People have leaned on potassium bitartrate longer than most realize. Centuries before it found a place on grocer’s shelves as “cream of tartar,” winemakers saw it crystallizing in casks and barrels. Early on, not many understood how the white, crusty residue collected at the bottom of grape fermentations could help outside the vineyard. Later, bakers learned that the same substance playing a quiet part in stabilizing wine could also turn egg whites glossy and lend lightness to cakes. The French, as it happened, first scooped up these crystals and turned them into a household staple. By the late 1800s, chemists pieced together its molecular structure and standardized its production, giving the world a food additive, acidulant, and leavening agent all at once. For folks in the kitchen or lab, potassium bitartrate’s value keeps growing with each new application.
Potassium bitartrate takes the form of a fine, white powder. It sports a slightly acidic flavor and often comes packaged in small jars labeled “cream of tartar.” You’ll find this ingredient in spice sections and baking aisles, but its reach extends far beyond recipes. On the industrial side, it appears as a stabilizer, acidulant, and cleaning agent. In short, the journey from grape skins to food-grade powder makes potassium bitartrate a versatile tool at home and in factories.
At its core, potassium bitartrate has the formula KC4H5O6. It looks like a fine, white, odorless powder with a slightly tart flavor, dissolving slowly in cold water but with more ease in hot. It melts at 230°C, a useful detail when heat processing comes into play. The powder tends to clump if exposed to moisture due to its hygroscopic nature. It turns slightly acidic in water, clocking in at a pH near 3.5. Since it doesn’t dissolve in ethanol, applications in winemaking steer clear of ethanol-rich stages. Chemically, potassium bitartrate stands as the potassium acid salt of tartaric acid, which influences its behavior in baking powder blends and metal cleaning.
Labels for potassium bitartrate show its identity as E336 in the European food additive registry. Strict limits exist regarding its purity; food-grade versions must meet benchmarks for water content, insoluble matter, and trace metal contamination. Manufacturers keep a close eye on lead, arsenic, and heavy metal residues. Packages will list the net weight, recommended storage conditions, and expiration dates to prevent caking and preserve strength. Labeling regulations ask suppliers to specify tolerances for iron, calcium, and other ions, because small impurities can affect performance in baked goods or in fermentation control.
Potassium bitartrate comes from winemaking. During fermentation, tartaric acid in grape juice binds with potassium ions to create crystals that stick to cask walls or drop to the bottom. Workers scrape off these crystals as sediment. The coarser bits go through washing with water, purification to remove wine residues, drying, and grinding until the powder meets food standards. No synthetic process rivals this grape-born path, and wine regions across Europe and North America often send their tartaric residues off to specialized processors. Some experiments have tried to extract it from other plant sources, but grape fermentation remains the most reliable method.
Potassium bitartrate interacts in clever ways. In baking, it works as an acidulant, reacting with sodium bicarbonate (baking soda) to create carbon dioxide gas. This puff of gas lifts cakes and cookies, giving them their airy structure. Blending potassium bitartrate with strong bases like sodium hydroxide breaks it down into potassium tartrate and water. Industrial chemists harness this property to shift acidity, purify metal surfaces, or manage scaling. Esterification and further neutralization deliver dipotassium tartrate (Rochelle salt)—which found fame in early radio technology and as a laboratory reagent. Modifying its hydration or particle size changes solubility and performance, a reason why manufacturers care about batch-to-batch consistency.
Over time, potassium bitartrate picked up more than one moniker. “Cream of tartar” stands as the common kitchen name. Older recipes reference “tartar powder” or “tartaric acid salt.” Chemical catalogs use “potassium hydrogen tartrate.” Sometimes, labels use E336 (i), signaling European food additive standards. No matter the name, they point to the same crystalline acid salt collected from winemaking vats.
Safety deserves attention at every stage, from manufacturing to kitchen use. Food regulatory bodies check potassium bitartrate for contaminants, focusing on metals and residues from wine processing. Workers handling large volumes follow dust and inhalation precautions, with ventilation in drying and grinding rooms. Left unchecked, the powder can irritate lungs or cause mild stomach upset if consumed in excess. Global food standards, like those from Codex Alimentarius and the FDA, place strict thresholds on allowable impurity levels. Storage standards ask for sealed, dry containers away from strong oxidizers or sources of moisture. In practical use, potassium bitartrate rarely causes trouble unless mistakenly incorporated in very large quantities.
