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Phosphated Distarch Phosphate – Material Safety Data Sheet (MSDS)

Identification

Product Name: Phosphated Distarch Phosphate
Chemical Family: Modified Starch
Synonyms: E1413, Phosphate Starch
CAS Number: 55963-33-2
Recommended Use: Food industry thickener, binder for pharmaceuticals and paper, general industrial applications
Supplier Information: Name, address, emergency contact number of manufacturer or distributor, along with website for documentation access and SDS request.

Hazard Identification

Classification: Not classified as hazardous under GHS. Not considered dangerous for supply or conveyance.
Physical Hazards: Dust may form explosive mixtures with air.
Health Hazards: Inhalation of dust could irritate respiratory tract, mechanical irritation to eyes or skin may occur with direct contact.
Environmental Hazards: Not classified as hazardous to the environment, spills in large amounts could cause surface water clogging or sediment buildup.
Label Elements: Not required under normal use. No hazard pictograms, signal words, or hazard statements mandated.
Other Hazards: Fine dust has a potential for dust explosion risk, especially in confined or poorly ventilated environments.

Composition / Information on Ingredients

Chemical Name: Phosphated Distarch Phosphate
Common Names: Modified Starch, E1413, Phosphate Starch
Ingredient Percentage: 97–100% by weight
Impurities and Stabilizing Additives: May contain trace moisture, negligible sodium tripolyphosphate (<0.5%), non-reactive minor process residuals
Molecular Formula: (C6H10O5)n (phosphate groups cross-linked)
Physical State: Fine white to off-white powder or granule, nearly odorless

First Aid Measures

Inhalation: Move affected person to fresh air, ensure they remain calm and breathe normally, seek medical attention for persistent irritation, rinse mouth if necessary
Skin Contact: Wash skin with water and mild soap; remove contaminated clothing and launder before reuse; if irritation develops, see a physician
Eye Contact: Immediately flush eyes with plenty of running water for at least 15 minutes, hold eyelids open, remove contact lenses, consult a doctor for prolonged discomfort
Ingestion: Rinse mouth with water, drink water to dilute, do not induce vomiting, obtain medical help if feeling unwell
Most Important Symptoms: Possible discomfort from dryness or mild irritation of mucous membranes; no known serious acute effects under normal use
Notes for Physician: Treat symptomatically, no antidote known, product has low toxicity

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide; avoid high-pressure water streams to minimize dust formation
Hazards from Combustion: Burning can produce carbon dioxide, carbon monoxide, minor phosphorus oxides
Protective Equipment: Wear respirator, protective clothing, eye protection, gloves if exposed to smoke or powders
Firefighting Advice: Cool nearby containers with water, evacuate area for large fires, prevent run-off from spreading to drains or natural water sources
Special Notes: Dust may be explosive if suspended in air and ignited; minimize dust cloud formation.

Accidental Release Measures

Personal Precautions: Use dust masks, protective eyewear, and gloves; avoid inhalation of dust and unnecessary contact with skin or eyes
Environmental Precautions: Prevent significant spillage from entering water systems, sewers, open drains
Methods for Clean-up: Gently sweep or vacuum up material and place in airtight labeled containers for disposal; use gentle, damp sweeping where possible to reduce airborne dust
Spill Size Response: For minor spills, sweep up immediately; for large releases, cordon off area, deploy appropriate dust controls, and notify authorities according to local regulations
Disposal: Collect waste in sealed drums, avoid flushing with water that may disperse material, dispose according to Section 13.

Handling and Storage

Handling Practices: Avoid dust creation, use with local exhaust ventilation where handling or transferring powders, wear appropriate PPE for eye and respiratory protection in bulk processing
Storage Recommendations: Store in cool, dry, well-ventilated places, keep containers tightly closed and protected from moisture; avoid mineral acids or strong oxidizers nearby
Incompatibilities: Strong acids, strong oxidizers, combustible dusts; do not mix with incompatible chemicals
General Hygiene: Wash hands thoroughly after handling, keep good housekeeping standards in work areas to prevent dust accumulation
Packaging Materials: Use moisture-resistant packaging, label containers clearly for identification and hazard prevention.

Exposure Controls and Personal Protection

Exposure Limit Values: No specific regulatory limits for modified starch; use general nuisance dust standards—ACGIH TLV: 10 mg/m³ (inhalable) and 3 mg/m³ (respirable fraction)
Engineering Controls: Use local exhaust or general room ventilation to maintain airborne dust levels below exposure limits; implement process enclosure if needed
Personal Protective Equipment (PPE): Dust mask or particulate respirator (NIOSH-approved), protective eyewear (goggles or safety glasses), gloves for extended handling, washable workwear
Environmental Controls: Prevent run-off to public water systems, avoid dust dispersion by maintaining doors and windows closed during transfers
Other Precautions: Replace PPE regularly, maintain clean change areas for staff, provide emergency eye wash and shower stations in processing areas.

