Product Name: Ammonium Chloride
Chemical Formula: NH4Cl
Synonyms: Sal Ammoniac, Ammonium Muriate
CAS Number: 12125-02-9
Recommended Use: Industrial and laboratory use in fertilizers, batteries, metalwork, and textile printing
Supplier Details: Company name and address as on product label
Emergency Contact: Local poison control center or emergency response number from label
Classification: Acute Toxicity (oral, inhalation), Eye Irritation
GHS Label Elements: Warning, Exclamation mark
Hazard Statements: Harmful if swallowed, causes serious eye irritation, may cause respiratory tract irritation
Precautionary Statements: Avoid breathing dust, avoid contact with eyes, wash thoroughly after handling, wear protective equipment
Physical Hazards: Not flammable, not explosive, under certain conditions can release toxic gases
Environmental Hazards: Potential harm to aquatic life with long-term exposure
Chemical Name: Ammonium Chloride
Concentration: 98-100%
Impurities: Trace mineral salts and moisture, based on manufacturing source
Hazardous Components: None reported at standard concentrations
Inhalation: Move person to fresh air, assist breathing as needed, consult medical attention if symptoms persist
Skin Contact: Remove contaminated clothing and wash skin with soap and water, medical attention if irritation develops
Eye Contact: Rinse eyes with water for several minutes while keeping lids open, immediate medical attention for discomfort or vision changes
Ingestion: Rinse mouth with water, do not induce vomiting, seek medical advice right away
Most Important Symptoms: Burning sensations, coughing, shortness of breath, possible stomach upset or headache
Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Special Hazards: At high temperatures, can decompose and release ammonia and hydrogen chloride gases, both irritating and corrosive
Protective Equipment: Full protective clothing with self-contained breathing apparatus for firefighters
Advice for Firefighters: Stay upwind, prevent firefighting water from entering drains
Personal Precautions: Use proper personal protection including dust mask, goggles, gloves
Environmental Precautions: Avoid release into waterways, prevent spillage from entering drains, report large releases as per local regulation
Methods for Cleaning Up: Sweep and collect spilled material, avoid dry sweeping, vacuum with HEPA filter if possible, place in suitable container for proper disposal, wash spill site with water after cleanup
Precautions for Safe Handling: Avoid inhaling dust and direct contact with skin and eyes, work in well-ventilated areas, keep containers tightly closed when not in use, wash hands after use
Conditions for Storage: Store in dry, cool, well-ventilated environment, protect from moisture and incompatible materials like strong bases and oxidizers
Storage Container Materials: Use original containers, close lids tightly, keep away from sources of heat, acids, and alkalis
Permissible Exposure Limits: OSHA PEL: 10 mg/m3 (total dust), ACGIH TLV: 10 mg/m3
Engineering Controls: Local exhaust ventilation to reduce airborne concentration, enclosed process equipment where feasible
Personal Protective Equipment: Safety glasses or goggles, chemical-resistant gloves, dust mask or respirator in dusty environments, lab coat or work clothes
Hygiene Measures: Wash hands thoroughly after handling, launder contaminated clothing before reuse, keep eating and drinking out of work area
Appearance: White crystalline powder or colorless crystals
Odor: Odorless, slight saline taste
pH (10% solution): 5.0 – 5.5
Melting Point: Decomposes at 338°C (640°F)
Boiling Point: Sublimes without boiling at atmospheric pressure
Solubility: Readily soluble in water, soluble in glycerol, slightly soluble in alcohol
Density: About 1.527 g/cm3
Vapor Pressure: Practically none under normal conditions
Partition Coefficient (n-octanol/water): Not determined
Other Data: Non-flammable, stable under normal use conditions
Chemical Stability: Stable at standard temperature and pressure, moisture absorption can cause caking
Reactivity: Reacts with strong oxidizing agents, alkalis and acids release ammonia and hydrogen chloride gases on decomposition
Conditions to Avoid: High humidity, excess moisture, incompatible materials including chlorine, nitric acid, sodium and potassium hypochlorite
Hazardous Decomposition Products: Ammonia, hydrogen chloride gas
Possibility of Hazardous Reactions: None under recommended handling and storage
Acute Toxicity: Oral LD50 (rat) about 1650 mg/kg, relatively low toxicity except at high exposures
Inhalation: May cause irritation of nose, throat, lungs, coughing, breathing difficulty at high concentrations
Skin Contact: Prolonged exposure may cause mild irritation
Eye Contact: Risk of redness, pain, severe irritation with direct contact
Chronic Effects: Long-term excessive exposure can impact kidney, liver, result in metabolic imbalances; limited evidence in humans
Carcinogenicity: Not listed as carcinogenic by IARC, NTP, or OSHA
Other Effects: Sensitive individuals may react at lower levels; always best to limit prolonged or repeated exposure
Ecotoxicity: Toxic to aquatic organisms in high concentrations, particularly in small or enclosed water bodies
Persistence and Degradability: Product dissociates in water, ammonium ion can be nitrified by bacteria to nitrate
Bioaccumulative Potential: Low, little potential for buildup in organisms
Mobility in Soil: Moves readily with water, limited adsorption to soil particles, may leach to ground water
Other Effects: Contributes to eutrophication in nutrient-sensitive water systems, can harm algae and aquatic invertebrates
Waste Disposal Methods: Dispose of in accordance with local, regional, national regulations; avoid disposal into drains or natural water courses
Container Handling: Dispose of contaminated containers as hazardous waste if they cannot be cleaned
Neutralization: For small quantities, dissolve in water, dilute, and neutralize under professional supervision before controlled disposal
Recycling: Product and packaging recycling options depend on contamination, check with regional waste management authorities
UN Number: Not regulated for transport in most jurisdictions
Proper Shipping Name: Ammonium Chloride
Transport Hazard Class: Not classed as hazardous for road, rail, sea, or air
Packing Group: Not assigned
Special Precautions: Prevent movement during transport to avoid rupture or spillage, keep away from food and feedstuffs, do not transport with incompatible substances
OSHA (USA): Listed hazardous chemical, subject to workplace labeling and communication standards
SARA Title III: Not subject to reporting under Section 302 or 313, general workplace safety compliance applies
REACH (EU): Registered for approved uses, safety assessment required for significant volumes
Canadian WHMIS: Classified as D2B (toxic material causing other effects), subject to workplace and environmental regulations
Other Regulations: Ensure compliance with all relevant national, regional, and local regulations on worker safety, pollution prevention, and chemical storage