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Material Safety Data Sheet: Cyclamen Aldehyde

Identification

Product Name: Cyclamen Aldehyde
Chemical Name: 3-(4-Isopropylphenyl)-2-methylpropanal
CAS Number: 103-95-7
EC Number: 203-161-7
Synonyms: 2-Methyl-3-(4-isopropylphenyl)propanal
Recommended Use: Fragrance ingredient in perfumery, household products, personal care items
Supplier: Type the address, city, emergency contact numbers of the chemical supplier

Hazard Identification

Classification: Eye Irritant (Category 2), Skin Irritant (Category 2), Sensitizing (Category 1B), Hazardous to the aquatic environment (Chronic Category 2)
Signal Word: Warning
Hazard Statements: Causes skin irritation, may cause an allergic skin reaction, causes serious eye irritation, toxic to aquatic life with long-lasting effects
Pictograms: Exclamation mark, environment
Precautionary Statements: Avoid breathing dust, fumes, gas, mist, vapors, spray. Wash skin thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves, clothing, and eye protection.

Composition / Information on Ingredients

Chemical Identity: Cyclamen Aldehyde (purity > 95%)
CAS Number: 103-95-7
Additional Components: Trace impurities < 1% (identity varies by supplier)
Impurities: Not considered to contribute to hazard
Molecular Formula: C13H18O
Molecular Weight: 190.29 g/mol

First Aid Measures

Inhalation: Remove person to fresh air. Keep at rest in a comfortable position. Seek medical attention if symptoms persist.
Skin Contact: Wash immediately with soap and water. Take off contaminated clothing. Seek medical advice if irritation or reaction develops.
Eye Contact: Rinse cautiously with water for several minutes, holding eyelids open. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical care.
Ingestion: Rinse mouth thoroughly. Do not induce vomiting. Call a poison center or doctor if feeling unwell.
Most Important Symptoms: Redness and irritation of eyes and skin. Possible breathing discomfort on inhalation.

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, water spray (avoid full jet as it can spread burning liquid)
Special Hazards: Burning may produce irritant or toxic gases, including carbon monoxide or carbon dioxide
Advice for Firefighters: Wear self-contained breathing apparatus, use chemical protective clothing
Hazardous Combustion Products: Carbon oxides, unidentified fume and smoke may arise
Additional Information: Evacuate area, cool tanks / containers with water, manage fire water runoff to contain environmental impact

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, use personal protective equipment (gloves, goggles, protective clothing)
Environmental Precautions: Prevent further spillage or leakage if safe to do so. Prevent entry into sewers, surface water, groundwater, or confined spaces.
Methods for Containment: Absorb spill using inert material (sand, earth, vermiculite). Collect for disposal.
Cleaning Up: Ventilate area. Wash spill site after removal of material. Properly dispose of contaminated clean-up materials.

Handling and Storage

Handling Precautions: Handle following good industrial hygiene and safety practices. Avoid contact with eyes, skin, and clothing. Do not breathe vapors, spray, or mists.
Storage Conditions: Keep tightly closed in original container, store in a cool, well-ventilated place, away from direct sunlight, heat, ignition sources, acids, and oxidizing agents.
Special Requirements: Ground containers when transferring product to avoid static. Use only equipment designed for chemical resistance.
Incompatibilities: Avoid storing with strong acids, strong bases, or oxidizers.

Exposure Controls and Personal Protection

Exposure Limits: No official occupational exposure limits established, but minimize exposure.
Engineering Controls: Use local exhaust or general ventilation to maintain airborne concentrations below recommended exposure limits.
Personal Protective Equipment (PPE): Use chemical-resistant gloves (e.g., nitrile), tightly fitting goggles, protective clothing. In case of inadequate ventilation, wear respiratory protection (organic vapor cartridge).
Hygiene Measures: Keep away from food and drink. Wash thoroughly after handling. Remove and wash contaminated clothing before reuse.
Environmental Controls: Minimize emissions. Prevent product from entering drains or waterways.

Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Floral, cyclamen-like, fresh
Odor Threshold: Not available
pH: Not applicable (neutral organic liquid)
Melting Point/Freezing Point: -20°C to -18°C
Initial Boiling Point/Range: 275°C (estimated)
Flash Point: 120°C (closed cup)
Evaporation Rate: Not determined
Flammability: Not classified as highly flammable
Vapor Pressure: 0.04 mmHg at 25°C
Vapor Density: Heavier than air
Relative Density: 0.976–0.980 at 20°C
Solubility in Water: Slightly soluble
Partition Coefficient (n-octanol/water): log Kow 4.02
Auto-ignition Temperature: 385°C
Decomposition Temperature: Not determined
Viscosity: 8.5 mPa.s at 25°C

Stability and Reactivity

Chemical Stability: Stable in normal storage and handling conditions
Reactivity: Not reactive under recommended use and storage
Hazardous Reactions: Violent reactions may occur with strong oxidizing agents
Conditions to Avoid: Avoid excessive heat, flame, sources of ignition
Incompatible Materials: Acids, oxidizers, strong bases
Hazardous Decomposition Products: Carbon oxides, other irritating gases

Toxicological Information

Acute Toxicity (Oral, Dermal, Inhalation): LD50 (oral, rat) approximately 3,300 mg/kg; LD50 (dermal, rabbit) > 5,000 mg/kg; Inhalation data not available
Skin Corrosion/Irritation: Causes irritation on contact with skin
Serious Eye Damage/Irritation: Strongly irritating to eyes, may cause redness and pain
Respiratory Sensitization: Not classified (allergic reactions rare from inhalation)
Skin Sensitization: May cause allergic skin reactions in susceptible individuals
Germ Cell Mutagenicity: Not classified
Carcinogenicity: No data indicating carcinogenic or tumorigenic effects
Reproductive Toxicity: No significant reproductive or developmental toxicity identified
STOT (Single Exposure): May cause transient respiratory irritation
STOT (Repeated Exposure): Not known to have long-term health effects
Aspiration Hazard: Not classified as presenting an aspiration risk

Ecological Information

Aquatic Toxicity: Toxic to aquatic life with long-lasting effects (LC50 for fish: <10 mg/L)
Persistence and Degradability: Readily biodegradable in standard laboratory tests (OECD 301)
Bioaccumulative Potential: Potential for bioaccumulation, based on log Kow > 4
Mobility in Soil: Low mobility, adsorbed by soil organic matter
Other Adverse Effects: Harmful to aquatic environments, do not release untreated to water, soil, or drains

Disposal Considerations

Disposal Methods: Dispose through licensed chemical waste contractor. Rinse containers before recycling or disposal.
Product Waste: Treat as hazardous organic chemical waste. Incineration in approved facility preferred.
Contaminated Packaging: Empty containers may contain residue and require disposal as hazardous waste.
Precautions: Consult local, regional, national, and international regulations for detailed waste disposal guidelines.

Transport Information

UN Number: UN 3082
Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (contains Cyclamen Aldehyde)
Transport Hazard Class: 9 (miscellaneous dangerous substances and articles)
Packing Group: III
Marine Pollutant: Yes
Special Precautions: Prevent accidental release, secure packaging, avoid temperature extremes, handle with appropriate equipment for hazardous liquids during transit

Regulatory Information

Labelling: Meets GHS (Globally Harmonized System for Classification and Labelling of Chemicals) standards for hazard communication
TSCA Listing: Listed in the United States Toxic Substances Control Act inventory
REACH Status (EU): Compliant with REACH regulation under applicable uses
Other Regulations: Subject to workplace safety laws regarding chemical handling, PPE, storage stability, employee training. Compliance required with international shipping regulations (IMDG, IATA, ADR/RID). Check local, national, and regional regulatory frameworks for updated restrictions and guidelines.