Cooks turn to potassium bitartrate for more than meringues and soufflés. It stabilizes egg whites, adds tartness to syrups, and keeps sugar from crystallizing in candies. Its acid plays a role in natural food coloring, helping anthocyanins hold their red tones. Pickling recipes sometimes favor it to tweak pH. Industrial users slap it into cleaning solutions for brass or copper; the acid properties help shine metal without leaving harsh residues. Some manufacturers sprinkle it in wine or alcoholic beverage production to control unwanted carbonation or fermentation byproducts. Specialty chemical applications dip into its properties for use in buffer solutions, while ceramics and tanning industries occasionally include it in process aids.
Innovation continues, both in food science and in environmental technology. Researchers study how particle size affects baking performance or how potassium bitartrate interacts with gluten-free flours. Winemakers want faster, cleaner ways to remove it from barrels and tanks, aiming for higher purity and more sustainable production. Food technologists experiment with blending it into new leavening systems, looking to tailor shelf life and rise rates. Other labs check its function as a corrosion inhibitor for non-food metals. Scientists in pharmacology look for ways to repurpose it in dietary supplements and controlled-release formulations, testing its compatibility with various actives. Environmental research digs into recovering more from grape residues, minimizing waste while boosting value for wineries.
Toxicologists have scoured the literature, and potassium bitartrate doesn’t rank high on the danger list when properly consumed. High doses—well beyond anything in food—sometimes cause stomach irritation, laxative effects, or electrolyte imbalances. Some rare reports link deliberate ingestion of large quantities to cases of hyperkalemia, a spike in blood potassium that can threaten heart rhythm. For the average person, the low levels found in recipes or industrial applications don’t come close to causing harm. Ongoing research scans for accumulation effects in those with kidney problems or unusual diets, underlining the importance of moderation and labeling. The European Food Safety Authority and the U.S. FDA both consider it safe as a food additive within standard guidelines.
Looking ahead, demand for potassium bitartrate keeps rising in response to changes in food habits and manufacturing trends. Gluten-free and clean-label products need gentle leavening acids, and potassium bitartrate fits that bill. Wine production shows no sign of stopping, so the raw material supply remains stable in grape-rich regions. More sustainable processing might soon cut waste by turning grape sediments into high-purity powder more efficiently. Formulators in cosmetics, environmental cleaning, and green chemistry scout for milder organic acids, often settling on potassium bitartrate for both safety and performance. As tighter regulations hit synthetic acidulants, this grape-based classic continues to find new roles across kitchens, factories, and research labs.
Walk into most home kitchens or bakeries, and you’ll find potassium bitartarate, even if it hides under the name “cream of tartar.” That little white powder plays a bigger role than its unassuming look. For bakers, this ingredient holds together dozens of classic treats and turns tricky recipes into reliable favorites.
Potassium bitartarate comes from the winemaking process, forming as crystals inside wine barrels after fermentation. Its main role shows up in baking: it’s a natural acid, and acids help shape the chemistry of baked goods. Take meringues. Egg whites on their own whip up just fine, but cream of tartar keeps those peaks glossy and stiff. The acid stabilizes proteins, stopping them from collapsing after a few minutes. Without it, angel food cake comes out saggy and flat.
Baking powder is another spot where you’ll find potassium bitartarate at work. It teams up with baking soda, which needs acid to create carbon dioxide bubbles. That’s where the lift in fluffy pancakes or biscuits comes from. Many store-bought baking powders list it among their most important ingredients because it gives that rise with no bitter aftertaste.
Cream of tartar solves kitchen puzzles outside of baking too. Copper pots, which my grandmother always kept sparkling, lose their shiny finish without a soft touch. Mix a little cream of tartar with vinegar and watch tarnish disappear, without harsh fumes or waste.
Some folks grow up hearing it’s good for stabilizing whipped cream, or for keeping boiled sugar smooth in homemade candy. Bitartarate’s acid stops crystals from forming, which lets fudge and syrups stay silky. Its usefulness doesn’t end at desserts, though. People mix it in water and lemon juice for old-fashioned sore throat relief, though I stick to tea myself.
