MSDS – Geranium Oil

Identification

Product Name: Geranium Oil
Synonyms: Pelargonium Graveolens Oil, Geranium Bourbon Oil
Recommended Use: Fragrance, flavoring, aromatherapy
Supplier: Essential oil producers, fragrance suppliers
Contact Information: Manufacturer or local distributor details on label
Emergency Contact: Check CHEMTREC or relevant poison center
CAS Number: 8000-46-2
EC Number: 289-995-2

Hazard Identification

Classification: Flammable Liquid, Eye Irritant, Skin Sensitizer
Hazards: May ignite easily, may irritate eyes and skin, potential for allergic skin reaction
Label Elements: Flame, exclamation mark
Signal Word: Warning
Hazard Statements: Causes skin irritation, causes serious eye irritation, may cause allergic skin reaction, flammable liquid and vapor
Precautionary Statements: Avoid heat, sparks, direct sunlight; use gloves and eye protection; wash hands thoroughly after use

Composition / Information on Ingredients

Main Components: Citronellol (20–40%), Geraniol (10–20%), Linalool (2–10%), Isomenthone, 10-epi-γ-Eudesmol, Citronellyl formate
Nature: Essential oil from Pelargonium graveolens
Impurities: Small amounts of other terpenoids
Ingredient Disclosure: Full breakdown may be available upon request from supplier

First Aid Measures

Inhalation: Remove to fresh air, seek medical attention if symptoms occur
Skin Contact: Wash area with soap and water for several minutes; remove contaminated clothing
Eye Contact: Rinse cautiously with water for several minutes; remove contact lenses if present; seek medical advice
Ingestion: Rinse mouth, do not induce vomiting, seek medical attention
Symptoms: Redness, irritation, difficulty breathing with large inhalation

Fire-Fighting Measures

Suitable Extinguishing Media: Alcohol-resistant foam, dry chemical, carbon dioxide
Unsuitable Media: Water jet—may spread fire
Specific Hazards: Vapors may form explosive mixtures with air
Protective Equipment: Full protective gear, self-contained breathing apparatus
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, irritating fumes
Advice to Firefighters: Keep exposed containers cool with water spray

Accidental Release Measures

Personal Precautions: Avoid contact with skin and eyes; wear gloves and goggles
Environmental Precautions: Prevent release into drains or waterways
Methods of Cleanup: Cover spill with non-combustible absorbent material (sand, earth); collect and dispose in suitable container
Ventilation: Ensure adequate ventilation in cleanup area

Handling and Storage

Handling: Keep away from sources of ignition, use in well-ventilated areas, do not breathe vapor
Storage Conditions: Store in tightly closed container in a cool, dry, well-ventilated space, shielded from direct sunlight
Storage Incompatibilities: Strong oxidizing agents, acids
Other Precautions: Maintain proper labeling, keep away from children and animals

Exposure Controls and Personal Protection

Exposure Limits: No established OSHA/ACGIH limits for geranium oil components
Engineering Controls: Mechanical ventilation, local exhaust
Personal Protection: Chemical-resistant gloves, safety goggles or face shield, lab coat or apron
Respiratory Protection: Use NIOSH/MSHA approved respirator during high vapor concentrations
Hygiene Measures: Wash hands and skin after handling, keep contaminated clothing separate

Physical and Chemical Properties

Appearance: Pale green to yellow liquid
Odor: Floral, rose-like
Boiling Point: Approximate range 220–250°C
Melting Point: Below -10°C
Flash Point: About 72°C (closed cup)
Solubility: Insoluble in water, soluble in alcohol and oils
Specific Gravity: 0.880–0.900
Refractive Index: 1.460–1.470
Vapor Pressure: Not available
Viscosity: Thin, mobile liquid
pH: Not measurable as oil

Stability and Reactivity

Chemical Stability: Stable under recommended storage
Reactivity: Can react with strong oxidizers
Conditions to Avoid: Heat, sparks, open flames, sunlight
Incompatible Materials: Strong acids, alkalis, oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide, possibly irritating organic vapors

Toxicological Information

Acute Toxicity: Low oral and dermal toxicity for humans
Potential Effects: Skin irritation, allergic reactions, eye irritation, respiratory discomfort after inhalation
Chronic Effects: Prolonged or repeated exposure may cause sensitization
Carcinogenicity: No evidence in available data for geranium oil
Other Information: People with fragrance allergies should avoid contact; ingestion in significant quantities can cause nausea or vomiting

Ecological Information

Ecotoxicity: Harmful to aquatic life with long-lasting effects
Persistence and Degradability: Readily biodegradable, but high concentrations may temporarily harm aquatic life
Bioaccumulative Potential: Low
Mobility in Soil: Low due to volatility and insolubility in water
Other Adverse Effects: Avoid large-scale environmental release

Disposal Considerations

Waste Disposal Methods: Dispose of contents and container according to local, regional, national regulations
Contaminated Packaging: Rinse out container and send for recycling if possible, otherwise dispose in accordance with regulations
Precautions: Do not pour into drains, sewers, or natural waterways
Consult: Licensed waste disposal company for bulk disposal

Transport Information

UN Number: UN1169
Proper Shipping Name: Extracts, aromatic, liquid
Transport Hazard Class: 3 (flammable liquid)
Packing Group: III
Marine Pollutant: Yes
Special Precautions for Transport: Keep container tightly sealed, protect from physical damage and extreme temperatures

Regulatory Information

Labeling Requirements: Conform to OSHA Hazard Communication Standard, GHS classification
Inventory Status: Listed in TSCA, EINECS, DSL (region dependent)
Other Regulations: Subject to IATA, IMDG, ADR transport rules
Restrictions: Cosmetic and food use may be regulated under FDA and EU directives
Additional Information: Check national or regional safety acts for further requirements