Physical and Chemical Properties

Appearance: White to off-white, fine powder or granule
Odor: Virtually odorless
Odor Threshold: Not established
pH: 5.0 – 8.0 in aqueous suspension
Melting/Freezing Point: Decomposes before melting; starch does not have a definite melting point
Boiling Point: Not applicable (solid material)
Flash Point: Not applicable; will only burn following ignition as dust cloud
Flammability: Dust may be combustible in air; risk of explosion with suspended dust
Vapor Pressure: Not relevant
Solubility: Swells in cold water, partially dispersible; better dispersibility in hot water
Partition Coefficient: Not applicable
Density: 0.5 – 0.7 g/cm³ (bulk density)
Explosive Properties: Dust may become explosive in confined areas with ignition source
Other Data: Slightly hygroscopic, absorbs atmospheric moisture if exposed

Stability and Reactivity

Chemical Stability: Stable in normal storage and handling conditions
Reactivity: Not reactive with most chemicals under ambient conditions
Conditions to Avoid: Elevated temperatures, sources of ignition or open flame, high humidity, accidental mixing with incompatible chemicals such as strong acids or oxidizers
Incompatible Materials: Mineral acids, chlorine, strong oxidizing agents
Hazardous Decomposition Products: Burning forms CO, CO₂, minor phosphate vapors
Hazardous Reactions: None expected during typical processing or industrial use

Toxicological Information

Acute Toxicity: No evidence of acute toxicity; oral LD50 in rats >2000 mg/kg, considered biologically inert
Skin Corrosion/Irritation: Non-irritant to skin, though mechanical dryness possible with repeated contact
Serious Eye Damage/Irritation: May cause discomfort from particulates, reversible on rinsing
Respiratory Sensitization: No indication of respiratory sensitization in animal or human data; dust may cause transient irritation
Germ Cell Mutagenicity: No known mutagenic effects
Carcinogenicity: Not listed by IARC, NTP, OSHA
Reproductive Toxicity: No adverse reproductive effects reported
Repeated Dose Toxicity: No observed adverse effects with subchronic or chronic dietary exposure
Other Health Effects: Ingestion in significant volumes may cause mild gastrointestinal discomfort; not expected at typical exposure levels.

Ecological Information

Ecotoxicity: Not expected to be bioaccumulative, toxic to aquatic life, or persistent in the environment; derived from starches, readily biodegradable through normal microbiological processes
Persistence and Degradability: Readily biodegradable by soil and aquatic microorganisms
Bioaccumulation Potential: Low potential; hydrolyzed and assimilated rapidly in environmental conditions
Mobility in Soil: Limited mobility; solid particles settle quickly, degrade biologically
Other Adverse Effects: Substantial dumping may physically blanket water bodies by sedimentation, impacting oxygenation or visibility.

Disposal Considerations

Waste Disposal Methods: Dispose through landfill according to local/national regulations for non-hazardous solid waste; avoid incineration unless controlled due to dust combustion characteristics
Product Disposal: Do not discharge into drains, sewers, or waterways; avoid contaminating natural water sources
Contaminated Packaging: Clean and recycle packaging where possible; otherwise, treat as solid waste
Regulatory Compliance: Always follow waste disposal laws and consult environmental authorities for proper protocol
Environmentally Responsible Practices: Seek routes for composting or energy recovery in food waste streams where feasible.

Transport Information

UN Number: None assigned (not classified as a dangerous good)
Proper Shipping Name: Phosphated Distarch Phosphate
Transport Hazard Class: Not regulated for transport under ADR, IMDG, IATA
Packing Group: Not applicable
Environmental Hazards: None; bulk transport considerations center on dust hazard in air
Special Precautions for User: Secure packaging to prevent breakage or spillage; minimize dust formation during loading or unloading
Transport in Bulk: Follow best practice to prevent moisture ingress, which may cause caking or fermentation

Regulatory Information

International Inventories: Listed on EU EINECS/ELINCS, US TSCA, Canadian DSL/NDSL, Australian AICS, Chinese IECSC, Japanese ENCS
Regulations: Approved as a food additive (E1413) in many global regions; not classified as hazardous under OSHA, EU CLP, or GHS
Workplace Safety: Subject to general workplace dust regulatory limits; OSHA nuisance dust limits apply
Environmental Laws: No specific restrictions; observe waste, water discharge, and packaging management regulations
Other Requirements: Ensure product usage and disposal matches local, state, federal, or international standards; maintain updated safety documentation onsite.