Product Name: Acetic Acid
Chemical Formula: C2H4O2
Common Names: Ethanoic acid, Glacial acetic acid
CAS Number: 64-19-7
Recommended Use: Chemical manufacture, laboratory reagent, food additive (in diluted form as vinegar), descaling agent
Manufacturer/Supplier: Refer to supplier documentation
Emergency Contact Number: Listed on product packaging or local poison control center
Classification: Corrosive to metals, skin corrosion/irritation (Category 1A), serious eye damage (Category 1), flammable liquid (Category 3)
Label Elements: Pictograms for flame, corrosion, exclamation mark
Signal Word: Danger
Hazard Statements: Causes severe skin burns and eye damage. May cause respiratory irritation. Flammable liquid and vapor.
Precautionary Statements: Keep away from heat, sparks, open flames. Wear protective gloves, clothing, eye and face protection. Avoid breathing vapors or mist. Wash hands thoroughly after handling.
Component: Acetic Acid
Concentration: 99-100% for glacial form, diluted forms have lower percentages
Synonyms: Vinegar acid, Methanecarboxylic acid
Impurities: Water, trace organics in technical grade
Other Components: No known significant impurities for analytical and reagent grades
Inhalation: Move person to fresh air. Seek immediate medical attention if breathing is difficult, coughing persists, or symptoms worsen.
Skin Contact: Remove contaminated clothing. Wash skin immediately with plenty of soap and water for several minutes. Get medical advice without delay.
Eye Contact: Rinse eyes gently with water for at least 15 minutes lifting upper and lower eyelids. Do not allow victim to rub eyes. Get emergency medical assistance.
Ingestion: Do not induce vomiting. Rinse mouth thoroughly. Never give anything by mouth to an unconscious person. Call physician or poison center right away.
Suitable Extinguishing Media: Carbon dioxide, alcohol-resistant foam, dry chemical
Unsuitable Extinguishing Media: Do not use water directly on flames as acetic acid is water miscible and water spray may spread the fire
Hazards from Combustion: Produces irritating or toxic fumes including carbon monoxide, carbon dioxide
Protective Equipment for Firefighters: Full protective gear and self-contained breathing apparatus recommended
Special Precautions: Vapors heavier than air can travel to ignition source and flash back. Cool exposed containers with water spray to prevent pressure build-up and possible explosion.
Personal Precautions: Evacuate area, ventilate well. Avoid inhalation of vapors. Keep people away from upwind direction.
Protective Equipment: Use chemical-resistant gloves, safety goggles, face shield, and suitable respiratory protection.
Environmental Precautions: Prevent material from entering drains, sewers, and waterways.
Method for Containment and Cleanup: Absorb with inert material like sand or earth. Collect in appropriate containers for disposal. Wash spill site with copious amounts of water after cleanup, ensuring runoff does not reach storm drains.
Handling: Work in a ventilated area. Use spark-proof tools and explosion-proof equipment. Avoid splashing and formation of mist.
Precautions: Do not breathe vapors or spray. Avoid contact with skin, eyes, clothing. Do not smoke around storage area. Keep away from combustible materials.
Storage: Store in tightly closed containers, in cool, dry, well-ventilated areas out of direct sunlight. Segregate from oxidizers, strong bases, and alkalines. Use containers resistant to corrosion, made from materials like glass, stainless steel, or specific plastics.
Special Considerations: Store away from food or animal feed. Keep upright and secure to prevent leaks or spills.
Occupational Exposure Limits: OSHA PEL: 10 ppm (25 mg/m3), ACGIH TLV: 10 ppm (25 mg/m3), Short-Term Exposure Limit: 15 ppm (37 mg/m3)
Ventilation: Use local exhaust ventilation to control airborne concentrations below exposure limits.
Respiratory Protection: Use NIOSH-approved respirators for vapor/mist if engineering controls do not maintain adequate levels.
Skin Protection: Wear chemical-resistant gloves (nitrile, neoprene), lab coats, aprons, and protective footwear.
