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Potassium Nitrate MSDS

Identification

Product Name: Potassium Nitrate
Chemical Formula: KNO3
CAS Number: 7757-79-1
Synonyms: Nitrate of potash, Nitric acid potassium salt, Saltpeter
Recommended Use: Fertilizer component, oxidizer in fireworks, food preservative, laboratory reagent
Supplier Identification: Manufacturer's name, address, and emergency contact number must be clearly provided on the label and data sheet.

Hazard Identification

GHS Classification: Oxidizing solid (Category 3), Eye irritation (Category 2A)
Pictograms: Exclamation mark, Flame over circle
Signal Word: Warning
Hazard Statements: May intensify fire (oxidizer), Causes serious eye irritation
Precautionary Statements: Keep away from heat, sparks, open flames, and combustible materials; Wash hands thoroughly after handling; Wear protective equipment such as gloves and eye protection to avoid direct exposure.

Composition / Information on Ingredients

Chemical Name: Potassium Nitrate
Common Name and Synonyms: Saltpeter, Nitrate of potash
CAS Number: 7757-79-1
Concentration: Greater than 99% by weight
Impurities: Product quality and grade specifications set by supplier may contain minimal traces of other potassium or nitrate compounds.

First Aid Measures

General Advice: Move affected person to fresh air. Remove contaminated clothing and shoes.
Inhalation: Move person to fresh air, seek medical attention if symptoms like coughing or difficulty breathing persist.
Skin Contact: Wash skin with soap and water. Remove contaminated clothing. Seek medical advice if irritation appears.
Eye Contact: Rinse eyes cautiously with water for at least 15 minutes, lifting eyelids occasionally. Seek medical attention.
Ingestion: Rinse mouth, do not induce vomiting. Seek immediate medical attention, showing the label or data sheet.

Fire-Fighting Measures

Suitable Extinguishing Media: Flood fire area with water. Potassium nitrate does not burn but supports combustion.
Special Hazards: May intensify fire when in contact with combustible substances. During fire, toxic fumes such as nitrogen oxides and potassium oxides can form.
Fire Fighter Instructions: Use full protective gear and positive pressure self-contained breathing apparatus.
Explosion Risk: Vigorous heating may cause hazardous decomposition, releasing gases. Mixing with organic or reducing agents can enhance fire risk.

Accidental Release Measures

Personal Precautions: Wear protective clothing, avoid contact with spilled material, use proper respiratory protection.
Environmental Precautions: Prevent release into drains, watercourses, or soil.
Spill Clean-Up Methods: Contain and sweep up spill, avoiding dust generation. Collect in containers for disposal. Use water to clean contaminated surfaces if spillage is minor, minimizing runoff to the environment.

Handling and Storage

Handling: Wear suitable protective equipment. Avoid generating dust. Do not mix with combustible or reducing agents. Wash thoroughly after handling.
Storage: Store in tightly closed containers in a cool, dry, well-ventilated location away from heat, moisture, and ignition sources. Keep away from acids, flammable materials, organics, and other incompatible substances.
Incompatibilities: Avoid storing with reducing agents, ammonium salts, acids, combustibles.

Exposure Controls and Personal Protection

Exposure Limits: No specific occupational exposure limits are established for potassium nitrate by OSHA or ACGIH.
Engineering Controls: Work in well-ventilated areas. Use local exhaust ventilation to reduce exposure.
Personal Protection: Use safety goggles or face shield, chemical resistant gloves, long-sleeve clothing, and dust-proof respirator when handling large quantities or powders.
Hygiene Measures: No eating, drinking, or smoking during use. Wash hands thoroughly after working with potassium nitrate.

Physical and Chemical Properties

Appearance: White or colorless crystalline solid
Odor: Odorless
pH (5% solution): Nearly neutral (6.2–8.5)
Melting Point: 334°C (633°F)
Boiling Point: Decomposes at 400°C (752°F)
Solubility: Soluble in water (31.6 g/100 mL at 20°C)
Vapor Pressure: Not applicable (non-volatile solid)
Density: 2.11 g/cm³ at 20°C
Partition Coefficient (n-octanol/water): Not determined
Evaporation Rate: Not applicable

Stability and Reactivity

Chemical Stability: Stable under normal storage and handling conditions.
Possibility of Hazardous Reactions: Strong oxidizer, enhances combustion of other materials. May react with incompatible substances, causing fire or explosion risks.
Incompatible Materials: Combustible materials, organic substances, reducing agents, sulfur, phosphorus, metallic powders, acids, ammonium salts.
Hazardous Decomposition Products: Nitrogen oxides, potassium oxide gases upon heating or fire.

Toxicological Information

Acute Toxicity: Low toxicity in normal use. Oral LD50 (rat) reported at about 3750 mg/kg. Inhalation of dust may cause respiratory irritation.
Skin Corrosion/Irritation: May cause mild skin irritation on prolonged contact.
Eye Damage/Irritation: Causes irritation and redness. In high concentrations, may damage eye tissues.
Ingestion Effects: Large doses can cause abdominal pain, diarrhea, nausea, methemoglobinemia, cyanosis, weakness.
Long-term Exposure: Chronic exposure may affect blood and kidneys. No known carcinogenicity.
Sensitization: No data indicates allergic sensitization from repeated use.

Ecological Information

Aquatic Toxicity: Potassium nitrate is highly soluble in water and readily dissociates. Large releases can cause eutrophication and harmful algal blooms in water bodies.
Persistence and Degradability: Nitrate ions persist in the environment, contribute to water pollution, and promote undesirable plant growth.
Bioaccumulation Potential: Does not bioaccumulate in organisms.
Mobility in Soil: Highly mobile in soils and can leach into groundwater.
Other Effects: Excessive concentrations harm aquatic life and degrade water quality.

Disposal Considerations

Waste Treatment Methods: Dispose of potassium nitrate according to local, regional, and national regulations.
Unused Product: Consider reuse wherever possible, or incinerate only in authorized facilities.
Contaminated Packaging: Rinse and recycle empty containers following regulations, or dispose as hazardous waste.
Environmentally Sound Practices: Prevent contamination of water, soil, and drains during disposal.

Transport Information

UN Number: UN1486
Proper Shipping Name: Potassium Nitrate
Hazard Class: 5.1 (Oxidizer)
Packing Group: III
Labels: Oxidizer label required on packages
Special Precautions: Protect from moisture. Ensure no contact with organic materials or reducing agents during transport. Comply with all applicable transport regulations for road, sea, and air freight.

Regulatory Information

Regulatory Status: Potassium nitrate is regulated as an oxidizer under several international transport and workplace safety guidelines.
OSHA: Not classified as a hazardous chemical, though subject to specific handling requirements due to oxidizer status.
EPA: Listed as a hazardous substance; release reporting requirements may apply.
TSCA: Listed in the US TSCA Inventory.
REACH: Registered under European Regulation (EC) No 1907/2006.
Other: Users must review local, regional, and national regulations regarding labeling, transport, storage, environmental release, and disposal.