It’s tempting to think every kitchen helper belongs in the medicine cabinet. Stories float around social media claiming potassium bitartarate can work as a detox, laxative, or remedy for just about anything. In truth, doctors haven’t found enough evidence for those sweeping claims, and using a lot at once risks upsetting your stomach or leading to potassium overload. Reliable sources like the FDA only approve it for food use. Treat it like you’d treat baking soda – not a health fad, just a tool for the kitchen.
Home bakers depend on potassium bitartarate because it keeps recipes simple and cuts down on food waste. Swapping it out isn’t always easy. Lemon juice or vinegar can work in a pinch for some recipes, but neither blends as well with egg whites. The science behind this ingredient lets us use fewer additives, and gives younger bakers room to experiment without worrying about results flopping.
Trust builds over decades, and potassium bitartarate has shown its worth time and again. Families pass down fudge recipes and holiday pies, knowing this one powder fixes more than it ever claims on the label. Innovation in the kitchen might bring new tricks, but sometimes the best results come from tools that have quietly proven themselves through generations.
Walk into any grocery store and you'll probably spot a tiny bottle with a white powder called “cream of tartar.” Flip it over, and the ingredient list might mention potassium bitartrate, or potassium hydrogen tartrate. All these names point to the same compound—a byproduct scraped from the inside of wine barrels during fermentation. In kitchens big and small, folks reach for cream of tartar to whip up meringue, stabilize stiff peaks, or add a cookie’s signature tang. At the molecular level, it’s potassium bitartrate. Commercial food producers, home cooks, and lab technicians work with exactly the same material despite the label difference.
For those who bake, this stuff is more workhorse than background player. Cream of tartar strengthens egg whites, helping them trap air and hold their shape through baking. Lemon meringue pie would flop into a puddle without it. Cookie recipes lean on it for chew and mild acidity. Some families keep it close for cleaning tarnished pans or polishing up metal faucets—old-school, but it works. So the confusion between potassium bitartrate and cream of tartar isn’t harmless trivia; if you misread a technical recipe and swap something else in, the results fall flat.
There's always some concern over what goes into ingredients with long chemical names. In this case, cream of tartar rates as food-safe on all major health guides. The United States Food and Drug Administration lists it as generally recognized as safe (GRAS). Anyone with kidney issues may need to watch their intake, as the body handles excess potassium less easily when the kidneys struggle. Major brands track purity; manufacturing follows food safety regulations. Anyone looking for “organic” might be disappointed, though it’s about as natural as it comes—no artificial additives, just a cleaned-up byproduct from winemaking. Junk science sometimes pushes cream of tartar as a detox cure, but credible medical advice does not support wild health claims.
Scientific names can trip up even the most attentive shopper or home chef. Grocery store shelves use familiar labels like “cream of tartar,” but technical manuals, chemical suppliers, or bulk ingredients use potassium bitartrate or E336. This gap creates unnecessary worry, especially for parents or folks with dietary concerns. Some gluten-free recipes direct readers to buy only “potassium bitartrate,” thinking cream of tartar has gluten. There’s no difference at all—just a change of vocabulary depending on the setting. Clearer packaging and better education go a long way here, so customers don’t spend time triple-checking every label or missing out on a family recipe out of misplaced caution.
Manufacturers can help smooth things over by listing “potassium bitartrate (cream of tartar)” on packaging. Cooking schools and recipe books have taken notice and already include both names. Food science teachers do their part busting the myth; a little knowledge saves a lot of frustration. Swapping out real knowledge for internet speculation can lead to expensive mistakes—or odd-tasting cakes. A clear, fact-based approach benefits both home kitchens and classrooms, helping bakers shop smart and experiment with confidence.
Staring down a recipe for snickerdoodles or a fluffy angel food cake, sooner or later the name potassium bitartrate pops up. Most of us know it by its grocery store alias, cream of tartar. In my kitchen, it’s always lurking in the spice drawer – that little white powder does more than just help egg whites fluff up. But scroll through online forums or overhear conversations in the supermarket, and suddenly there’s a debate: Is potassium bitartrate actually safe to put in food?
I taught myself the ropes of home baking, learning that potassium bitartrate comes from the crust that forms during wine fermentation. It’s nothing new to the human diet. Each time I whisk it into meringue, I know the stuff’s working as a stabilizer, keeping the peaks high and glossy. Regulatory agencies like the U.S. Food and Drug Administration categorize it as “generally recognized as safe” (GRAS). This isn’t just a label tossed out lightly. Agencies price safety above convenience, running substances through a battery of tests before letting them land on shelves.
