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Material Safety Data Sheet: Biological Sulfur

Identification

Product Name: Biological Sulfur
Chemical Formula: S
Common Synonyms: Elemental Sulfur, Bio-sulfur
Recommended Use: Soil amendment, fungicide, bioremediation agent
Supplier Information: Provided upon request
Emergency Contact Number: Provided upon request

Hazard Identification

GHS Classification: Not classified as hazardous for most uses, but dust can present respiratory irritation hazard.
Label Elements: Pictogram: Exclamation mark for irritation
Hazard Statements: Can cause eye, skin, and respiratory irritation upon contact or inhalation of dust.
Precautionary Statements: Avoid inhalation of dust, use adequate ventilation, wear recommended protective gear.
Other Hazards: Sulfur dust may give rise to explosive mixtures with air.

Composition / Information on Ingredients

Main Component: Elemental Sulfur, 85%–99% by weight
Impurities: Trace minerals, naturally occurring organic matter up to 10%
CAS Number: 7704-34-9
Molecular Weight: 32.07 g/mol
Appearance: Yellow powder or granules

First Aid Measures

Inhalation: Move to fresh air, seek medical attention if symptoms persist.
Skin Contact: Wash thoroughly with soap and water.
Eye Contact: Flush immediately with water for minimum 15 minutes, seek medical attention for irritation.
Ingestion: Rinse mouth, do not induce vomiting, seek medical advice for larger quantities.
Symptoms: Coughing, sneezing, mild burning of eyes or skin, headache if a significant amount of dust is inhaled.

Fire-Fighting Measures

Flammability: Flammable as a fine dust or powder.
Suitable Extinguishing Media: Dry chemical, foam, sand; avoid using water jets directly on burning powder.
Unsuitable Extinguishing Media: Avoid water spray that may spread dust.
Hazardous Combustion Products: Hydrogen sulfide, sulfur dioxide.
Special Precautions: Firefighters should wear full protective clothing and self-contained breathing apparatus.
Explosion Risk: Dust clouds may explode if ignited in confined space.

Accidental Release Measures

Personal Precautions: Avoid breathing dust, ensure adequate ventilation, use protective gear.
Environmental Precautions: Prevent large amounts from entering waterways, sewers.
Clean-up Procedures: Sweep or shovel into suitable containers for recycling or disposal; use non-sparking tools.
Disposal: Dispose in accordance with local regulations.
Decontamination: Wash spill site with water after material pick-up is complete, avoid creating dust clouds.

Handling and Storage

Handling: Use in well-ventilated areas, avoid generating dust, ground/bond containers.
Personal Hygiene: Wash hands after handling, avoid eating or smoking around product.
Storage Conditions: Keep containers tightly closed in a cool, dry, well-ventilated area.
Storage Incompatibilities: Keep away from oxidizers, sources of ignition, acids.
Special Storage Requirements: Store in labeled containers, control access to trained staff.

Exposure Controls and Personal Protection

Occupational Exposure Limit: None established for biological product; general dust limit applies (10 mg/m³ total inhalable dust, 5 mg/m³ respirable dust).
Engineering Controls: Use local exhaust ventilation, dust collectors, closed systems.
Personal Protective Equipment: NIOSH-approved respirator for dusty conditions, gloves (nitrile or neoprene), goggles or face shield, long sleeves and pants.
Environmental Controls: Collect dust at source, avoid discharge to environment.
Workplace Hygiene: Clean up regularly to avoid accumulation of dust.

Physical and Chemical Properties

Physical State: Solid (powder, granules, or micro-prills)
Color: Bright yellow to pale yellow
Odor: Faint characteristic smell, can be pungent if impure
Melting Point: 115 °C (239 °F)
Boiling Point: 445 °C (833 °F)
Solubility: Insoluble in water, soluble in carbon disulfide
Density: ~2.0 g/cm³
Vapor Pressure: Negligible under normal conditions
Flash Point: 190 °C (374 °F)

Stability and Reactivity

Chemical Stability: Stable under normal conditions, sensitive to high temperature and sparks.
Possibility of Hazardous Reactions: Contact with oxidizing agents may result in violent reactions.
Conditions to Avoid: Heat, open flames, sparks, static discharge, strong oxidizers, acids.
Hazardous Decomposition Products: Sulfur oxides, hydrogen sulfide.
Polymerization: Does not occur.
Reactivity: Reacts vigorously with strong oxidizing agents.

Toxicological Information

Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Acute Effects: Respiratory tract irritation from dust, mild skin or eye irritation.
Chronic Effects: Prolonged exposure may exacerbate asthma or bronchitis.
LD50 (oral, rat): > 5000 mg/kg (low toxicity)
Carcinogenicity: Not listed as carcinogenic by IARC, OSHA, or NTP.
Mutagenicity: No evidence in standard tests
Other Health Effects: May cause headache, dizziness at high dust concentrations.

Ecological Information

Aquatic Toxicity: Low risk to aquatic life in normal use.
Persistence and Degradability: Elemental sulfur is slowly oxidized to sulfate by soil bacteria.
Bioaccumulative Potential: Not likely due to limited solubility and mobility.
Mobility in Soil: Low, but can move with erosion or runoff in large spills.
Other Adverse Effects: Large releases may disrupt local soil or water ecosystems temporarily; generally used as a soil amendment.

Disposal Considerations

Waste Treatment Methods: Collect waste and contaminated material for approved landfill or incineration.
Container Disposal: Empty containers may contain residue; triple-rinse and recycle according to local laws.
Environmental Precautions: Avoid dispersing large amounts in waterways.
Regulatory Guidance: Follow local, regional, and national guidelines.

Transport Information

UN Number: 1350
Proper Shipping Name: Sulfur
Transport Hazard Class: 4.1 (Flammable solid for bulk shipments)
Packing Group: III
Labeling Requirements: Flammable solid label for bulk or powder transport
Special Precautions for Users: Avoid transporting with oxidizers, acids, or sources of ignition.
Other Transport Information: Not regulated in small, non-bulk packaging by road, rail, or air.

Regulatory Information

OSHA: Not specifically regulated, follow general safety guidelines
SARA Title III: Not listed as a hazardous chemical
TSCA Inventory: Listed
EPA Regulations: Not subject to special reporting, regular environmental precautions apply
EU Regulations: Reach Registered; not classified as dangerous under EEC Directive 67/548/EEC
Other Regulatory Notes: Check regulations in your local area before manufacture, import, storage, and use.