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Material Safety Data Sheet: DL-Tartaric Acid

1. Identification

Product Name: DL-Tartaric Acid
Synonyms: Racemic Tartaric Acid, 2,3-Dihydroxybutanedioic acid
CAS Number: 133-37-9
Recommended Use: Acidulant in food processing, ingredient in pharmaceuticals, reagent in laboratories, agent in metal cleaning and textile industries
Supplier: Manufacturer or distributor details as shown on commercial purchase documents
Emergency Contact: Poison Control Center, local emergency services, or supplier specific hotline as provided with shipment

2. Hazard Identification

Classification: Eye irritation, Category 2A; Skin irritation, Category 2
Label Elements: Signal word: Warning; Pictogram: Exclamation mark
Hazard Statements: Causes serious eye irritation, may cause skin irritation
Precautionary Statements: Wash exposed skin thoroughly, wear protective gloves and eye protection, avoid dust formation and contact
Potential Health Effects: Eyes: redness, pain, serious irritation; Skin: dryness, redness, itching on contact; Inhalation: coughing, respiratory irritation from powder dust; Ingestion: abdominal pain or discomfort, nausea if swallowed
Other Hazards: Not considered hazardous under normal usage in small quantities, individuals with allergies may react

3. Composition / Information on Ingredients

Chemical Name: DL-Tartaric Acid
Purity: Typically 99% or greater
Molecular Formula: C4H6O6
Molecular Weight: 150.09 g/mol
Hazardous Components: DL-Tartaric Acid (100% active ingredient); product does not generally contain other additives or impurities at hazardous levels
Impurities: Trace contaminants may result from manufacturing but are not present at hazardous levels according to established food or industrial safety standards

4. First Aid Measures

Eye Contact: Rinse immediately with clean water for at least 15 minutes, keep eyelids open, seek medical advice if irritation persists
Skin Contact: Remove contaminated clothing, wash with soap and water, seek medical attention for persistent irritation
Inhalation: Move to fresh air, assist breathing if necessary, get medical help if symptoms develop
Ingestion: Rinse mouth, drink water if conscious, do not induce vomiting, contact healthcare provider for further advice

5. Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, carbon dioxide, dry chemical powder
Unsuitable Media: Strong water jets (may spread dry product)
Hazards from Fire: Product decomposes under intense heat to release carbon monoxide, carbon dioxide, and possibly irritating fumes
Protective Equipment: Firefighters should wear full gear and self-contained breathing apparatus
Special Procedures: Evacuate area, prevent runoff from entering drains or water courses, keep dust to a minimum

6. Accidental Release Measures

Personal Precautions: Evacuate unprotected personnel, avoid breathing dust, ensure good ventilation
Protective Equipment: Gloves, safety goggles, dust mask or respirator if powder is airborne
Environmental Precautions: Avoid discharge to waterways, minimize product entering sewers or gutters
Methods for Clean-Up: Sweep or vacuum spilled material, avoid raises dust, transfer to labeled container for disposal, wash area with water after collection

7. Handling and Storage

Handling: Avoid skin and eye contact, prevent dust clouds with careful transfer, use in well-ventilated areas, do not eat, drink, or smoke in processing areas, wash thoroughly after handling
Storage: Store in tightly closed containers, keep in a dry, cool, well-ventilated place, protect from moisture, strong oxidizing agents, or heat sources, label containers properly, avoid storage near incompatible materials such as alkalies or strong reducing agents

8. Exposure Controls and Personal Protection

Engineering Controls: Local exhaust ventilation or general ventilation to reduce airborne dust
Personal Protective Equipment: Respiratory: Dust mask or approved respirator for powder handling, Skin: Chemical-resistant gloves, Eye: Safety goggles or face shield, Body: Protective lab coat or apron
Occupational Exposure Limits: No established exposure limits for DL-Tartaric Acid, keep dust levels as low as possible by good workplace practices
Hygiene Measures: Regular hand washing, change contaminated clothing, avoid contact with food and drink while handling

9. Physical and Chemical Properties

Appearance: White crystalline powder or colorless crystals
Odor: Odorless
pH: 2.2 (0.5% solution in water)
Melting Point: 206–212°C
Boiling Point: Decomposes before boiling
Flash Point: Not applicable
Explosive Properties: Not explosive
Solubility: Soluble in water, slightly soluble in ethanol
Density: About 1.76 g/cm³

10. Stability and Reactivity

Chemical Stability: Shelf-stable under recommended storage conditions
Reactivity: Reacts with strong oxidizing agents, strong bases
Conditions to Avoid: Moisture, excessive heat, open flames, incompatible chemicals
Incompatible Materials: Strong oxidizers (e.g., peroxides, permanganates), strong acids, bases
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, acrid smokes or fumes under intense heat

11. Toxicological Information

Routes of Exposure: Inhalation, ingestion, skin and eye contact
Acute Toxicity: Oral LD50 (rat): about 5000 mg/kg, low acute toxicity
Skin Corrosion/Irritation: May cause mild to moderate irritation on prolonged contact
Serious Eye Damage/Irritation: Can cause serious irritation, pain, redness
Respiratory Irritation: Dust may irritate nose, throat, lungs
Sensitization: No data indicating skin or respiratory sensitization
Chronic Toxicity: No evidence of long-term health effects in humans from normal exposure
Carcinogenicity/Mutagenicity: Not listed as a carcinogen by IARC, NTP, or OSHA; negative in standard mutagenicity tests

12. Ecological Information

Aquatic Toxicity: Low toxicity to aquatic life, readily biodegradable in the environment
Persistence and Degradability: Rapidly broken down by bacteria, does not accumulate
Bioaccumulative Potential: Not expected to bioaccumulate
Mobility in Soil: High water solubility means compound will leach readily in soil and may enter waterways
Other Ecological Effects: In large spills, may cause pH drop in water bodies, avoid release to environment in uncontrolled quantities

13. Disposal Considerations

Disposal Methods: Dispose as non-hazardous organic waste at approved facility, landfill or incineration following local regulations
Packaging Disposal: Triple rinse empty containers, recycle or dispose as per local rules
Precautions: Prevent contact of waste with incompatible materials, do not flush large quantities into drains or waterways, consult local, state, and federal waste managers for further guidance

14. Transport Information

UN Number: Not regulated
Proper Shipping Name: Not classified as dangerous for transport
Transport Hazard Class: Not applicable
Packing Group: Not applicable
Environmental Hazards: Not considered a marine pollutant
Special Precautions: Avoid securing near foodstuffs in mixed loads, ensure containers are sealed and labeled

15. Regulatory Information

OSHA Status: Not classified as hazardous under OSHA Hazard Communication Standard
TSCA (Toxic Substances Control Act): Listed on TSCA inventory
DSL/NDSL (Canada): Listed
Labeling Requirements: Eye and skin irritation warnings per GHS
Other Regulations: Product subject to food additive regulations if employed in food processing; refer to FDA and EU food safety guidelines for acceptable use; review local, state, and international rules for industrial or laboratory use
REACH Status (EU): Registered or exempt under typical quantities for laboratory and commercial use
Worker Safety: Employers provide training and hazard communication per chemical safety regulations
Community Right-To-Know: Not listed under SARA Title III Section 313