No food ingredient sails through life without a rumor or two chasing it. Someone always worries about “chemicals” in food, just because the name sounds technical. Potassium bitartrate has potassium in it – the same mineral that helps steady your heartbeat and balance fluids in your cells. The amounts found in a teaspoon scattered across a cake recipe hardly dent most people’s daily potassium intake. Only folks with chronic kidney disease need to be strict about their potassium sources. For most other people, small culinary doses are simply too tiny to mess up any balance.
There’s a stretch where caution becomes paranoia. Stories float around about using cream of tartar for “cleanses” or home remedies, with some believing it can pull off miracles. Tossing back spoonfuls for supposed health benefits is a huge mistake – too much can upset your stomach or cause electrolyte issues. In my experience, there’s never been a reason to reach for cream of tartar by the tablespoon. It belongs in recipes, not self-made medicines.
Health agencies keep revisiting published data to catch any new findings about kitchen staples. So far, research shows this ingredient is metabolized and excreted efficiently in the quantities people use for cooking. It doesn’t linger in the body or accumulate in tissues. Cream of tartar’s biggest claim to fame in the household isn’t health, but the perfect batch of cookies. Regulatory panels in the US, Canada, and across Europe keep an eye on all food additives, dropping the hammer if any real danger pops up – and potassium bitartrate remains on the safe list.
I learned a lot from my grandmother, who believed in respecting every ingredient, whether salt or spices. She kept things labeled and measured carefully. No chemical in the kitchen should be used blindly, and every label deserves a quick glance. The power of potassium bitartrate lies in its chemistry, raising fluffy peaks in dessert or helping baking powder do its job. Used by the gram, not the spoonful, this ingredient fits safely into recipes, just like it has for generations.
Potassium bitartrate holds onto its spot in the baker’s toolkit by doing what it’s always done – supporting stable textures and light results. Worries about its safety don’t hold much weight unless you toss out moderation altogether. Respect for science, a measuring spoon, and a hearty bit of common sense will carry any home cook farther than online panic ever will.
Potassium bitartarate, better known as cream of tartar, has a long history on the shelves of both home kitchens and food manufacturers. Folks often pull it off the back row of a pantry to stabilize egg whites or keep sugar from crystallizing. Still, it does more than whip up a good meringue or batch of candy. For bakers, food processors, and anyone using this powder, keeping its quality up starts with proper storage.
Ask anyone who’s ever dealt with stubborn clumping in cream of tartar, and you’ll hear that moisture does the most damage. Potassium bitartarate naturally pulls water out of the air, causing clumps and sometimes hardening beyond practical use. That means a tight lid on a clean, dry container is a must. I’ve learned this the hard way after losing half a jar during a rainy stretch, just because it was left loose in a cupboard.
Too much light and unfiltered air don’t ruin the powder overnight, but they can encourage slow changes in quality. Clear jars might look fancy, but they let light in, which is far from ideal. Stick to opaque jars or dark cabinets away from heat. Food safety agencies, like the FDA, recommend cool, dark storage not just for potassium bitartarate, but for a long list of dry ingredients. It’s a simple step that makes a difference over months.
High temperatures rarely destroy potassium bitartarate, but swinging temperatures can encourage condensation inside a container. In my years working in a bakery, the open-to-close cycle of ovens once left our whole dry-goods shelf in rough shape during summer. A cool pantry or storeroom, somewhere between 15°C and 25°C (60–77°F), keeps the powder loose and reliable. Cold storage, like a fridge, can actually lead to moisture problems during the dreaded “out then back in” routine.
Storing any food ingredient somewhere that’s crowded or messy raises the risk of cross-contamination. Cream of tartar powders pick up odors and flavors from strong-smelling neighbors. Keep it far from onions, garlic, and potent spices. Always use clean, dry scoops to prevent introducing moisture or unwanted particles. Food-grade containers do more than look professional — they stop accidental flavor swaps or pest infestations.
