desired output. The process keeps things relatively straightforward. People load iron ore from the top, inject reducing gases through the bottom or sides, and pull spongy iron from the base. Waste gases leave through another outlet, often scrubbed and re-used to save fuel and cut pollution. Along the way, careful temperature control and gas recycling keep costs in check.

Why the World Pays Attention

Steel plants face real pressure to move away from coal- and coke-heavy methods. Burning pure coal or coke not only whips out thick clouds of CO₂ and pollutants, but also ties companies to a fuel with a shrinking future. By switching part of the steel mix to reduced iron, mills shrink their carbon footprint. Each ton made by DRI methods can slash CO₂ output by more than half—sometimes even further if paired with renewable hydrogen.

I remember touring an electric arc furnace facility in the Midwest a few years back. They pointed to their stock of DRI and called it their insurance policy against wild swings in scrap metal prices, not to mention a way to keep their process leaner. They said, “We know what’s in it, so we make better steel, plain and simple.” That stuck with me. Consistency makes a difference when you want to avoid out-of-spec batches that cost cash and reputation.

The Push for Greener Steel

Some big players now eye hydrogen made by splitting water with green electricity. It costs more right now, but early projects in Sweden and the Middle East prove industry can shift. They run pilot plants making DRI with barely any carbon emissions, hoping to scale up and sell their story: low-carbon steel for bridges, cars, and appliances that won’t fuel climate change.

Of course, it’s not all rosy. Natural gas still runs most DRI plants, so the quest for greener solutions means heavy investment in renewables, pipelines, and storage. Policymakers talk up credits, taxes, and grants to nudge steelmakers in the right direction. Some regions face higher costs, while others gamble that cleaner steel will draw more customers.

Looking Ahead

With the world asking for better ways to build, reduced iron sits as a solid starting point. If more places bet on hydrogen and smart energy, DRI can lead the shift toward cleaner steel—cutting emissions without giving up reliability or edge in the global marketplace.

What are the primary uses of reduced iron?

Turning Iron into a Workhorse

A lot of people don't realize how essential reduced iron has become for modern life. In shops, cars, and buildings, you’ll find steel and iron parts holding everything together. Reduced iron—also called sponge iron—plays a big part in that story. The process strips away oxygen from iron ore, giving us a material that's almost pure, ready for new uses. Steelmakers rely on this because it brings them closer to the quality and consistency their industry demands—without creating as much pollution as older methods.

Feeding Steel Mills

Steel plants run on a mix of inputs, and reduced iron solves several problems. Traditional blast furnaces gulp down coke (that’s coal, baked into nearly pure carbon). This method worked for centuries, but it pumps greenhouse gases into the air. Reduced iron offers a smarter alternative. It feeds electric arc furnaces, letting companies skip coke. These furnaces take recycled scrap, add reduced iron, and turn it into steel for everything from skyscraper beams to rebar. This approach eats up less energy and shrinks pollution. With demand for cleaner metal growing, reduced iron keeps stepping up.

Boosting Scrap Quality

Steel recycling depends on the piles of scrap left over from cars, appliances, and torn-down buildings. Every batch of scrap carries some leftover bits of copper, tin, and other “tramp elements” that mess with the properties of the finished metal. Here, reduced iron acts as a balancing ingredient. Tossing it into the furnace with scrap lowers the risky mix of unwanted metals. That translates into higher-quality steel, able to take on tougher jobs—think bridges, high-speed rails, or car frames.

Providing Consistent Supply

In some parts of the world, high-purity scrap metal isn’t easy to come by. Industries in regions short on scrap or far from big seaports depend on reduced iron to keep production lines humming. It closes the gap. Instead of shipping steel from halfway around the world, factories can use reduced iron made from local ore and natural gas. Countries like India, Iran, and Mexico have built their manufacturing strength partly on this strategy. They’re making their own supplies rather than counting on someone else’s leftovers.

Cleaner Steel for Tomorrow

Today’s steel business faces more pressure than ever to clean up its act. Regulations and climate targets are pushing hard against old practices. Reduced iron helps lower carbon footprints because it skips some of the dirtiest steps in steelmaking. New projects in Europe and North America are betting on green hydrogen as the next big thing. Hydrogen, instead of coal or natural gas, can break the oxygen off iron ore. The result? Steel that leaves less carbon dioxide behind. This isn’t science fiction—it’s happening in pilot plants and will pick up steam as the technology matures.

