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Product Name: Ferrous Fumarate
Chemical Formula: C4H2FeO4
Synonyms: Iron(II) fumarate, Ferrous(II) fumarate
CAS Number: 141-01-5
Recommended Use: Oral iron supplement, ingredient in fortified foods
Manufacturer Information: Contact details for supplier or manufacturer
Emergency Contact: Local poison control center or emergency medical services
Classification: Not classified as hazardous according to GHS
Primary Hazards: Ingestion in excess may lead to iron poisoning, especially in small children; dust can irritate respiratory tract, eyes, and skin
Label Elements: No mandatory hazard symbols required, precautionary statements regarding accidental ingestion
Routes of Exposure: Inhalation, ingestion, skin contact, eye contact
Symptoms of Overexposure: Nausea, vomiting, abdominal pain, diarrhea, drowsiness, circulatory collapse with high doses
Target Organs: Gastrointestinal tract, cardiovascular system in severe overdose cases
Chemical Identity: Ferrous Fumarate
Common Name: Iron(II) fumarate
Concentration: Typically 97-100%
Impurities: May contain trace impurities, not expected to present additional hazards
Inhalation: Move exposed individual to fresh air. Seek medical attention if persistent cough or respiratory symptoms develop.
Skin Contact: Remove contaminated clothing. Wash affected skin with plenty of soap and water.
Eye Contact: Rinse immediately with water for at least 15 minutes, lifting upper and lower eyelids occasionally. If irritation continues, get medical help.
Ingestion: If a significant amount is swallowed, get medical attention immediately. Do not induce vomiting unless told by poison control or a healthcare provider. Keep the victim calm and hydrated.
Symptoms to Watch: Severe stomach upset, low blood pressure, rapid heartbeat, drowsiness, shock in children.
Suitable Extinguishing Media: Water spray, dry chemical, foam, or carbon dioxide, as appropriate for surrounding fires
Unusual Fire Hazards: Ferrous fumarate itself does not burn, but dust can pose a combustion risk if suspended in air
Protective Equipment: Firefighters need self-contained breathing apparatus and protective clothing
Decomposition Products: Combustion releases oxides of iron and carbon dioxide; smoke may contain unidentified toxic compounds
Precautions for Firefighters: Cool surrounding containers with water if exposed to fire. Avoid inhaling dust, smoke, or fumes.
Personal Precautions: Evacuate area of unprotected personnel. Use respiratory protection if dust is generated. Wear gloves and eye protection.
Environmental Precautions: Prevent product from entering drains, sewers, or waterways.
Cleanup Methods: Scoop up spilled material. Use a vacuum or wet method to reduce dust formation. Place in a suitable container for proper disposal.
Decontamination: Wash spill area thoroughly with water after cleanup. Control dust during cleanup to limit airborne exposure.
Waste Disposal: Dispose of according to local, regional, or national regulations.
Safe Handling: Handle in accordance with good industrial hygiene practices. Avoid contact with eyes, skin, and clothing. Do not ingest or inhale excessive dust.
Storage Requirements: Store in a cool, dry, well-ventilated place. Keep container tightly closed and away from incompatible materials such as strong oxidizers.
Protect Against: Moisture, heat, strong acids, strong bases and oxidizing agents.
Storage Containers: Store in original packaging or appropriately labeled containers made from materials that do not react with iron salts.
Exposure Limits: OSHA PEL for nuisance dust 15 mg/m³ (total dust), 5 mg/m³ (respirable dust); ACGIH TLV (inhalable particulate matter) 10 mg/m³
Engineering Controls: Ensure adequate ventilation. Use local exhaust or general dilution ventilation as needed to keep dust levels below recommended limits.
Personal Protective Equipment (PPE): Use safety glasses with side shields, gloves made of rubber or nitrile, protective clothing as necessary.
Respiratory Protection: If dust is generated, use an approved particulate respirator.
Good Hygiene Practices: Wash hands thoroughly after handling. Avoid eating, drinking, or smoking in work area.
Physical State: Solid
Appearance: Reddish-orange crystalline powder
Odor: Odorless
Molecular Weight: 169.90 g/mol
Melting Point: Decomposes above 200°C
Solubility: Slightly soluble in water; no significant solubility in ethanol or ether
Density: Approximately 2.435 g/cm³
pH (suspension in water): 2.5 - 3.5
Flash Point: Not applicable
Vapor Pressure: Not applicable
Partition Coefficient (log Kow): Not available
Stability: Stable under normal storage conditions
Reactivity: No dangerous reactions under normal use
Hazardous Reactions: May react with strong oxidizers, releasing heat or toxic gases
Incompatible Materials: Oxidizing agents, strong acids, strong bases
Decomposition Products: Thermal decomposition can release carbon oxides and iron oxides
Acute Toxicity: Oral LD50 (rat) exceeds 1000 mg/kg; large doses in humans, especially children, can cause acute iron poisoning
Chronic Effects: Prolonged or repeated overexposure may affect liver, heart, and kidneys
Carcinogenicity: Not classed as carcinogenic by IARC, NTP, OSHA
Mutagenicity: No data indicating mutagenic potential
Reproductive Toxicity: Not classified as a reproductive toxin
Routes of Entry: Inhalation, ingestion, skin and eye contact
Irritation: Dust may cause mild irritation to skin, eyes, and respiratory tract
Symptoms of Overdose: Vomiting, diarrhea, abdominal pain, lethargy, circulatory shock at high exposures
Aquatic Toxicity: Not expected to be toxic to aquatic life at environmental concentrations
Persistence and Degradability: Inorganic compound; does not readily degrade but iron may accumulate in soil under certain conditions
Bioaccumulation: Minimal potential for bioaccumulation
Mobility in Soil: Low mobility, binds to soil particles
Other Effects: Excess iron in water bodies may cause insoluble precipitates, affecting aquatic organisms
Waste Treatment Methods: Dispose according to federal, state, and local requirements; incineration or landfill permitted for non-hazardous materials
Product Disposal: Collect and place in suitable containers for disposal with chemical waste
Packaging Disposal: Empty containers must be triple rinsed and then disposed of in accordance with local regulations
Precautions: Prevent material from entering waterways or sewer systems
UN Number: Not regulated as a hazardous material for transport
Proper Shipping Name: Ferrous Fumarate
Transport Hazard Class: Not classified
Packing Group: None
Environmental Hazards: Avoid release to environment during transport
Special Precautions: Basic precautions for bulk transit, avoid dust creation, secure containers against spillage
Safety, Health, and Environmental Regulations: Listed under relevant chemical control inventories (TSCA, EINECS), not a controlled drug or hazardous under major transport regulations.
OSHA Hazard Communication: Generally regarded as safe with standard handling, but large doses hazardous
SARA Title III: Not listed as a reportable substance
California Proposition 65: Does not contain chemicals subject to reporting.