Kept right, potassium bitartarate can last for years, but it pays to check before every use. Lumps that don’t break up easily or a weird, off smell signal the need to toss it. Regulatory bodies like the USDA say to rely on sensory checks — if something seems off, don’t take chances, especially in commercial kitchens where a single bad batch can hurt more than just the day’s profits.
For business owners or high-volume bakers, investing in airtight bins, humidity indicators, and regular rotation systems cuts waste and keeps product quality steady. Training new staff to follow the “use by” dates, know proper transfer methods, and recognize compromised product supports both safety and consistency — two things every food business rests on. Simple steps up front, less headache later.
Potassium bitartarate, better known as cream of tartar, hangs around in most kitchens—often living quietly in the back of a spice drawer. Folks usually spot it in meringue recipes, where it promises sturdy egg whites. Every time I pull it out, I remember how bakers through the years leaned on this powder for a reason. Cream of tartar keeps sugar from crystallizing, making candy and syrup smooth, and nobody likes lumpy fudge.
The heart of every loaf and cake springs from leavening. Baking powder and baking soda rule this game. Keep in mind, leavening means producing those tiny bubbles lifting dough and batter. Baking soda alone needs an acidic friend to kick-start carbon dioxide bubbles. Without it, all you get is a dense slab instead of a fluffy cake. That’s where potassium bitartarate steps up. Mix cream of tartar with baking soda, you’ve made homemade baking powder. Add water, and the fizz begins—there's your lift.
I tried tossing just cream of tartar into a batch of muffins, hoping for a shortcut. Without baking soda, those muffins stayed stubbornly low. Cream of tartar alone brings the acid, but not the fizz. The actual bubbles come after baking soda joins the mix, reacting together right there in the bowl. This chemistry lesson shapes why stores sell premixed baking powder—consistency and convenience. Even science agrees: research from food chemistry journals highlights that the best rise comes from tailoring acid and base in the right amount. Too much acid sours taste; too much base leaves everything soapy. Getting that balance right matters.
Through experience, I’ve learned cream of tartar’s real star power shines in stabilizing egg whites and smoothing syrups more than replacing baking powder. It keeps angel food cakes from falling flat. It blocks sugar crystals when I make caramels. If you keep only one leavening agent in your pantry, make it baking powder—but keep cream of tartar around for tricks only it can manage.
The U.S. Food and Drug Administration lists potassium bitartarate as safe for food use and backs up its reliability in baking. From nutritionists to old-school bakers, the consensus runs clear: combine it correctly, and it performs. Baking powder itself often lists potassium bitartarate as an ingredient, confirming its role behind the scenes.
If your baking powder runs out, blend two parts cream of tartar with one part baking soda, and you’ll have a decent substitute. This tip saved my cookies more than once. Watch out for freshness. Old powder loses punch, so test a teaspoon in warm water. No bubbles means it’s time to grab a new can.
For people searching for simple, reliable results, commercial baking powder beats fussing with homemade mixes. Still, knowing how these basics work means you can recover from kitchen mistakes, cut chemical additives, and get closer to scratch baking. Skill with cream of tartar doesn’t just build knowledge. It gives control for better, tastier food.