Looking Ahead: More Than Just Metal

As energy gets cleaner and climate concerns climb, reduced iron offers a way to meet the world’s hunger for steel without wrecking the planet. Building more electric arc furnaces, swapping coal for hydrogen, and fine-tuning supply chains will all help. The steel you see in a skyscraper or a car might start out life as reduced iron—proof that some of the world’s biggest changes start with a single switch in a metallurgical recipe.

What is the difference between reduced iron and pig iron?

Why the Separation Matters

Steel touches nearly every aspect of our modern lives, from bridges that carry morning traffic to kitchen knives we use daily. Behind that steel stands a world few get to see—a world that begins with two raw iron materials: reduced iron and pig iron. The differences between them shape the way steel gets made, the emissions it puts out, and the costs behind every pipe or beam.

What is Reduced Iron?

Many in the trade know reduced iron by its more common name—direct-reduced iron (DRI). Think of DRI as iron ore that’s taken a shortcut. Mills process it through a low-temperature chemical reaction, using natural gas or coal to pull the oxygen out. This leaves behind iron with fewer impurities like carbon and sulfur, and the result offers a very predictable makeup for steelmakers who keep a close eye on quality. DRI often travels in a pellet or lump form and serves as a clean charge material in electric arc furnaces, especially in places where scrap is either too expensive or inconsistent.

Pig Iron’s Old-School Roots

Pig iron carries a certain grit from the old ways. At blast furnaces, iron ore, coke, and limestone combine under extreme heat, churning out molten iron rich in carbon—sometimes over 4%. This product cools into chunky ingots that once resembled piglets in a sow’s row, earning its odd name. Pig iron picks up extra elements along the way—phosphorus, silicon, and manganese—because of the process itself. Manufacturers then feed it into basic oxygen or electric furnaces where most of that carbon and other extras burn away. Historically, it’s the backbone of everything from rails to frying pans, though it’s less clean than DRI right out of the gate.

Real-World Impact: From Mills to Markets

Choosing between reduced iron and pig iron goes beyond chemistry. It touches the wallet and the planet. Plants relying on DRI tend to pump out less CO2, since natural gas produces fewer emissions compared to the tons of coal used in traditional blast furnaces. In regions where gas is cheap, you often see newer mills leaning toward DRI for this reason. Reliable quality and lower environmental costs can add up to savings and a lighter footprint.

Pig iron, by contrast, plays a central role in older, coal-rich regions—think of the massive integrated steel sites in China and India. The sheer scale and established supply chains keep pig iron relevant despite growing pressure to clean up. Still, it often serves as the default for plants that don’t get enough scrap metal or DRI.

What the Future Holds

The steel trade leans more and more on environmental rules and the push for lower carbon. Some companies take action by swapping out blast furnaces for direct reduction plants, which use less fossil fuel and offer more options for using “green” hydrogen in the future. Big automakers and construction giants now ask suppliers where their steel comes from and how it’s made. This sort of market pressure nudges both new and traditional mills to rethink their recipes and invest in cleaner routes like DRI.

Straightforward Solutions

Investing in direct reduction technology takes guts and capital, but the payoff goes beyond dollar savings. Workers stay healthier, cities get cleaner air, and mills open up new business with clients chasing low-carbon steel. Policies that offer tax breaks or carbon credits for green production can speed up the shift. Meanwhile, pig iron isn't vanishing overnight. Better recycling and alternative fuels for blast furnaces could help cut emissions even there. For anyone who cares about the stuff their world is built from, it’s worth knowing where the iron starts—and how that start shapes what comes next.

What are the advantages of using reduced iron in steelmaking?

Understanding the Basics

Steel fuels much of today's world, from bridges and cars to high-rise buildings. Making steel isn’t just about melting some scrap metal or adding a pinch of coal. It calls for dependable raw materials that deliver clean results every time. Reduced iron, also called direct reduced iron (DRI), has earned its place as a reliable feedstock for steelworks everywhere.

Cleaner Steel, Less Pollution

Steel made from raw iron ore often deals with unwanted elements—sulfur, phosphorus, and other impurities hitch a ride during the journey. Melting down scrap can also bring in tramp metals, like copper and tin, turning a batch of steel unpredictable. Reduced iron helps tackle these problems at the source. The DRI process strips out much of the junk, giving steelmakers a purer material to melt. Cleaner input means steel that holds up—stronger, tougher, safer for big construction. Our cities and factories run better with reliable steel, whether it lines pipelines or forms the frame of a ship.

