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Material Safety Data Sheet: Glycerol Ester Of Hydrogenated Rosin

Identification

Product Name: Glycerol Ester Of Hydrogenated Rosin
Chemical Family: Modified Natural Rosin Ester
CAS Number: 65997-13-9
EC Number: 500-162-5
Recommended Uses: Used in adhesives, food packaging, inks, coatings, cosmetics, chewing gum
Supplier Details: Manufacturer and contact information found on product label or SDS footer
Emergency Contact: Company-specific emergency telephone, national poison control

Hazard Identification

Classification: Not classified as dangerous or hazardous according to global chemical regulations including GHS
Physical Hazards: May form combustible dust concentrations in air
Health Hazards: Can cause mild eye irritation and mild skin irritation after repeated or prolonged contact
Environmental Hazards: No immediate environmental hazards identified; use proper containment in spills
Signal Word: None required by current standards
Hazard Statements: May cause mild irritation, handle with care; dust may irritate respiratory system
Precautionary Statements: Avoid dust generation, use ventilation, wash hands after handling

Composition / Information on Ingredients

Chemical Identity: Glycerol Ester Of Hydrogenated Rosin
Component: Glycerol, Rosin (hydrogenated)
Concentration: More than 95% by weight
Impurities: Small traces of unreacted rosin acids, glycerol compounds, possible trace organic impurities

First Aid Measures

Inhalation: Move person to fresh air, seek medical advice if symptoms persist
Eye Contact: Rinse gently with plenty of water for several minutes, remove contact lenses if present, get medical attention if irritation occurs
Skin Contact: Wash thoroughly with soap and water, remove contaminated clothing
Ingestion: Rinse mouth, drink water to dilute, do not induce vomiting, get medical help if symptoms appear
Medical Attention: Treat symptoms, no specific antidote known
Most Important Symptoms: Mild irritation to eyes or skin, cough or sneeze from dust inhalation

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Extinguishing Media: Direct water jet for large fires
Specific Hazards: Product may form combustible dust clouds; during combustion, may produce CO, CO2, and irritating fumes
Firefighter Precautions: Wear full protective gear, use self-contained breathing apparatus in confined space
Special Procedures: Avoid smoke inhalation, contain water runoff
Explosion Data: Fine dust can create explosion hazard; avoid static discharge

Accidental Release Measures

Personal Precautions: Avoid dust inhalation and contact with skin or eyes, ventilate area, use personal protection
Environmental Precautions: Prevent further spillage, avoid drainage into water bodies or sewers
Cleanup Methods: Sweep up material without dust generation, collect for safe disposal; use damp cloths or vacuum with explosion-proof equipment
Waste Handling: Place in labeled containers for recovery or disposal; follow local waste regulations

Handling and Storage

Handling: Minimize dust creation and accumulation, use local exhaust ventilation, wash hands before eating or drinking, use safe lifting when handling bulk bags
Storage: Store in cool, dry, well-ventilated area, protect from direct sunlight and moisture, keep container tightly closed, keep away from heat and ignition sources
Storage Incompatibilities: Strong oxidizers, strong acids
Special Notes: Keep away from food and animal feed, use original containers where possible

Exposure Controls and Personal Protection

Occupational Exposure Limits: No specific exposure limits set for this product; use nuisance dust limits of 10 mg/m3 (total dust, inhalable)
Engineering Controls: Provide local exhaust ventilation, maintain good general room ventilation
Eye Protection: Use chemical splash goggles where dust or splatter may occur
Skin Protection: Wear gloves and protective clothing for prolonged or repeated contact
Respiratory Protection: Use dust mask (P2 or N95) where dust levels exceed limits
Hygiene Measures: No eating, drinking, or smoking during handling, wash exposed skin after work

Physical and Chemical Properties

Physical State: Solid; hard amber flakes, granules, or pale yellow semi-transparent blocks
Odor: Mild resinous
pH: Not applicable
Melting Point: Range 85 – 100°C (blocks)
Boiling Point: Decomposes before boiling
Flash Point: >220°C (closed cup)
Auto-ignition Temperature: >350°C
Flammability: Combustible as dust or powder
Vapor Pressure: Negligible at room temperature
Density: 1.05 – 1.10 g/cm3
Solubility: Insoluble in water, soluble in alcohols and organic solvents
Explosion Limits: Not established
Viscosity: Not relevant (solid)

Stability and Reactivity

Chemical Stability: Stable under normal storage conditions
Reactivity: Inert, non-reactive with most materials
Conditions to Avoid: Excessive heat, open flame, static discharge leading to dust ignition
Materials to Avoid: Strong oxidizing agents, acid chlorides
Hazardous Decomposition: In fire, decomposes to form carbon monoxide, carbon dioxide, and possible traces of formaldehyde or acrolein
Polymerization: Will not occur

Toxicological Information

Acute Toxicity: Low toxicity, LD50 oral (rat): >5000 mg/kg
Skin Irritation: Low potential, mild and reversible
Eye Irritation: Slight, typically reversible
Inhalation Risk: Dust can cause mild upper respiratory discomfort
Sensitization: Not a known sensitizer, though repeated skin contact may worsen eczema in sensitive people
Chronic Effects: Not listed as carcinogenic, mutagenic, or toxic for reproduction by global regulatory agencies
Other Health Effects: No neurological, developmental, or reproductive hazards found in animal studies
Medical Conditions Aggravated: Existing skin or respiratory conditions may become more symptomatic with frequent exposure

Ecological Information

Aquatic Toxicity: Not considered toxic to aquatic organisms, based on poor solubility and high molecular weight
Bioaccumulation: Product likely to biodegrade slowly; bioaccumulation not identified as a concern
Persistence and Degradability: Derived from natural plant materials; primary breakdown through mechanical and microbial action
Mobility in Soil: Product binds to soil particles, rarely migrates into groundwater
Other Environmental Effects: Avoid uncontrolled release, especially near water sources; handle waste responsibly

Disposal Considerations

Disposal Methods: Dispose of in accordance with regional, national, and local laws; material may go to landfill or be incinerated
Contaminated Packaging: Clean and recycle, or dispose as non-hazardous waste if contaminated with product
Waste Codes: Not classified as hazardous waste by EU, US, or international standards
Precautions: Prevent dust from contaminating water courses; avoid burning in open air

Transport Information

UN Number: Not regulated for transport
Proper Shipping Name: Not dangerous goods
Transport Hazard Class: Not assigned
Packing Group: Not required
Environmental Hazards: Non-hazardous for all modes of transportation
Special Precautions: Secure loads during transport; avoid spillage and dust generation
Regulatory Transport Markings: None required on outer packaging

Regulatory Information

Classification: Not classified as hazardous under EU CLP, US OSHA HCS, Canada WHMIS, or UN GHS
Inventory Listings: Listed on EINECS/ELINCS/TSCA/DSL and most major chemical inventories
Food Additive Status: Permitted in some jurisdictions for indirect food contact; check local regulations
Labeling Requirements: Product labeling according to workplace regulations; no signal word or pictogram required in most regions
Restrictions: Use only as permitted by national law and product application standards
Other Regulations: Not subject to global conventions on chemical hazards or controlled substances