| Names | |
| Preferred IUPAC name | Potassium 2,3-dihydroxybutanedioate |
| Other names |
Cream of Tartar Potassium Hydrogen Tartrate Potassium Acid Tartrate |
| Pronunciation | /poʊˌtæsiəm baɪˈtɑːrəteɪt/ |
| Preferred IUPAC name | Potassium 2,3-dihydroxybutanedioate |
| Other names |
Cream of Tartar Potassium Hydrogen Tartrate Monopotassium Tartrate |
| Pronunciation | /poʊˈtæsiəm baɪˈtɑːrtəreɪt/ |
| Identifiers | |
| CAS Number | 868-14-4 |
| Beilstein Reference | 3592222 |
| ChEBI | CHEBI:132753 |
| ChEMBL | CHEMBL1201482 |
| ChemSpider | 10310 |
| DrugBank | DB11097 |
| ECHA InfoCard | 100.031.745 |
| EC Number | E336 |
| Gmelin Reference | Gmelin Reference: **20915** |
| KEGG | C14347 |
| MeSH | D011090 |
| PubChem CID | 8779 |
| RTECS number | WS7250000 |
| UNII | MP490U3B6E |
| UN number | UN3077 |
| CompTox Dashboard (EPA) | DJ19G1763D |
| CAS Number | 868-14-4 |
| Beilstein Reference | 3599536 |
| ChEBI | CHEBI:53499 |
| ChEMBL | CHEMBL1375 |
| ChemSpider | 5286 |
| DrugBank | DB11090 |
| ECHA InfoCard | 0324625 |
| EC Number | E336 |
| Gmelin Reference | Gmelin Reference: **15898** |
| KEGG | C00517 |
| MeSH | D011090 |
| PubChem CID | 23665763 |
| RTECS number | WG2950000 |
| UNII | VCRE8U3HIG |
| UN number | UN3077 |
| CompTox Dashboard (EPA) | DTXSID3047328 |
| Properties | |
| Chemical formula | KC4H5O6 |
| Molar mass | 188.18 g/mol |
| Appearance | White crystalline powder |
| Odor | Odorless |
| Density | 1.05 g/cm3 |
| Solubility in water | 4.0 g/L (20 °C) |
| log P | -0.77 |
| Acidity (pKa) | 3.57 |
| Basicity (pKb) | 4.57 |
| Magnetic susceptibility (χ) | −77.0·10⁻⁶ cm³/mol |
| Refractive index (nD) | 1.337 |
| Dipole moment | 0 D |
| Chemical formula | KC₄H₅O₆ |
| Molar mass | 188.18 g/mol |
| Appearance | White crystalline powder |
| Odor | Odorless |
| Density | 1.044 g/cm3 |
| Solubility in water | 4.0 g/L (20 °C) |
| log P | -0.77 |
| Vapor pressure | Negligible |
| Acidity (pKa) | 3.57 |
| Basicity (pKb) | pKb ≈ 10.25 |
| Magnetic susceptibility (χ) | −77.0·10⁻⁶ cm³/mol |
| Refractive index (nD) | 1.336 |
| Dipole moment | 0 D |
| Thermochemistry | |
| Std molar entropy (S⦵298) | 166.5 J·mol⁻¹·K⁻¹ |
| Std enthalpy of formation (ΔfH⦵298) | -1612.0 kJ/mol |
| Std enthalpy of combustion (ΔcH⦵298) | –1685 kJ/mol |
| Std molar entropy (S⦵298) | 217.2 J·mol⁻¹·K⁻¹ |
| Std enthalpy of formation (ΔfH⦵298) | -1596.2 kJ/mol |
| Std enthalpy of combustion (ΔcH⦵298) | -1580 kJ/mol |
| Pharmacology | |
| ATC code | A12BA02 |
| ATC code | A12BA01 |
| Hazards | |
| Main hazards | May cause respiratory tract irritation, skin and eye irritation. |
| GHS labelling | GHS07, Warning, H319, P264, P280, P305+P351+P338, P337+P313 |
| Pictograms | GHS07, GHS08 |
| Signal word | Warning |
| NFPA 704 (fire diamond) | 1-0-0 |
| Autoignition temperature | 200°C |
| Lethal dose or concentration | LD50 (oral, rat): 2,500 mg/kg |
| LD50 (median dose) | LD50 (median dose): Oral-rat LD50: 2500 mg/kg |
| NIOSH | RT8750000 |
| PEL (Permissible) | 15 mg/m³ |
| REL (Recommended) | 70 mg/kg |
| IDLH (Immediate danger) | No IDLH established. |
| GHS labelling | GHS Labelling: "Not a hazardous substance or mixture according to the Globally Harmonized System (GHS) |
| Pictograms | GHS07,GHS08 |
| Signal word | Warning |
| Precautionary statements | P264, P270, P301+P312, P330 |
| NFPA 704 (fire diamond) | 1-0-0 |
| Lethal dose or concentration | LD50 (oral, rat): 4800 mg/kg |
| LD50 (median dose) | LD50 (median dose): Oral-rat LD50: 4300 mg/kg |
| NIOSH | WH8225000 |
| PEL (Permissible) | 15 mg/m³ |
| REL (Recommended) | 70 mg/kg |
| IDLH (Immediate danger) | No IDLH established. |
| Related compounds | |
| Related compounds |
Potassium tartrate Tartaric acid Sodium bitartrate Calcium tartrate |
| Related compounds |
Potassium tartrate Tartaric acid Sodium bitartrate Sodium tartrate |