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Material Safety Data Sheet (MSDS) – Magnesium Citrate

Identification

Chemical Name: Magnesium Citrate
Chemical Formula: C6H6MgO7
CAS Number: 3344-18-1
Synonyms: Magnesium (II) citrate, Magnesium 2-hydroxypropane-1,2,3-tricarboxylate
Recommended Use: Food additive, dietary supplement, pharmaceutical ingredient, laboratory uses
Company Contact Information: Manufacturer or distributor information and emergency contact number should be listed here to provide single-point access in case of urgent queries.

Hazard Identification

Hazard Classification: Not classified as hazardous under GHS
Physical Hazards: May form dust that can irritate airways
Health Hazards: May cause mild gastrointestinal irritation if ingested in large amounts; contact may cause minor skin or eye irritation; inhalation of large quantities of dust could cause mild respiratory discomfort
Environmental Hazards: No significant environmental hazard expected in small quantities

Composition / Information on Ingredients

Chemical Name: Magnesium Citrate
Concentration: Pure compound, typically above 98%
Impurities or Stabilizing Additives: No relevant impurities present which affect hazard classification
Molecular Weight: 214.41 g/mol

First Aid Measures

Eye Contact: Flush eyes with plenty of water for at least 15 minutes; remove contact lenses if present and easy to do
Skin Contact: Wash affected skin with soap and water
Inhalation: Move person to fresh air; seek medical attention if irritation develops or symptoms persist
Ingestion: Rinse mouth with water; seek medical attention if unnecessarily large quantities have been ingested and symptoms appear
General Advice: Get medical attention if adverse symptoms persist after exposure

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Extinguishing Media: None known for magnesium citrate specifically
Specific Hazards: Fine dust may form explosive mixtures with air under certain conditions
Special Protective Equipment: Firefighters should wear standard protective equipment and self-contained breathing apparatus
Hazardous Combustion Products: May form irritating or toxic fumes when exposed to fire

Accidental Release Measures

Personal Precautions: Avoid creating dust; use personal protective equipment such as gloves and safety goggles
Environmental Precautions: Prevent spillage from entering drains or surface water to limit unnecessary contamination
Containment and Cleanup: Sweep up and collect the material for suitable disposal; ventilate area; wash spill site after removal; do not dry sweep to minimize airborne dust; use vacuum equipped with HEPA filter

Handling and Storage

Safe Handling: Handle in well-ventilated areas; minimize dust generation; wear appropriate personal protective equipment
Storage: Store in tightly sealed containers in cool, dry, well-ventilated areas away from incompatible substances such as strong acids; keep containers tightly closed when not in use; avoid sources of ignition
Incompatibilities: Strong acids, strong oxidizing agents

Exposure Controls and Personal Protection

Occupational Exposure Limits: No specific regulatory exposure limits established; maintain dust levels below OSHA nuisance dust limits
Engineering Controls: Provide exhaust ventilation or other engineering controls to keep airborne concentrations low
Personal Protective Equipment (PPE): Eye protection (safety glasses or goggles), protective clothing as needed, gloves, dust mask or respiratory protection for high dust levels
Hygiene Measures: Wash hands and face thoroughly after handling; remove contaminated clothing and protective equipment before eating or drinking

Physical and Chemical Properties

Appearance: White to off-white crystalline powder
Odor: Odorless
Odor Threshold: Not applicable
pH: Mildly acidic in solution
Melting Point/Freezing Point: Decomposes on heating, does not have a melting point under normal pressure
Boiling Point: Not applicable
Flash Point: Not flammable
Solubility: Moderately soluble in water
Vapor Pressure: Not applicable
Specific Gravity: Approximately 1.8 (water = 1)
Partition Coefficient (n-octanol/water): Not determined
Evaporation Rate: Not applicable
Auto-ignition Temperature: Not self-igniting
Decomposition Temperature: Approximately 180-200°C
Viscosity: Not applicable

Stability and Reactivity

Stability: Stable under recommended storage conditions
Reactivity: Inert under normal conditions
Hazardous Reactions: May react with strong oxidizers or strong acids
Conditions to Avoid: Excessive heat, humidity that could lead to clumping
Incompatible Materials: Strong acids, strong oxidizing agents
Hazardous Decomposition Products: Carbon oxides, magnesium oxides, irritating fumes if strongly heated or burned

Toxicological Information

Likely Routes of Exposure: Ingestion, inhalation, skin and eye contact
Acute Toxicity: Low toxicity by oral route; may produce mild gastrointestinal effects (nausea, diarrhea) in excessive doses
Skin Corrosion/Irritation: Minimal to no irritation
Serious Eye Damage/Irritation: May cause mild irritation by mechanical action
Respiratory or Skin Sensitization: No data indicating allergenic potential
Chronic Effects: No long-term health effects reported for normal exposure levels
Carcinogenicity: Not listed as a carcinogen by IARC, NTP, OSHA
Mutagenicity: No data indicating mutagenic risk
Reproductive Toxicity: No effects anticipated at normal exposure levels

Ecological Information

Ecotoxicity: Low risk to aquatic and terrestrial organisms due to low solubility and minimal toxicity
Persistence and Degradability: Readily biodegradable under most environmental conditions
Bioaccumulative Potential: Not expected to bioaccumulate significantly
Mobility in Soil: Moderate mobility if leached by groundwater
Other Adverse Effects: No known significant adverse environmental impact

Disposal Considerations

Waste Treatment Methods: Dispose of as non-hazardous chemical waste in accordance with local, regional, and national regulations
Contaminated Packaging: Rinse containers thoroughly before disposal; recycle if possible or dispose of as permitted by local regulations
Special Precautions: Avoid discharge to surface waters; prevent large releases to the environment

Transport Information

UN Number: Not regulated
UN Proper Shipping Name: Not regulated for transport
Transport Hazard Class: Not applicable
Packing Group: Not assigned
Marine Pollutant: No
Transport Precautions: Protect from physical damage and moisture during transport; otherwise standard precautions for dust-generating powders apply

Regulatory Information

TSCA (Toxic Substances Control Act): Listed
DSL/NDSL (Canada): Listed
ECHA REACH: Exempt as a food and pharmaceutical ingredient
OSHA Hazard Communication: Not defined as hazardous
SARA Title III: Not classified as a hazardous substance
California Proposition 65: Not listed
EU Classification: Not hazardous under Regulation (EC) No 1272/2008 (CLP)
Labeling Requirements: Standard chemical labeling practices apply; ensure the presence of identification and hazard labeling where required