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Material Safety Data Sheet (MSDS): Polyglycerol Esters Of Fatty Acids

Identification

Chemical Name: Polyglycerol Esters of Fatty Acids
Common Names: PGE, Polyglycerol Fatty Acid Esters
CAS Number: 67784-82-1
Product Codes: FDA food additive categories, E475
Recommended Use: Emulsifier in food, pharmaceuticals, cosmetics
Supplier: Manufacturer and distributor details with emergency phone contacts
Contact for SDS: Safety officer, regulatory compliance desk

Hazard Identification

Classification (GHS): Not classified as hazardous
Physical Hazards: No significant physical hazard under normal handling
Health Hazards: May cause mild eye or skin irritation in sensitive individuals
Environmental Hazards: Low risk for aquatic and terrestrial animals
Label Elements: No obligatory hazard pictograms, signal word: none
Precautionary Statements: Avoid unnecessary exposure, use personal protective equipment in industrial settings

Composition / Information on Ingredients

Ingredient: Polyglycerol Esters of Fatty Acids
Chemical Formula: Variable, based on fatty acid and polyglycerol sources
Purity: Minimum 90% active ingredient
Impurities: Glycerol, free fatty acids below 3% total content
Additives: No preservatives, no artificial colors or flavors

First Aid Measures

Inhalation: Move person to fresh air, seek medical attention if symptoms develop
Skin Contact: Wash area with plenty of water, remove contaminated clothing, contact physician if irritation persists
Eye Contact: Rinse eyes thoroughly with water for several minutes, contact a healthcare professional if pain or redness continues
Ingestion: Drink water to dilute, do not induce vomiting, consult a medical professional if adverse symptoms arise
Note to Physician: Symptomatic treatment only, no specific antidote known

Fire-Fighting Measures

Suitable Extinguishing Media: Carbon dioxide, foam, dry chemical powder, water spray
Unsuitable Media: High-pressure water jets may spread material
Specific Hazards: Combustion may generate carbon monoxide and carbon dioxide
Protective Equipment: Firefighters should use self-contained breathing apparatus and full protective gear
Special Procedures: Cool containers near flame with water spray; avoid inhaling vapors or smoke

Accidental Release Measures

Personal Precautions: Wear gloves, goggles, avoid skin and eye contact
Environmental Precautions: Prevent entry into drains, waterways, or soil
Methods for Cleaning Up: Absorb with inert material such as sand, scoop into suitable disposal containers, wash area with water and detergent
Spill Sizes: For large release, contain using dikes, notify local authorities
Disposal: Dispose of waste in accordance with local and national regulations

Handling and Storage

Handling: Use only with adequate ventilation, minimize spills, avoid ingestion and contact with eyes
Personal Hygiene: Wash hands after working, remove contaminated clothing
Storage: Store in tightly closed containers in a cool, dry, well-ventilated place away from sources of ignition
Incompatibilities: Keep away from strong oxidizers, acids
Storage Life: Best within manufacturer’s shelf-life, typically 24 months

Exposure Controls and Personal Protection

Exposure Limits: No occupational exposure limit assigned
Engineering Controls: Local exhaust ventilation recommended for large-scale use
Personal Protective Equipment: Safety glasses, gloves, apron in industrial settings
Respiratory Protection: Not required under normal conditions, NIOSH-approved mask in case of mist formation
Hygiene Measures: Maintain clean working environment, mandatory hand-washing before eating or drinking

Physical and Chemical Properties

Form: Waxy solid, flakes, or viscous liquid depending on grade
Color: White to pale yellow
Odor: Mild fatty characteristic
Melting Point: Range from 55°C to 70°C
Boiling Point: Decomposes before boiling
Solubility: Insoluble in water, dispersible in hot water, soluble in ethanol and oils
pH: Not applicable (insoluble in water)
Viscosity: High, increases substantially with concentration
Flash Point: Typically above 220°C
Relative Density: 0.96–1.01 g/cm³ (at 25°C)

Stability and Reactivity

Chemical Stability: Stable under normal use and storage
Conditions to Avoid: High heat, open flame, direct sunlight
Incompatible Materials: Strong oxidizing agents, concentrated acids
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide under fire conditions
Polymerization: Will not occur

Toxicological Information

Acute Toxicity: Low oral toxicity; LD50 (oral, rat) > 5000 mg/kg
Local Effects: Possible mild irritation to skin and eyes
Sensitization: Rare allergic responses reported
Chronic Effects: No evidence of carcinogenicity, mutagenicity, or reproductive toxicity
Routes of Exposure: Oral, dermal, ocular contact
Medical Conditions Aggravated: Pre-existing skin conditions may be aggravated on contact

Ecological Information

Environmental Fate: Readily biodegradable, breaks down into glycerol and fatty acids
Bioaccumulation: Low potential in aquatic or terrestrial organisms
Aquatic Toxicity: No evidence of acute or chronic harm in aquatic species at environmental concentrations
Soil Mobility: Low mobility, material tends to bind to soil
Other Effects: No known adverse effects on plants or wildlife

Disposal Considerations

Waste Disposal: Handle as non-hazardous waste under most circumstances, observe local regulations
Container Disposal: Triple rinse empty containers, dispose via reconditioning or landfill as permitted
Recycling: Not feasible for used product, clean uncontaminated product may be recyclable
Precaution: Prevent product from entering natural water sources or sewage system during disposal

Transport Information

UN Number: Not subject to UN regulations
Transport Hazard Class: Not regulated as hazardous
Packing Group: Not applicable
Shipping Name: Polyglycerol Esters Of Fatty Acids
Special Precautions: Protect from overheating, avoid package rupture during transport

Regulatory Information

EU Classification: Not classified under CLP Regulation
US FDA Status: Approved as food additive under 21 CFR 172.854
TSCA Status: Listed in the US Toxic Substances Control Act Inventory
Canada: DSL/NDSL listed
Other Regulations: Subject to REACH registration in the European Union, recognized under accepted food safety standards worldwide
Labelling: No hazard labeling required for finished food products, industrial labeling for raw bulk shipments
Worker Safety: OSHA-compliant information on workplace handling and safety practices