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Material Safety Data Sheet (MSDS): Monocalcium Phosphate (MCP)

Identification

  • Product Name: Monocalcium Phosphate
  • Chemical Formula: Ca(H₂PO₄)₂·H₂O
  • Other Names: MCP, Calcium Dihydrogen Phosphate
  • CAS Number: 7758-23-8
  • Recommended Use: Feed additive, fertilizer, leavening agent, food additive
  • Supplier: Contact details provided on request
  • Emergency Contact: Usually accessible through national poison control centers

Hazard Identification

  • Classification: Not classified as hazardous under GHS
  • Main Hazards: Can cause irritation to eyes, skin, and respiratory tract
  • Pictograms: No GHS symbols required in most jurisdictions
  • Signal Word: None required
  • Hazard Statements: May irritate eyes upon direct contact; inhaling large amounts may irritate respiratory passages
  • Precautionary Statements: Avoid generating dust, avoid eye contact, wash hands thoroughly after handling

Composition / Information on Ingredients

  • Main Ingredient: Monocalcium Phosphate (Ca(H₂PO₄)₂·H₂O)
  • Content: 98-100%
  • Impurities: May contain trace amounts of dicalcium phosphate, calcium sulfate, water
  • Other Ingredients: No hazardous impurities above reporting thresholds

First Aid Measures

  • Inhalation: Remove to fresh air, seek medical attention for symptoms including difficulty breathing
  • Skin Contact: Wash affected area with plenty of water and soap
  • Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present, continue rinsing, seek medical advice if irritation persists
  • Ingestion: Rinse mouth, never induce vomiting unless directed by medical personnel, consult a physician if substantial quantities are swallowed
  • Most Important Symptoms: Eye redness, mild respiratory discomfort, possible mild skin dryness

Fire-Fighting Measures

  • Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
  • Special Hazards: Material itself does not burn, but packaging may combust
  • Hazardous Combustion Products: Phosphorus oxides, calcium oxides released during heating
  • Protective Equipment: Wear self-contained breathing apparatus and full protective clothing if exposed to smoke or fumes
  • Firefighting Instructions: Avoid breathing vapors or dust, prevent runoff into waterways

Accidental Release Measures

  • Personal Precautions: Use protective gloves, goggles, dust mask; avoid breathing dust
  • Environmental Precautions: Prevent spillage from entering drains, surface water, or soil
  • Methods for Cleaning Up: Sweep or shovel into suitable container, avoid raising dust, wash affected area with abundant water
  • Disposal: See section on disposal considerations

Handling and Storage

  • Precautions for Safe Handling: Avoid contact with eyes and skin, prevent dust formation, ensure adequate ventilation in workplaces
  • Safe Storage Conditions: Store in a dry, cool, well-ventilated area away from strong alkalis and moisture
  • Packaging Materials: Use containers that keep material dry and protected from contamination
  • Special Considerations: Keep out of reach of children and unauthorized personnel

Exposure Controls and Personal Protection

  • Occupational Exposure Limits: No specific occupational exposure limit values set for MCP, use dust limits for nuisance particulates (typically 10 mg/m³ total dust, 3 mg/m³ respirable dust)
  • Engineering Controls: Local exhaust ventilation recommended, closed system operations preferred for bulk handling
  • Personal Protective Equipment: NIOSH approved dust mask, safety goggles, chemical-resistant gloves, work clothing covering arms and legs
  • Hygiene Measures: Wash hands before eating, drinking, or smoking, launder contaminated clothing regularly

Physical and Chemical Properties

  • Appearance: White crystalline powder, sometimes granular
  • Odor: Odorless
  • Molecular Weight: 252.07 g/mol (monohydrate)
  • pH: Typically 2.5–4.5 (1% solution)
  • Melting Point: Decomposes before melting
  • Solubility: Slightly soluble in water, insoluble in alcohol
  • Bulk Density: 900–1200 kg/m³
  • Boiling Point: Not applicable
  • Vapor Pressure: Negligible
  • Autoignition Temperature: Not applicable
  • Explosive Properties: Not explosive
  • Oxidizing Properties: Not oxidizing

Stability and Reactivity

  • Chemical Stability: Stable under normal conditions
  • Reactivity: Reacts with strong alkalis forming calcium phosphate precipitate and releasing heat
  • Incompatible Materials: Alkaline substances, strong oxidizers
  • Decomposition Products: Phosphorus oxides, calcium oxides with strong heating
  • Conditions to Avoid: Excessive heat, incompatible chemicals, moisture to prevent caking

Toxicological Information

  • Acute Toxicity: Not acutely toxic; oral LD₅₀ (rat) estimated >5,000 mg/kg
  • Chronic Toxicity: Long-term exposure to excessive dust may cause mild irritation to lungs and eyes
  • Skin Corrosion/Irritation: Mild irritant on prolonged or repeated contact
  • Eye Damage/Irritation: Can cause redness or temporary discomfort
  • Respiratory or Skin Sensitization: Not classified as a sensitizer
  • Carcinogenicity: Not listed as carcinogenic by IARC, NTP, OSHA
  • Mutagenicity/Teratogenicity: No data suggesting mutagenic or teratogenic effects at occupational exposures

Ecological Information

  • Ecotoxicity: Low environmental toxicity; large discharges can encourage algae growth in water bodies
  • Persistence and Degradability: Inorganic phosphate becomes permanently bound in soils, not biodegradable
  • Bioaccumulative Potential: Not expected to bioaccumulate
  • Mobility in Soil: Moderate; can migrate in soil under certain conditions, especially in runoff
  • Other Adverse Effects: Excessive runoff may contribute to eutrophication in lakes and reservoirs

Disposal Considerations

  • Waste Disposal: Dispose of product in accordance with local, regional, national, and international regulations for non-hazardous mineral substances
  • Contaminated Packaging: Rinse thoroughly before recycling or disposal
  • Special Considerations: Prevent release of large quantities to sewage systems or waterways
  • Preferred Disposal Methods: Landfill in designated areas or apply to land as appropriate for fertilizer use (subject to regulations)

Transport Information

  • UN Number: Not regulated for transport
  • Transport Hazard Class: Non-hazardous according to transport regulations
  • Packing Group: Not classified
  • Environmental Hazards: None identified for transport
  • Special Precautions for User: Protect from moisture during transit, use sealed containers

Regulatory Information

  • Labeling Requirements: Not classified as dangerous for supply or transport
  • Global Inventory Status: Listed in TSCA (USA), EINECS (EU), DSL (Canada), AICS (Australia), ENCS (Japan), and other chemical inventories
  • Workplace Regulations: Handle according to standard industrial hygiene and safety practices
  • US OSHA: Not regulated as a hazardous substance
  • EU Reach: Registered under applicable uses
  • Other National Inventories: Check for local or specific country requirements if outside above jurisdictions