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Ferrous Succinate: Material Safety Data Sheet (MSDS)

Identification

Product Name: Ferrous Succinate
Chemical Formula: C4H4FeO4
CAS Number: 1668-56-2
Recommended Use: Commonly used as an iron supplement in pharmaceuticals, feed, and food fortification
Manufacturer: Contact details and address available on product label
Emergency Contact: Emergency telephone numbers printed on supplied documentation
Synonyms: Iron(II) succinate, Succininic acid, iron(2+) salt

Hazard Identification

GHS Classification: Considered harmful if swallowed, low acute toxicity
Hazard Symbols: No pictograms required under GHS for finished product
Signal Word: Warning
Hazard Statements: May irritate gastrointestinal tract if ingested in large amounts
Precautionary Statements: Keep out of reach of children, avoid exposure to dust
Routes of Exposure: Ingestion, skin contact, inhalation of dust
Effects of Overexposure: Symptoms may include nausea, vomiting, abdominal pain

Composition / Information on Ingredients

Chemical Name: Ferrous Succinate
Concentration: 100% by weight
CAS Number: 1668-56-2
Impurities: No known significant impurities affecting classification
Molecular Weight: 183.93 g/mol

First Aid Measures

Inhalation: Move individual to fresh air, seek medical attention if respiratory symptoms occur
Skin Contact: Wash skin thoroughly with soap and water, remove contaminated clothing
Eye Contact: Rinse cautiously with water for several minutes, remove contacts if present and easy to do, seek medical advice if irritation persists
Ingestion: Rinse mouth, do not induce vomiting, seek prompt medical attention if large quantities are swallowed
Most Important Symptoms: Nausea, stomach pain, possible gastrointestinal upset
Notes for Physician: Treat symptomatically, monitor blood iron levels if ingestion is significant

Fire-Fighting Measures

Suitable Extinguishing Media: Use carbon dioxide, dry chemical, or foam extinguisher; for larger fires use water spray
Unsuitable Extinguishing Media: None reported
Hazardous Combustion Products: Emits toxic fumes under fire conditions including CO, CO₂, and iron oxides
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear
Fire/Explosion Hazards: Product is not flammable, but fine dust may pose a slight explosion risk if dispersed in air

Accidental Release Measures

Personal Precautions: Wear dust mask, safety goggles, gloves; avoid inhaling dust
Environmental Precautions: Prevent large quantities from entering watercourses or drains
Cleanup Methods: Sweep up material without raising dust, shovel into labeled waste containers; clean remaining residues with water and detergent
Disposal: Dispose of in accordance with local, state, and national regulations

Handling and Storage

Handling: Avoid generation of dust, wash hands thoroughly after handling, avoid contact with eyes and skin
Storage: Store in tightly closed containers, in a cool, dry, and well-ventilated area; protect from light, moisture, and incompatible materials
Incompatible Materials: Strong oxidizers, acids, and alkalis
Hygiene Measures: Do not eat, drink, or smoke during use; wash hands after handling

Exposure Controls and Personal Protection

Engineering Controls: Ensure adequate local exhaust ventilation in processing areas
Personal Protection: Wear protective gloves, safety goggles, and clothing; use dust mask or respirator if dust generation cannot be avoided
Occupational Exposure Limits: No specific limits established for ferrous succinate; follow general dust exposure standards (e.g., OSHA PEL for nuisance dust 15 mg/m³ total, 5 mg/m³ respirable)
Environmental Controls: Prevent emission of dust to surrounding environment

Physical and Chemical Properties

Appearance: Pale green powder or crystalline solid
Odor: Odorless
pH: Slightly acidic to neutral when dissolved in water
Solubility: Slightly soluble in water, soluble in dilute acids
Melting Point: Decomposes before melting
Boiling Point: Not applicable
Vapor Pressure: Negligible at ambient temperature
Density: Around 1.84 g/cm³
Flash Point: Not flammable
Explosive Properties: Not explosive under normal conditions
Partition Coefficient: Not determined

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactivity: Slightly reactive with strong acids, may release heat and toxic gases
Conditions to Avoid: Exposure to moisture, high humidity, and strong oxidizers
Hazardous Decomposition Products: CO₂, CO, iron oxides upon thermal decomposition
Incompatible Materials: Strong oxidizing agents, acids, alkalis

Toxicological Information

Acute Toxicity: Oral LD50 (rat): Not established for this compound, estimated low to moderate toxicity
Chronic Exposure: No data indicating chronic toxicity for expected exposures
Routes of Entry: Ingestion, inhalation, skin and eye contact
Symptoms: Large doses may result in gastrointestinal discomfort, nausea, vomiting, diarrhea
Carcinogenicity: Not listed as carcinogenic by IARC, NTP, OSHA
Mutagenicity: No data indicating mutagenic risk
Reproductive Effects: No data indicating reproductive risk

Ecological Information

Ecotoxicity: No detailed studies available, expected to have low toxicity to aquatic and terrestrial organisms
Persistence and Degradability: Compound breaks down into iron and succinate ions in the environment
Bioaccumulation Potential: Not expected to bioaccumulate significantly
Mobility in Soil: Moderate mobility in soils, influenced by local conditions
Other Adverse Effects: Large spills may contribute to localized eutrophication of water bodies due to iron release

Disposal Considerations

Disposal Methods: Use approved landfill or incineration facilities, avoid discharge of large amounts into sewage, waterways, or soil
Container Disposal: Empty containers can be reused or recycled after thorough cleaning, or disposed of as industrial waste as per regulations
Regulatory Requirements: Dispose in compliance with local, regional, and national regulations

Transport Information

UN Number: Not classified as a hazardous material for transport
Transport Hazard Class: Not regulated
Packing Group: Not applicable
Labeling Requirements: No specific transport labeling required
Special Precautions: Protect containers from physical damage and moisture during transport
DOT Classification: Not regulated

Regulatory Information

TSCA Status: Listed in the US Toxic Substances Control Act (TSCA) inventory
EU Classification: Not classified as hazardous under European legislation
OSHA Hazard Communication: Does not meet the criteria for hazardous chemicals
SARA Title III: Not subject to reporting under SARA Title III sections 302, 304, or 313
California Proposition 65: Not listed
Other Regulations: Compliance with national and regional regulations required for workplace and environmental safety