Product Name: Chlorophyllin Copper Complex
Chemical Family: Porphyrin Derivative
CAS Number: 11006-34-1
Synonyms: Sodium copper chlorophyllin, copper complex of chlorophyllin
Use: Food additive (colorant), dietary supplement, pharmaceuticals, cosmetics ingredient, toothpaste pigment, research chemical
Manufacturer: Supplier-specific details required
Contact for Emergency: Refer to supplier; local poison control centers
Relevant Identified Uses: Colorant in food or industrial applications, supplement ingredient
GHS Classification: Not classified as hazardous according to United Nations GHS criteria
Signal Word: None
Hazard Statements: Not expected to produce significant acute hazards
Precautionary Statements: Avoid unnecessary contact, inhalation, or ingestion; use approved PPE
Routes of Entry: Inhalation, ingestion, skin and eye contact possible
Symptoms: May cause mild gastrointestinal upset if swallowed; possible mild eye or skin irritation on direct contact
Chronic Effects: No known long-term toxic effects at typical use levels; copper toxicity may be possible in extreme overdose or misuse
Environmental Risks: Large spills could affect plant or algal growth in watercourses due to copper content
Sodium Copper Chlorophyllin: 90-98% (active ingredient)
Sodium Salts: 2-10% (stabilizers, buffer)
Impurities: Possible trace amounts of sodium chloride, copper salts, organic plant pigments
Eye Contact: Rinse thoroughly with water for at least 15 minutes, keeping eyelids open; seek medical advice if irritation persists
Skin Contact: Wash affected area with soap and water; remove contaminated clothing
Inhalation: Move to fresh air, seek medical support for persistent cough or breathing problems
Ingestion: Rinse mouth, drink water, do not induce vomiting; seek medical assistance for persistent symptoms
Advice for Doctors: Symptomatic treatment, monitor for signs of copper toxicity in large ingestion cases
Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Media: None identified under normal conditions
Hazardous Combustion Products: Oxides of copper, carbon oxides
Special Protective Equipment: Firefighters wear full protective clothing, including self-contained breathing apparatus
Explosion Risk: Not explosive, not flammable under typical storage conditions
Personal Protection: Use gloves, safety glasses, and dust mask or respirator as needed
Environmental Precautions: Prevent entry into waterways or sewers; collect spilled material to minimize environmental contamination
Cleanup Procedures: Sweep up material using methods to minimize dust; rinse area with plenty of water; collect for disposal according to local requirements
Disposal of Spill: Place in appropriate labeled waste containers for authorized disposal
Safe Handling: Avoid generating dust; handle in well-ventilated areas; use personal protective equipment if risk of contact exists
Storage Requirements: Store in a dry, cool, well-ventilated area, away from incompatible materials (acids or oxidizers)
Conditions to Avoid: Excessive moisture, heat, and strong acids
Hygiene Measures: Wash hands thoroughly after handling; do not eat, drink, or smoke during use
Occupational Exposure Limits: Not established for this substance; observe limits for nuisance particulates and copper compounds
Respiratory Protection: Use approved mask or respirator if airborne dust is generated
Skin Protection: Gloves and protective work clothing where direct exposure is likely
Eye Protection: Safety goggles or face shield
Engineering Controls: Local exhaust ventilation or general room ventilation
Environmental Controls: Prevent contaminated runoff or dust from entering storm water drains
Appearance: Dark green to blue-green powder or granules
Odor: Odorless or faint plant-like scent
pH (1% solution): Typically 9–11 (alkaline)
Melting Point: Decomposes before melting
Solubility: Water soluble
Density: Approximately 0.5–0.7 g/cm³
Boiling Point: Not applicable
Vapor Pressure: Not volatile
Other: Stable under normal storage conditions; forms strong-colored solutions
Chemical Stability: Stable under dry, cool, and normal atmospheric conditions
Conditions to Avoid: Excessive heat, moisture, exposure to acids
Incompatible Materials: Strong acids, oxidizing agents
Hazardous Decomposition Products: Produces copper oxides, carbon oxides under extreme heat or fire
Polymerization: Does not occur
Acute Toxicity: Low toxicity by oral or dermal routes in typical applications
Skin Irritation: Mild, possible in sensitive people
Eye Irritation: Mild and reversible
Respiratory Effects: Dust may cause coughing or mild upper respiratory tract irritation
Chronic Effects: No evidence of carcinogenicity, mutagenicity, or reproductive toxicity from typical use; copper toxicity potential if consumed in very high amounts
Sensitization: Unlikely
LD50 (oral, rat): >10,000 mg/kg (literature values)
Ecotoxicity: May be toxic to aquatic organisms at high concentrations due to copper component
Persistence and Degradability: Not readily biodegradable, but expected to be slowly degraded over time
Bioaccumulation: Little evidence of significant bioaccumulation
Soil Mobility: Moderate; may bind to soil particles
Other Adverse Effects: Spilled product can color water and stain natural surroundings
Disposal Methods: Dispose as non-hazardous waste in accordance with local, state, federal, and national regulations; avoid uncontrolled release to environment
Waste Code: Not classified as hazardous under standard US or EU waste codes
Packaging Disposal: Triple rinse containers and recycle or dispose based on local requirements
UN Number: Not regulated
Proper Shipping Name: Not classified as dangerous goods
Hazard Class: Not applicable
Packing Group: Not applicable
Transport Precautions: Avoid shipment with acids, oxidizers; keep containers sealed, upright, and protected from moisture
US Regulations: Food and drug use permitted by FDA for specified purposes; compliant with US TSCA define status
EU Regulations: Authorized for use as food additive (E141); subject to REACH registration for industrial applications
GHS Classification: Not hazardous
Labeling: Comply with local labeling requirements for workplace chemicals
Other Information: Observe workplace exposure limits for copper if processing large quantities