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Material Safety Data Sheet (MSDS) for Allura Red

Identification

Product Name: Allura Red AC
CAS Number: 25956-17-6
Synonyms: FD&C Red No. 40, Food Red 17, C.I. 16035
Recommended Use: Food colorant, pharmaceutical dye, cosmetic applications
Manufacturer: Refer to supply chain or distributor contact information
Emergency Contact: Local poison control center or emergency response number provided on product label

Hazard Identification

Classification: Not classified as hazardous according to OSHA Hazard Communication Standard
Signal Word: None required
Hazard Statements: May cause skin and eye irritation upon direct contact; overexposure through inhalation or ingestion could aggravate existing health conditions
Pictograms: None required under GHS
Precautionary Statements: Avoid breathing dust; avoid contact with eyes, skin, and clothing; wash hands thoroughly after handling
Potential Health Effects: Allergic reactions have occurred in sensitive individuals, symptoms vary from mild rash to hyperactivity in children reported in some studies

Composition / Information on Ingredients

Chemical Name: Disodium 6-hydroxy-5-[(2-methoxy-5-methyl-4-sulfonatophenyl)azo]naphthalene-2-sulfonate
Common Names: Allura Red, FD&C Red 40
CAS Number: 25956-17-6
EC Number: 247-368-0
Concentration: Greater than 90% Allura Red, trace amounts of subsidiary coloring agents and sodium salts as typical impurities

First Aid Measures

Eye Contact: Rinse with plenty of water for several minutes, remove contact lenses if present, continue rinsing, seek medical attention if irritation persists
Skin Contact: Wash area thoroughly with soap and water, remove contaminated clothing, consult doctor if irritation develops
Inhalation: Move to fresh air, monitor for respiratory symptoms, seek medical attention if coughing or breathing difficulty appears
Ingestion: Rinse mouth, drink water, avoid inducing vomiting, consult poison control or physician

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, foam, dry chemical, or carbon dioxide
Unsuitable Extinguishing Media: Strong direct water jets
Specific Hazards: Thermal decomposition produces hazardous gases including nitrogen oxides, sulfur oxides, and carbon monoxide
Protective Equipment: Firefighters use self-contained breathing apparatus and protective clothing
Special Precautions: Avoid breathing fumes from combustion, contain runoff

Accidental Release Measures

Personal Precautions: Use personal protective equipment as required, ventilate area, avoid generation of dust, stop source of spill if safe
Environmental Precautions: Prevent entry into sewers or water systems, notify authorities in case of large discharge
Methods for Clean-Up: Sweep up dry material, avoid creating dust, transfer material to suitable container for disposal, clean surfaces with water after collection
Disposal: Refer to disposal considerations

Handling and Storage

Handling: Avoid dust formation, use local exhaust ventilation if necessary, wash hands after use, keep separate from incompatible substances
Storage: Store in tightly closed containers in cool, dry, well-ventilated area, protect from moisture and direct sunlight, keep away from oxidizers and reducing agents, maintain inventory record to monitor expiration

Exposure Controls and Personal Protection

Engineering Controls: Use adequate ventilation or local exhaust to control dust, keep airborne concentrations below recommended limits
Personal Protective Equipment: Use safety glasses or goggles, wear protective gloves, use dust mask or respirator if dust is generated
Hygiene Measures: Remove and wash contaminated clothing, do not eat, drink, or smoke while using product, maintain cleanliness of work area

Physical and Chemical Properties

Appearance: Dark red to orange-red powder
Odor: Odorless
Melting Point: Decomposes before melting above 300°C
Solubility: Soluble in water, insoluble in ethanol
pH: 5 – 7 for a 1% solution in water
Boiling Point: Not applicable
Flash Point: Not flammable
Vapor Pressure: Negligible at room temperature
Density: 1.2–1.3 g/cm³
Relative Molecular Mass: 496.42 g/mol
Other Properties: Stable under standard temperature and pressure, intensive staining ability, will color contact surfaces

Stability and Reactivity

Chemical Stability: Remains stable under recommended storage conditions
Conditions to Avoid: High temperatures, moisture, direct sunlight
Incompatible Materials: Strong oxidizing agents, strong reducing agents, acids, bases
Hazardous Decomposition Products: Nitrogen oxides, sulfur oxides, sodium oxides, carbon monoxide, carbon dioxide generated under fire conditions
Reactivity: Not considered reactively dangerous under normal use

Toxicological Information

Acute Toxicity: LD50 oral (rat): > 2000 mg/kg; not considered acutely toxic under normal use concentrations
Chronic Effects: Studies suggest risk of allergic response; some reports of hyperactivity in children associated with food coloring intake, though major health agencies consider intake within established ADI as safe
Skin Contact: May cause mild irritation in sensitive individuals
Eye Contact: May cause irritation
Sensitization: Possible for individuals with dye sensitivity
Carcinogenicity: Not listed as carcinogen by IARC, NTP, OSHA
Mutagenicity: Negative in most assays, occasional positive result in in-vitro systems—regulatory reviews indicate risk is low
Reproductive Toxicity: Listed studies do not indicate reproductive impacts

Ecological Information

Ecotoxicity: Not readily biodegradable, dyes water when released, may affect aquatic environments at elevated concentrations
Persistence and Degradability: Allura Red is not easily broken down by natural biological processes, focusing attention on long-term accumulation potential
Bioaccumulation: Low bioaccumulation factor in aquatic and terrestrial species
Mobility in Soil: Water soluble, may leach to groundwater under certain conditions, but rapid dilution reduces biological risks
Other Adverse Effects: Effluent regulation for dye substances often focuses on direct discharge to water, review local wastewater requirements

Disposal Considerations

Waste Disposal: Safely dispose in accordance with local, regional, and national requirements, avoid disposing large quantities in the normal waste stream
Container Disposal: Thoroughly clean before reuse or recycling, or dispose as hazardous waste
Special Precautions: Do not release into the environment, ensure material does not enter drains or natural waters
Preferred Treatment: Incineration or landfill under controlled conditions where local laws permit, use of authorized waste disposal contractors is recommended

Transport Information

UN Number: Not regulated as a dangerous good
Proper Shipping Name: Not dangerous according to transport regulations
Transport Hazard Class: Not classified
Packing Group: Not assigned
Environmental Hazards: Not classified
Special Precautions for Transport: Prevent package breaking or spillage, mark clearly if residues present

Regulatory Information

OSHA: Not classified as hazardous under 29 CFR 1910.1200
EU Classification: Approved as food additive E129, regulated under European Food Safety Authority and REACH
TSCA: Listed
DSL/NDSL: Listed
SARA Title III: Not subject to reporting
California Proposition 65: Not listed
Other Regulatory Status: FDA and European authorities periodically review safety; maximum allowable concentration in food specified by legislation