Energy Savings and Lower Emissions

Traditional blast furnaces burn through coke and coal at remarkable rates. This method eats up a ton of energy and throws off a lot of carbon. Switching over to direct reduction cuts out some of those steps. Factories using reduced iron often rely on natural gas, or even hydrogen in some experimental plants. This energy shift slashes carbon dioxide emissions by around 40 percent, according to the World Steel Association. As governments set stricter climate rules, steelmakers turn to DRI as a smart way to stay within new limits—not just to tick boxes, but also to help communities breathe easier.

Flexible Steelmaking, Adapting to Changing Scraps

Sourcing steel scrap isn’t what it used to be. Less demolition, higher recycling, and global trade issues can put pressure on prices and supply. Reduced iron steps in as a flexible backup. Factories mix DRI with whatever scrap they can find, evening out quality from batch to batch. This flexibility cushions the pain during years when steel scrap gets scarce or expensive. It also helps developing economies grow their own steel industries, even if local scrap supplies fall short.

Building the Next Generation of Green Steel

Researchers keep pushing the boundaries with hydrogen-based DRI, eyeing a future where steel plants leave almost no pollution behind. Sweden’s HYBRIT project made headlines for producing emission-free steel using hydrogen, showing that large-scale green steel isn’t just a pipe dream. This matters for everyday folks who want to know their new cars or city bridges leave a smaller environmental footprint. In the coming years, these greener production methods could set the tone for industries everywhere.

Balancing Growth with Responsibility

Cost remains the biggest barrier for many steelmakers—installing DRI capacity and securing clean energy isn’t cheap. Still, choosing reduced iron isn’t just about running a business, it’s about accountability to workers, neighborhoods, and the planet. As someone who’s watched old mills close up shop and new plants break ground, I’ve seen how the right investment lifts a whole community. By betting on reduced iron, companies put themselves on the side of progress, not just profit.

How should reduced iron be stored and handled safely?

Why Reduced Iron Commands Respect

Reduced iron, often called sponge iron or direct reduced iron, holds a lot of potential—and risk. This stuff looks harmless, a gray powder or pellet that just sits in a barrel or bin, waiting for its trip into a furnace. Looks deceive. Add a little moisture, toss in some oxygen, you could get sparks—sometimes even a fire. People in steel plants know this worry all too well. I spent my fair share of hours around industrial stockpiles, and lessons stick when you’ve seen a container catch a whiff of humidity and start heating up for no good reason.

Understanding the Hazards Up Close

At its core, reduced iron wants to go back to its old self—iron oxide. That reaction gives off heat, and if left unchecked, a fresh pile can ramp up in temperature and catch fire from within. No one wants to handle hot metal or deal with emergency responders in the middle of shift. Several documented incidents, like the 2017 fire at an Indian steel facility, trace back to careless storage and handling. The stakes can run high—think property loss, environmental damage, or even injury.

Getting Storage Right

No fancy engineering degrees required, just respect for the basics. Keep this iron dry. Water kicks off the oxidation. A shed with a leaky roof turns every rainfall into a hazard. Concrete floors without drainage, standing puddles—more risk. I’d trust a sturdy covered storage, sloped so water drains away, equipped with reliable ventilation. Off the ground is best—wooden pallets or metal trays can help keep the iron from soaking up dampness from the floor. Some companies push for inert gas blankets for big stockpiles, like nitrogen, but for most, a dry, cool environment does a lot of heavy lifting.

Avoid Cutting Corners When Moving It

Shifting reduced iron feels routine until someone gets careless. Metal buckets, chutes, conveyor belts—they all need regular checks. Broken equipment can mean leaks, which feed iron powder straight onto a damp patch. Better to keep transfers quick, avoid bottlenecks, and sweep up spills right away. Crushed pellets or powder raise dust clouds. Inhalation hazards pile onto fire hazards. Simple dust masks help, and keeping the workspace swept cuts down on buildup. Regular teams should have access to safety showers and eye wash stations—just because things are safe today doesn't promise a smooth ride tomorrow.

Putting Training On the Front Burner

Walk onto a new site, and the best outfits go beyond signs on the wall. Hands-on training means people actually understand how to spot warning signs—rising temperatures in a pile, odd smells, moisture creeping in from a loading dock. Toolbox talks push folks to bring up close calls or point out leaky bins. These conversations, supported with OSHA standards and the latest guidance from groups like the World Steel Association, keep the standard of care high. Every major incident starts as a million ignored details—bring a microscope to those details and people stay safer.