Eye Protection: Use tight-fitting goggles and face shield.
Appearance: Clear, colorless liquid with strong vinegar odor
Odor: Pungent, sharp
pH: 2.4 (1N solution)
Melting Point: 16.6°C (62°F)
Boiling Point: 118°C (244°F)
Flash Point: 39°C (102°F), closed cup
Flammability: Flammable at higher concentrations
Explosive Properties: Vapor may form explosive mixtures with air
Vapor Pressure: 15.7 mmHg at 20°C
Relative Density: 1.049 at 20°C
Solubility: Completely miscible with water
Partition Coefficient (log Kow): -0.17
Autoignition Temperature: 427°C
Chemical Stability: Stable under recommended storage and handling conditions. Rapidly absorbed by moisture.
Incompatible Materials: Strong oxidizing agents, strong bases, metals, reducing agents, chlorates, permanganates
Conditions to Avoid: Heat, sparks, flame, direct sunlight, high humidity
Hazardous Decomposition Products: Toxic fumes of carbon monoxide, carbon dioxide under fire conditions
Hazardous Polymerization: Does not occur under normal handling
Routes of Exposure: Inhalation, skin contact, ingestion, eye contact
Acute Effects: Severe damage to mucous membranes, respiratory tract, gastrointestinal tract upon ingestion or inhalation. Skin burns and eye damage.
Chronic Effects: Repeated exposure damages skin, respiratory system, teeth. Cases of bronchitis, erosion, ulceration recorded.
LD50 (oral, rat): 3,310 mg/kg
LC50 (inhalation, rat): 11.4 mg/L (4 hours)
Carcinogenicity: Not classified as carcinogenic by IARC, NTP, or OSHA
Mutagenicity/Teratogenicity: Not known to cause mutations or birth defects in humans.
Sensitization: No evidence identified from reviewed sources.
Ecotoxicity: Harmful to aquatic life at high concentrations. Rapidly biodegrades in environment.
Acute Toxicity for Aquatic Organisms: EC50 (daphnia, 48h): 65 mg/L, LC50 (fish, 96h): 75 mg/L
Bioaccumulation Potential: Low; log Kow -0.17 indicates little bioaccumulation.
Mobility in Soil: Moves quickly, highly miscible in water, penetrates soils easily, may lower pH.
Persistence and Degradability: Degrades quickly under aerobic and anaerobic conditions due to microbial action.
Waste Disposal Methods: Dispose of in accordance with local, regional, and national regulations. Dilute before neutralizing using sodium bicarbonate, then flush with plenty of water. Avoid releasing undiluted product into sewers or the environment.
Container Disposal: Rinse containers thoroughly before discarding. Do not cut, weld, or reuse containers unless completely decontaminated.
Special Precautions: Consult local hazardous waste authorities for details specific to your area.
UN Number: UN2789
UN Proper Shipping Name: Acetic Acid, Glacial
Transport Hazard Class: 8 (corrosive), Subsidiary risk: 3 (flammable liquid)
Packing Group: II
Labels: Corrosive, Flammable Liquid
Marine Pollutant: Not regulated as marine pollutant
Special Precautions for User: Keep containers tightly sealed, upright, labeled during transport. Emergency procedures in case of leakage set by carrier and local law.
OSHA: Listed as hazardous chemical, skin/eye/respiratory irritant
TSCA: Listed on Toxic Substances Control Act inventory
SARA Title III Sections 302/304: Not identified as extremely hazardous substance but subject to reporting under certain quantities
SARA Title III Section 313: Not subject to reporting
RCRA: Hazardous waste if discarded in high concentrations
CERCLA: Reportable quantity (RQ): 5,000 lbs
California Prop 65: Not listed
International Inventories: Listed on EINECS (EU), DSL/NDSL (Canada), ENCS (Japan), AICS (Australia), PICCS (Philippines), IECSC (China), NZIoC (New Zealand)