West Ujimqin Banner, Xilingol League, Inner Mongolia, China sales9@alchemist-chem.com 1531585804@qq.com
Follow us:



Material Safety Data Sheet: Ferrous Gluconate

Identification

Chemical Name: Ferrous Gluconate
Synonyms: Iron(II) gluconate, Gluconic acid ferrous salt
CAS No: 299-29-6
Molecular Formula: C12H22FeO14
Recommended Uses: Food additive, pharmaceutical ingredient, iron fortification
Supplier Details: Provided on product label or shipping documentation
Emergency Contact: Refer to local regulations and supplier

Hazard Identification

GHS Classification: Not classified as hazardous under GHS criteria for most uses
Physical Hazards: Non-combustible, can decompose at high temperatures producing fumes
Health Hazards: May cause mild irritation to eyes, skin, and respiratory tract; ingesting large amounts leads to harmful effects such as gastrointestinal discomfort or iron toxicity
Environmental Hazards: Not considered toxic to aquatic or terrestrial life under prescribed uses
Pictograms: None required for normal consumer and commercial handling
Signal Word: None required
Hazard Statements: Ingestion in excess may cause health problems due to iron overload, especially in young children

Composition / Information on Ingredients

Chemical Name: Ferrous Gluconate
Concentration: 97-100%
Impurities: May include trace levels of calcium, magnesium, or other mineral salts, but not at concentrations considered hazardous
Other Ingredients: None intentionally added

First Aid Measures

Eye Contact: Rinse cautiously with plenty of water, lift eyelids to flush out particles; seek medical attention if redness or discomfort persists
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water; persistent irritation warrants medical attention
Inhalation: Move person to fresh air, support breathing if necessary; seek medical advice for symptoms such as cough or shortness of breath
Ingestion: Rinse mouth with water, do not induce vomiting; consult a healthcare provider, especially if large quantities have been swallowed, due to risk of iron poisoning
Advice for Medical Personnel: Treat symptomatically, monitor for signs of iron toxicity (nausea, vomiting, abdominal pain, metabolic acidosis)

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry powder, foam, carbon dioxide
Unsuitable Media: No specific restrictions known
Hazardous Combustion Products: Iron oxides, carbon oxides and fumes at high temperature
Protective Equipment for Firefighters: Full protective clothing and self-contained breathing apparatus to prevent exposure to smoke, fumes, and decomposition products
Special Fire-Fighting Procedures: Isolate area, remove unprotected personnel, and apply standard firefighting procedures; prevent runoff from entering water systems

Accidental Release Measures

Personal Precautions: Wear appropriate PPE such as gloves and goggles to limit exposure
Environmental Precautions: Prevent entry into drains, sewers, or waterways by containing any spill immediately
Cleanup Methods: Gather up spilled powder using non-sparking tools, place in a suitable closed container for disposal, and clean area thoroughly with water; avoid creating dust
Additional Measures: Dispose of waste in accordance with local, regional, and national regulations

Handling and Storage

Handling: Keep container tightly closed when not in use to avoid moisture uptake and contamination; minimize dust formation when transferring or mixing; handle with clean, dry hands or tools
Storage Conditions: Store in a cool, dry, well-ventilated area away from incompatible substances such as oxidizing agents and acids; avoid direct sunlight
Incompatible Materials: Strong oxidizers, strong acids, alkali materials, materials which react with iron
Packaging: Use containers made from materials resistant to corrosion and moisture ingress to preserve quality

Exposure Controls and Personal Protection

Occupational Exposure Limits: No specific exposure limits set for ferrous gluconate, follow general nuisance dust limits (e.g., OSHA PEL for total dust)
Engineering Controls: Provide adequate general and local exhaust ventilation to control airborne concentrations below recommended limits
Personal Protective Equipment: Use gloves made of impervious material, safety goggles, dust masks or respirators if airborne dust is possible
Hygiene Measures: Wash hands before breaks, after handling, and before eating or drinking, keep work surfaces clean
Environmental Protection: Implement measures to prevent contamination of water or soil

Physical and Chemical Properties

Appearance: Light yellow-gray to greenish powder
Odor: Odorless
Odor Threshold: Not applicable
pH: Neutral to slightly acidic (aqueous solutions)
Melting Point: Decomposes before melting
Boiling Point: Not applicable
Flash Point: Not flammable
Evaporation Rate: Not applicable
Flammability: Non-flammable solid
Vapor Pressure: Not applicable
Vapor Density: Not applicable
Solubility: Soluble in water
Partition Coefficient (n-octanol/water): Not available
Auto-ignition Temperature: Not self-igniting
Decomposition Temperature: Above 150°C, releases iron oxides and carbon dioxide
Viscosity: Not applicable

Stability and Reactivity

Chemical Stability: Stable under normal storage and handling conditions
Possibility of Hazardous Reactions: May react with strong acids producing iron salts, with oxidizers causing fire or explosion risk
Conditions to Avoid: Excessive heat, moisture, direct sunlight, sources of ignition
Incompatible Materials: Strong oxidizers, strong acids, alkalis
Hazardous Decomposition Products: Iron oxides, carbon oxides, potentially irritating vapors at high temperature

Toxicological Information

Acute Toxicity: Oral LD50 in rats reported at above 420 mg/kg
Skin Corrosion/Irritation: Not classified as skin corrosive or irritant, mild irritation may occur with prolonged exposure
Serious Eye Damage/Irritation: May cause temporary irritation
Respiratory Sensitization: Not a sensitizer
Ingestion: Excessive intake can damage gastrointestinal lining, trigger metabolic and central nervous system disturbances in severe cases
Chronic Effects: Long-term high exposure linked to iron accumulation and risk for organ damage
Mutagenicity/Carcinogenicity: No evidence for carcinogenicity or genotoxic effects from available studies
Other Data: Population groups at higher risk include children and individuals with iron metabolism disorders

Ecological Information

Ecotoxicity: No significant toxicity reported for aquatic organisms at environmental concentrations
Persistence and Degradability: Organic component biodegradable; iron component stable and can accumulate in sludge and sediment
Bioaccumulation Potential: Low for organic fraction; iron may accumulate in soil and water over time
Mobility in Soil: Moderately mobile in water, adheres to soil particles
Other Adverse Effects: No known significant adverse ecological impacts under normal use or small accidental release

Disposal Considerations

Disposal Methods: Follow local or national disposal regulations, incinerate or landfill in authorized site according to best available practices
Container Disposal: Empty containers thoroughly, recycle or dispose following local requirements
Special Precautions: Prevent contamination of water supplies, never discharge into lakes, rivers, or sewers

Transport Information

UN Number: Not regulated for transport
Proper Shipping Name: Ferrous Gluconate
Transport Hazard Class: Not assigned
Packing Group: Not applicable
Environmental Hazards: Not regulated as a marine pollutant
Special Transport Notes: Store and transport in tightly sealed containers, protect from moisture and strong oxidizers

Regulatory Information

Relevant Standards: Regulated as a food additive and supplement component, subject to regional food and pharmaceutical laws
OSHA Status: Not classified as hazardous under US OSHA regulations for occupational exposure
WHMIS Classification: Not controlled under WHMIS (Canada)
TSCA Inventory: Listed
Other Registers: Included in EC, Australian, Japanese and other inventories
Label Elements: Not required to carry hazard symbols or statements under major chemical safety frameworks
Restrictions: Monitor for restrictions concerning iron supplements in food applications and pediatric uses