Building a Culture That Lasts

What sticks with me is how safety around reduced iron runs on community. From the maintenance worker checking a sump pump to the warehouse manager checking humidity, every layer matters. People who take time to do things right, supported by management that funds solid gear and training, keep mishaps rare. A one-off solution never beats consistent small steps. That’s what builds trust, keeps insurance rates down, and lets workers get home at the end of their shift with nothing worse than a tired back and a head full of good habits.

Reduced Iron
Names
Preferred IUPAC name Iron
Other names Sponge iron
Direct reduced iron
DRI
Pronunciation /rɪˈdjuːst ˈaɪən/
Preferred IUPAC name iron
Other names Sponge iron
Direct reduced iron
DRI
Pronunciation /ˈriːˌdjuːst ˈaɪən/
Identifiers
CAS Number 65997-19-5
3D model (JSmol) `3D model (JSmol): "Fe"`
Beilstein Reference 2639289
ChEBI CHEBI:50113
ChEMBL CHEMBL1201731
ChemSpider 119190
DrugBank DB01592
ECHA InfoCard 05f6be7f-a2f2-4185-bc1d-53e80e40e4fd
EC Number E172
Gmelin Reference Gmelin Reference: 1151
KEGG C14818
MeSH D017207
PubChem CID 23925
RTECS number WY3846000
UNII 3G44Q486SW
UN number UN 1376
CompTox Dashboard (EPA) DTXSID2022319
CAS Number 65996-65-8
3D model (JSmol) `3d:Fe`
Beilstein Reference III, 382
ChEBI CHEBI:53348
ChEMBL CHEMBL1201880
ChemSpider 26313
DrugBank DB01592
ECHA InfoCard 03d9380d-c9a7-41f2-9734-580e9fe76c5c
EC Number EC 231-096-4
Gmelin Reference Gm. 53
KEGG C14818
MeSH D011987
PubChem CID 6914313
RTECS number LW2990000
UNII HG18B9YRS7
UN number UN 1517
CompTox Dashboard (EPA) DTXSID7031624
Properties
Chemical formula Fe
Molar mass 55.85 g/mol
Appearance Grey metal pieces
Odor Odorless
Density 2.45 g/cm³
Solubility in water Insoluble
log P 4.40
Vapor pressure Low (0.03 mmHg at 20 °C)
Basicity (pKb) 14.4
Magnetic susceptibility (χ) 6.2×10⁻⁴
Refractive index (nD) 1.0
Dipole moment 0 Debye
Chemical formula Fe
Molar mass 55.85 g/mol
Appearance Grey powder or porous mass
Odor Odorless
Density 2.7 g/cm³
Solubility in water Insoluble in water
log P 1.3
Vapor pressure 0.0013 mm Hg @ 25 °C
Basicity (pKb) 14.0
Magnetic susceptibility (χ) +800 × 10⁻⁶
Refractive index (nD) 1.0
Dipole moment 0 Debye
Thermochemistry
Std molar entropy (S⦵298) 27.28 J/(mol·K)
Std enthalpy of formation (ΔfH⦵298) +14.9 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -142 kJ/mol
Std molar entropy (S⦵298) 27.28 J/(mol·K)
Std enthalpy of formation (ΔfH⦵298) +14 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -110.55 kJ/mol
Pharmacology
ATC code B03AB01
ATC code B03AB01
Hazards
GHS labelling GHS07, GHS08
Pictograms 
Signal word Warning
Precautionary statements P264, P270, P301+P312, P330, P501
NFPA 704 (fire diamond) 1-0-1
Autoignition temperature 650°C
Explosive limits Lower: 0. . . Upper: 100%
Lethal dose or concentration Lethal dose or concentration (LD50): **Oral (rat): 98.6 g/kg**
LD50 (median dose) 30 mg/kg (rat, oral)
NIOSH MN9800000
PEL (Permissible) 5 mg/m³
REL (Recommended) 58.0
IDLH (Immediate danger) IDLH: 2500 mg Fe/m³
GHS labelling GHS07, Warning, H302
Pictograms 
Signal word Warning
Precautionary statements P264, P270, P301+P312, P330, P501
NFPA 704 (fire diamond) 3-2-3
Autoignition temperature 450°C
Explosive limits Explosion limits: 20–1800 g/m³
Lethal dose or concentration LD50 Oral Rat 30,000 mg/kg
LD50 (median dose) 30 g/kg (rat, oral)
NIOSH 1477
PEL (Permissible) 10 mg/m³
REL (Recommended) 24.0
IDLH (Immediate danger) IDLH: 2500 mg Fe/m³
Related compounds
Related compounds Ferric oxide
Ferrous oxide
Related compounds Iron
Iron(II) oxide
Iron(III) oxide