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Material Safety Data Sheet (MSDS)

Linolenic Acid Ethyl Ester

Identification

Product Name: Linolenic Acid Ethyl Ester
Synonyms: Ethyl 9,12,15-octadecatrienoate
CAS Number: 1191-41-9
Recommended Use: Laboratory research, manufacturing of nutritional supplements, raw material for chemical synthesis
Manufacturer: [Insert actual producer if known]
Contact Information: Emergency response phone, supplier contact address needed in workplace practices

Hazard Identification

Classification: Eye irritant (Category 2B), Skin irritant (Category 2), Not considered a hazardous substance under standard GHS guidelines
Signal Word: Warning
Hazard Statements: May cause skin irritation, may cause eye irritation, exposure through inhalation unlikely due to low volatility
Pictograms: Exclamation mark (irritation warning)
Precautionary Statements: Avoid breathing vapors, wear protective gloves and eye protection, wash hands thoroughly after handling
Potential Health Effects: Prolonged or repeated contact can cause dermatitis, redness, or mild allergic reaction in sensitive individuals

Composition / Information on Ingredients

Chemical Name: Linolenic Acid Ethyl Ester
Concentration: ≥98%
Impurities: May contain minor related fatty acid esters; no hazardous contaminants expected above reportable thresholds
Molecular Formula: C20H34O2
Molecular Weight: 306.5 g/mol

First Aid Measures

Inhalation: Remove individual to fresh air if symptoms occur, seek medical advice if discomfort persists
Skin Contact: Rinse area with soap and water, remove contaminated clothing, seek medical attention for persistent irritation
Eye Contact: Rinse gently with running water for 15 minutes, remove contact lenses if easy, get medical attention if irritation develops
Ingestion: Rinse mouth, drink water, do not induce vomiting, seek medical attention if feeling unwell or if large amount is swallowed
Notes for Physician: Symptomatic treatment, monitor for signs of sensitization or allergic reaction

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide to extinguish
Unsuitable Media: Avoid direct water jet as it may spread burning liquid
Specific Hazards: Can release acrid smoke, carbon monoxide, and carbon dioxide upon thermal decomposition
Protective Equipment: Firefighters should wear self-contained breathing apparatus and protective gear
Advice for Firefighters: Keep containers cool using water spray, prevent runoff into drains or water sources

Accidental Release Measures

Personal Precautions: Wear gloves and eye protection; avoid contact with skin or eyes
Environmental Precautions: Prevent product from entering soil, sewers, surface, or groundwater
Containment: Absorb spill with earth, inert material, or vermiculite; shovel into appropriate waste containers
Clean-Up Method: Wash spill area thoroughly after collection; ventilate enclosed spaces if necessary
Disposal: Dispose of as chemical waste under local regulations

Handling and Storage

Safe Handling: Use in well-ventilated area, avoid inhalation and direct skin contact, handle with care
Storage Conditions: Store tightly sealed in a cool, dry, well-ventilated place, keep container away from sources of ignition
Incompatibilities: Strong oxidizers, strong acids and bases may trigger hazardous reactions
Hygiene: Wash hands after handling, do not eat, drink, or smoke during use
Other Precautions: Keep out of reach of children, use only as directed

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits
Engineering Controls: Use local exhaust for laboratory handling, ensure adequate air exchange in storage or prep rooms
Respiratory Protection: Not typically required; use respirator if aerosol or mist formation likely
Hand Protection: Wear chemical-resistant gloves
Eye Protection: Use goggles or safety glasses
Skin Protection: Wear lab coat or protective clothing to limit skin exposure
General Safety: Maintain good industrial hygiene, wash with soap after handling

Physical and Chemical Properties

Appearance: Pale yellow to clear oily liquid
Odor: Mild, vegetable oil-like
Odor Threshold: Not determined
pH: Not applicable (non-aqueous)
Melting Point/Freezing Point: About -20 °C
Boiling Point: 160-220 °C (at reduced pressure)
Flash Point: >150 °C (closed cup)
Evaporation Rate: Not measured (non-volatile)
Flammability: May ignite at high temperature
Vapor Pressure: Very low at ambient
Density: Around 0.89-0.92 g/cm³ at 20°C
Solubility: Insoluble in water, soluble in ethanol and organic solvents
Partition Coefficient (log Kow): Estimated high (lipophilic)
Autoignition Temperature: About 380 °C
Decomposition Temperature: Not tested; avoid heating above boiling point
Viscosity: Slightly viscous at room temperature

Stability and Reactivity

Chemical Stability: Stable under recommended conditions, sensitive to air, light, and heat causing slow oxidative degradation
Reactivity: Can form peroxides over long storage if exposed to oxygen or UV
Conditions to Avoid: Excessive heat, open flame, prolonged exposure to air or sunlight
Incompatible Materials: Strong oxidizers, chlorine, peroxides, alkalis
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acrolein and other aldehyde vapors under fire condition
Polymerization: Not known to occur

Toxicological Information

Acute Toxicity: Low toxicity by oral and dermal routes, not expected to be acutely toxic in standard animal studies
Routes of Exposure: Contact with skin and eyes, accidental ingestion
Symptoms: Redness or irritation of affected skin, temporary eye irritation, headache if handled in bulk with limited ventilation
Chronic Effects: No evidence of long-term or cumulative toxicity in repeated-use scenarios; nutritional studies indicate safety as food additive at usual levels
Sensitization: Not fully characterized; skin allergies unlikely but possible with repeat exposure
Mutagenicity: Studies have not shown genetic damage
Carcinogenicity: Not classified as carcinogen by IARC, NTP, OSHA

Ecological Information

Ecotoxicity: Readily biodegradable, no evidence of bioaccumulation, low aquatic toxicity expected based on chemical structure
Behavior in Environment: Tends to absorb into soil and degrade by natural microbial action
Mobility: Low mobility in soil due to high partition coefficient
Persistence and Degradability: Not persistent, breaks down rapidly in presence of air, light, and microorganisms
Potential for Bioaccumulation: Minimal
Aquatic Toxicity: No known risk to aquatic organisms at expected environmental concentrations

Disposal Considerations

Disposal Methods: Incineration or landfill in accordance with local, state, and national regulations
Waste Code: Classified as non-hazardous waste under most regulations, keep separate from solvents and oils with toxic additives
Container Disposal: Rinse thoroughly before recycling or discarding, do not reuse unless cleaned
Precautions: Avoid entry into streams, soil or drainage systems, handle waste responsibly

Transport Information

UN Number: Not assigned
UN Proper Shipping Name: Not regulated as dangerous goods
Transport Hazard Class: Not classified
Packing Group: Not applicable
Environmental Hazards: Not a marine pollutant
Bulk Transport: No special restrictions, transport in sealed containers to prevent leaks and exposure
Special Precautions: Standard practices for bulk oils apply

Regulatory Information

Inventory Listings: Listed on TSCA, EINECS/ELINCS, DSL, AICS
Regulatory Status: Not regulated as hazardous under GHS, OSHA, or WHMIS
Right-to-Know Information: Not listed as a substance of concern in major jurisdictions
Labeling Requirements: Basic identification and safety handling information, no specific hazard symbols beyond eye or skin irritant if required
Other Regulations: Safe for use in contact with food under certain national regulations, subject to purity standards when used as a food additive